Chinese Journal of Chemistry
Copyright © 2014 SIOC, CAS, Shanghai & WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Submit Your Next Manuscript Online
The Chinese Journal of Chemistry now offers web-based submission and peer review – Authors can now submit manuscripts to the Chinese Journal of Chemistry online anytime from anwhere
All Archive Articles Now Online
The complete archive of the Chinese Journal of Chemistry is now available online. All articles are fully searchable and linked with thousands of related articles through CrossRef/DOI.
Recently Published Articles
- On Desilylation of 13-Vertex Carborane 1,2-Me2Si(CH2)2-1,2-C2B11H11 (pages 777–782)
Jian Zhang and Zuowei Xie
Article first published online: 26 AUG 2014 | DOI: 10.1002/cjoc.201400433
Facile double desilylation of 13-vertex carborane 1,2-Me2Si(CH2)2-1,2-C2B11H11 can be attributed to joint actions of several factors involving the high ring-strain of exo five-membered C4Si ring, Lewis acidity of Si atom and Br⊘nsted acidity of silica surface.
- You have free access to this contentCover Picture: Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes (Chin. J. Chem. 8/2014) (page 657)
Xiao Shen, Qinghe Liu, Chuanfa Ni and Jinbo Hu
Article first published online: 26 AUG 2014 | DOI: 10.1002/cjoc.201490017
The cover picture shows an efficient nucleophilic difluoro(phenylsulfonimidoyl)methylation of unactivated primary alkyl bromides with PhSO(NTBS)CF2H. It is particularly remarkable that, when 1.5 equiv. of alkyl bromides are used, the substitution products are obtained in moderate to excellent yields. The prepared difluoro(phenylsulfonimidoyl)-methylated alkanes can be readily transformed to gem-difluoroalkenes via base-mediated β-elimination reaction. More details are discussed in the article by Hu et al. on page 703–708.
- You have free access to this contentDedicated to Professor Chengye Yuan and Professor Li-Xin Dai on the Occasion of Their 90th Birthdays (pages 659–660)
Article first published online: 26 AUG 2014 | DOI: 10.1002/cjoc.201490018
- π-Extented Conjugated Polymers Entailing Pechmann Dye Moieties for Solution-Processed Ambipolar Organic Semiconductors (pages 788–796)
Zhengxu Cai, Zitong Liu, Hewei Luo, Penglin Qi, Guanxin Zhang and Deqing Zhang
Article first published online: 26 AUG 2014 | DOI: 10.1002/cjoc.201400423
Two new D-A polymers (BPDBDTE and BPDDTE) with BPD as electron accepting moieties are reported. The results show that BPDBDTE with more alkyl parts shows similar ambipolar semiconducting behaviors with BPDDTE. Furthermore BPDDTE can be dissolved in common solvents at room temperature and solution-processed easily, thus this semiconducting polymer is potentially processible with inkjet printing and roll-to-roll printing techniques.