Advanced Synthesis & Catalysis

Cover image for Vol. 359 Issue 4

Early View (Online Version of Record published before inclusion in an issue)

Editor: Joe P. Richmond, Chairman of the Editorial Board: Eric N. Jacobsen

Impact Factor: 6.453

ISI Journal Citation Reports © Ranking: 2015: 1/72 (Chemistry Applied); 5/59 (Chemistry Organic)

Online ISSN: 1615-4169

Associated Title(s): Angewandte Chemie International Edition, Asian Journal of Organic Chemistry, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemCatChem, European Journal of Organic Chemistry

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  1. Updates

  2. Communications

    1. Chelation-Assisted Palladium-Catalyzed γ-Arylation of Aliphatic Carboxylic Acid Derivatives

      Aniruddha Dey, Sandeep Pimparkar, Arghya Deb, Srimanta Guin and Debabrata Maiti

      Version of Record online: 23 FEB 2017 | DOI: 10.1002/adsc.201601121

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  3. Full Papers

    1. Very Important Publication

  4. Updates

  5. Communications

    1. Intramolecular Carbonylative C–H Functionalization of 1,2,3- Triazoles for the Synthesis of Triazolo[1,5-a]indolones

      Cedrick Veryser, Gert Steurs, Luc Van Meervelt and Wim M. De Borggraeve

      Version of Record online: 21 FEB 2017 | DOI: 10.1002/adsc.201601388

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    2. Direct Access to Isoindolin-1-one Scaffolds by Copper-Catalyzed Divergent Cyclizations of 2-Formylbenzonitrile and Diaryliodonium Salts

      Li Liu, Jian Qiang, Shu-Hua Bai, Hui-Ling Sung, Chun-Bao Miao and Jian Li

      Version of Record online: 21 FEB 2017 | DOI: 10.1002/adsc.201601403

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  6. Full Papers

    1. Base-Promoted Addition of Arylacetonitriles to Terminal Alkynes: Regio- and Stereoselective Access to Disubstituted Acrylonitriles

      Chaorong Qi, Youbin Peng, Lu Ouyang, Yanwei Ren and Huanfeng Jiang

      Version of Record online: 21 FEB 2017 | DOI: 10.1002/adsc.201601024

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  7. Cover Pictures

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      Late-Stage Diversification of Non-Steroidal Anti-Inflammatory Drugs by Transition Metal-Catalyzed C–H Alkenylations, Thiolations and Selenylations

      Wenbo Ma, Hongbo Dong, Daoxin Wang and Lutz Ackermann

      Version of Record online: 21 FEB 2017 | DOI: 10.1002/adsc.201700173

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      The front cover image provided by Wenbo Ma and Lutz Ackermann, illustrates the ruthenium- and silver-catalyzed selective C–H alkenylations, thiolations and selenylations of phenazones with alkenes, disulfides and diselenides. These transformations could be applied to a wide range of substrates and proceed with excellent levels of chemo- and site-selectivity as well as high functional group tolerance. The power of the C–H functionalization strategy was also reflected by late-stage diversification to access selectively substituted pyrazolones with diverse pharmacological activities. Further details can be found in the full paper on page xxxx–xxxx (W. Ma, H. Dong, D. Wang, L. Ackermann, Adv. Synth. Catal. 2017, 359, xxxx–xxxx (DOI: 10.1002/adsc.201600937)

  8. Full Papers

    1. Regio- and Stereospecific O-Glycosylation of Phenolic Compounds Catalyzed by a Fungal Glycosyltransferase from Mucor hiemalis

      Jin Feng, Peng Zhang, Yinglu Cui, Kai Li, Xue Qiao, Ying-Tao Zhang, Shu-Ming Li, Russell J. Cox, Bian Wu, Min Ye and Wen-Bing Yin

      Version of Record online: 16 FEB 2017 | DOI: 10.1002/adsc.201601317

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    2. Very Important Publication

  9. Cover Pictures

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      Ruthenium-Catalyzed Aminomethylation and Methylation of Phenol Derivatives Utilizing Methanol as the C1 Source

      Seoksun Kim and Soon Hyeok Hong

      Version of Record online: 16 FEB 2017 | DOI: 10.1002/adsc.201700161

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      The front cover picture, provided by Seoksun Kim and Soon Hyeok Hong, illustrates the development of C–N and C–C bond formation reactions utilizing methanol as an environmentally benign C1 feedstock. Aminomethylation of phenol and methylation of naphthol were achieved via ruthenium-catalyzed dehydrogenation of methanol without using any additional reagent. On the basis of various mechanistic studies, an iminium cation, generated from methanol and an amine, is proposed to be the key electrophile in both reactions. Details can be found in the full paper on pages XXX–XXX (S. Kim, S. H. Hong, Adv. Synth. Catal. 2017, 359, XXX–XXX; DOI: 10.1002/adsc.201601117).

