Synthesis, Characterizations, Magnetism and Thermal Degradation of a 2-Fold Interpenetrated 3D Cobalt-Organic Framework
Linyan Yang, Liangliang Xin, Wen Gu, Shengyun Liao, Peiyao Du, Jinlei Tian, Yanping Zhang, Rui Lv, Xiaohua Wei, Xin Liu and Daizheng Liao
Article first published online: 17 FEB 2014 | DOI: 10.1002/cjoc.201300841
A new coordination polymer, [Co2(L)2(4,4′-bipy)]n·3nH2O (1) based on 5-(3-methyl-5-phenyl-4H-1,2,4-triazol-4-yl)isophthalic acid (H2L) and 4,4′-bipyridine (4,4′-bipy) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction, XRPD, IR, and elemental analysis. Temperature-dependent magnetic susceptibility and thermal degradation for 1 were also studied. A 2-fold parallel interpenetrated ins InS 3,4-conn topology has been obtained.