  10. Updates

    1. Ferrocenylindium Reagents in Palladium-Catalyzed Cross-Coupling Reactions: Asymmetric Synthesis of Planar Chiral 2-Aryl Oxazolyl and Sulfinyl Ferrocenes

      Mauro Mato, Cristina Pérez-Caaveiro, Luis A. Sarandeses and José Pérez Sestelo

      Version of Record online: 16 FEB 2017 | DOI: 10.1002/adsc.201601397

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  11. Full Papers

    1. Host-Catalyzed Cyclodehydration–Rearrangement Cascade Reaction of Unsaturated Tertiary Alcohols

      Lorenzo Catti, Alexander Pöthig and Konrad Tiefenbacher

      Version of Record online: 15 FEB 2017 | DOI: 10.1002/adsc.201601363

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  12. Updates

    1. Efficient Selenium-Catalyzed Selective C(sp3)−H Oxidation of Benzylpyridines with Molecular Oxygen

      Weiwei Jin, Poonnapa Zheng, Wing-Tak Wong and Ga-Lai Law

      Version of Record online: 8 FEB 2017 | DOI: 10.1002/adsc.201601065

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  13. Full Papers

    1. Gold-Oxazoline Complex-Catalyzed Cross-Dehydrogenative Coupling of Glycine Derivatives and Alkenes

      Minjie Ni, Yan Zhang, Tingting Gong and Bainian Feng

      Version of Record online: 8 FEB 2017 | DOI: 10.1002/adsc.201601066

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  14. Communications

    1. Regioselective Direct C3-Phosphorylation of N-Sulfonylindoles under Mild Oxidative Conditions

      Feng Su, Weidong Lin, Pengfei Zhu, Dezhi He, Jianbin Lin, Hui-Jun Zhang and Ting-Bin Wen

      Version of Record online: 7 FEB 2017 | DOI: 10.1002/adsc.201601204

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  15. Updates

    1. Diarylprolinol as a Ligand for Enantioselective Alkynylation of Cyclic Imines

      Lode De Munck, Alicia Monleón, Carlos Vila and José R. Pedro

      Version of Record online: 7 FEB 2017 | DOI: 10.1002/adsc.201601379

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    2. Green Organocatalytic Synthesis of Indolines and Pyrrolidines from Alkenes

      Alexis Theodorou and Christoforos G. Kokotos

      Version of Record online: 7 FEB 2017 | DOI: 10.1002/adsc.201601262

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  16. Communications

    1. One-Pot Assembly of Highly Functionalized Cyclopenta[b]pyrroles via a Calcium(II)- and Copper(II)-Catalyzed Reaction Sequence

      Lucile Marin, Vincent Gandon, Emmanuelle Schulz and David Lebœuf

      Version of Record online: 7 FEB 2017 | DOI: 10.1002/adsc.201601301

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  17. Full Papers

    1. Palladium-Catalyzed Addition of Arylboronic Acids to para- Quinone Methides for Preparation of Diarylacetates

      Ruijing Zhuge, Liang Wu, Mao Quan, Nicholas Butt, Guoqiang Yang and Wanbin Zhang

      Version of Record online: 6 FEB 2017 | DOI: 10.1002/adsc.201601302

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  18. Communications

    1. Synthesis of Fluorenes with an All-Carbon Quaternary Center via Palladium-Catalyzed Dual Arylation using Cyclic Diaryliodonium Triflates

      Xiaopeng Peng, Hongwen Luo, Fuhai Wu, Daqian Zhu, A. Ganesan, Peng Huang and Shijun Wen

      Version of Record online: 6 FEB 2017 | DOI: 10.1002/adsc.201601260

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  19. Reviews

    1. Very Important Publication

  20. Full Papers

    1. Regioselective Hydroxylation of Stilbenes by Engineered Cytochrome P450 from Thermobifida fusca YX

      Ansgar Rühlmann, Dragutin Antovic, Thomas J. J. Müller and Vlada B. Urlacher

      Version of Record online: 6 FEB 2017 | DOI: 10.1002/adsc.201601168

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    2. Cooperative Cation-Binding Catalysis as an Efficient Approach for Enantioselective Friedel–Crafts Reaction of Indoles and Pyrrole

      Mun Jong Kim, Lu Xue, Yidong Liu, Sushovan Paladhi, Si Joon Park, Hailong Yan and Choong Eui Song

      Version of Record online: 6 FEB 2017 | DOI: 10.1002/adsc.201601198

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    3. Iron(III) Chloride-Mediated Regio- and Stereoselective Chlorosulfonylation of Alkynes and Alkenes with Sodium Sulfinates

      Kui Zeng, Lang Chen, Yi Chen, Yongping Liu, Yongbo Zhou, Chak-Tong Au and Shuang-Feng Yin

      Version of Record online: 6 FEB 2017 | DOI: 10.1002/adsc.201601211

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  21. Updates

    1. Kinetic Resolution of Aromatic β-Amino Acids Using a Combination of Phenylalanine Ammonia Lyase and Aminomutase Biocatalysts

      Nicholas J. Weise, Syed T. Ahmed, Fabio Parmeggiani and Nicholas J. Turner

      Version of Record online: 6 FEB 2017 | DOI: 10.1002/adsc.201600894

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  22. Communications

    1. Synthesis of 2-Substituted Quinolines via Rhodium(III)-Catalyzed C–H Activation of Imidamides and Coupling with Cyclopropanols

      Xukai Zhou, Zisong Qi, Songjie Yu, Lingheng Kong, Yang Li, Wan-Fa Tian and Xingwei Li

      Version of Record online: 6 FEB 2017 | DOI: 10.1002/adsc.201601278

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    2. Utilizing an Encapsulated Solution of Reagents to Achieve the Four-Component Synthesis of (Benzo)Thiophene Derivatives

      Chaoren Shen, Anke Spannenberg, Matthias Auer and Xiao-Feng Wu

      Version of Record online: 6 FEB 2017 | DOI: 10.1002/adsc.201601343

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    3. Palladium-Catalyzed, Silver-Assisted Direct C-5–H Arylation of 3-Substituted 1,2,4-Oxadiazoles under Microwave Irradiation

      Shan Li, Penghui Wan, Jing Ai, Rong Sheng, Yongzhou Hu and Youhong Hu

      Version of Record online: 6 FEB 2017 | DOI: 10.1002/adsc.201600913

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  23. Updates

    1. Preparation of Propargylic Sulfinates and their [2,3]-Sigmatropic Rearrangement to Allenic Sulfones

      Rama Rao Tata, Carissa S. Hampton and Michael Harmata

      Version of Record online: 30 JAN 2017 | DOI: 10.1002/adsc.201600986

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    2. Palladium(0)-catalyzed Domino C−N Coupling/Hydroamination/C−H Arylation: Efficient Synthesis of Benzothieno[2′,3′:4,5]pyrrolo[1,2-f]phenanthridines

      Ghazwan Ali Salman, Ngo Nghia Pham, Thang Ngoc Ngo, Peter Ehlers, Alexander Villinger and Peter Langer

      Version of Record online: 30 JAN 2017 | DOI: 10.1002/adsc.201601285

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    3. Chromium-Catalysed Asymmetric Dearomatization Addition Reactions of Bromomethylnaphthalenes

      Weiqiang Chen, Jing Bai and Guozhu Zhang

      Version of Record online: 30 JAN 2017 | DOI: 10.1002/adsc.201600962

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    4. Metal–free Decarboxylative Amination: An Alternative Approach Towards Regioselective Synthesis of β-Carboline N-fused Imidazoles

      Dharmender Singh, Vipin Kumar, Nisha Devi, Chandi C. Malakar, Ravi Shankar and Virender Singh

      Version of Record online: 27 JAN 2017 | DOI: 10.1002/adsc.201600970

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    5. Silver-Catalyzed Regio- and Stereoselective Thiocyanation of Haloalkynes: Access to (Z)-Vinyl Thiocyanates

      Guangbin Jiang, Chuanle Zhu, Jianxiao Li, Wanqing Wu and Huanfeng Jiang

      Version of Record online: 27 JAN 2017 | DOI: 10.1002/adsc.201601142

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  24. Communications

  25. Full Papers

  26. Communications

    1. Boron Trifluoride-Catalyzed Synthesis of 3-Alkylidene-3H-indole N-Oxides via Tandem Reaction of Propargylic Alcohols and Nitrosobenzenes

      Sengodagounder Muthusamy, Alagesan Balasubramani and Eringathodi Suresh

      Version of Record online: 26 JAN 2017 | DOI: 10.1002/adsc.201601151

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  27. Full Papers

  28. Communications

    1. Cooperative Electrocatalytic and Chemoselective Alcohol Oxidation by Shvo's Catalyst

      Jeroen Lybaert, Stanislav Trashin, Bert U. W. Maes, Karolien De Wael and Kourosch Abbaspour Tehrani

      Version of Record online: 26 JAN 2017 | DOI: 10.1002/adsc.201600783

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    2. Disulfide-Directed C–H Hydroxylation for Synthesis of Sulfonyl Diphenyl Sulfides and 2-(Phenylthio)phenols with Oxygen as Oxidant

      Long Wang, Yi-Bi Xie, Nian-Yu Huang, Nuo-Nuo Zhang, De-Jiang Li, Yu-Lin Hu, Ming-Guo Liu and Dong-Sheng Li

      Version of Record online: 24 JAN 2017 | DOI: 10.1002/adsc.201600861

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  29. Full Papers

    1. Iron-Catalyzed Isopropylation of Electron-Deficient Aryl and Heteroaryl Chlorides

      James N. Sanderson, Andrew P. Dominey and Jonathan M. Percy

      Version of Record online: 24 JAN 2017 | DOI: 10.1002/adsc.201601097

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  30. Updates

  31. Communications

    1. Regioselective Enzymatic Carboxylation of Bioactive (Poly)phenols

      Katharina Plasch, Verena Resch, Julien Hitce, Jarosław Popłoński, Kurt Faber and Silvia M. Glueck

      Version of Record online: 18 JAN 2017 | DOI: 10.1002/adsc.201601046

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  32. Reviews

    1. Transition Metal-Catalyzed Reactions Involving Oximes

      Jun Li, Yitian Hu, Daopeng Zhang, Qing Liu, Yunhui Dong and Hui Liu

      Version of Record online: 18 JAN 2017 | DOI: 10.1002/adsc.201600807

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  33. Communications

  34. Updates

    1. Nickel-Catalyzed Deoxygenative Deuteration of Aryl Sulfamates

      Masami Kuriyama, Shota Kujirada, Kotaro Tsukuda and Osamu Onomura

      Version of Record online: 29 DEC 2016 | DOI: 10.1002/adsc.201601105

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    2. Unveiling the Hidden Performance of Whole Cells in the Asymmetric Bioreduction of Aryl-containing Ketones in Aqueous Deep Eutectic Solvents

      Paola Vitale, Vincenzo Mirco Abbinante, Filippo Maria Perna, Antonio Salomone, Cosimo Cardellicchio and Vito Capriati

      Version of Record online: 29 DEC 2016 | DOI: 10.1002/adsc.201601064

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    3. Copper-Catalyzed Remote C−H Amination of Quinolines with N-Fluorobenzenesulfonimide

      Yao Yin, Jian Xie, Feng-Qing Huang, Lian-Wen Qi and Bo Zhang

      Version of Record online: 28 DEC 2016 | DOI: 10.1002/adsc.201600947

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    4. Total Synthesis of (±)-Dihydroisosubamol

      Daniel Pflästerer, Matthias Rudolph, Brian F. Yates, Alireza Ariafard and A. Stephen K. Hashmi

      Version of Record online: 23 DEC 2016 | DOI: 10.1002/adsc.201600663

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    5. Fluorination-Oxidation of 2-Hydroxymethylindole Using Selectfluor

      Xiaojian Jiang, Feng Zhang, Junjie Yang, Pei Yu, Peng Yi, Yewei Sun and Yuqiang Wang

      Version of Record online: 22 DEC 2016 | DOI: 10.1002/adsc.201600786

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    6. Sulfide and Sulfonyl Chloride as Sulfonylating Precursors for the Synthesis of Sulfone-Containing Isoquinolinonediones

      Xiao-Feng Xia, Su-Li Zhu, Dawei Wang and Yong-Min Liang

      Version of Record online: 22 DEC 2016 | DOI: 10.1002/adsc.201600982

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