Advanced Synthesis & Catalysis

Cover image for Advanced Synthesis & Catalysis

Early View (Online Version of Record published before inclusion in an issue)

Editor: Joe P. Richmond, Chairman of the Editorial Board: Eric N. Jacobsen

Impact Factor: 5.663

ISI Journal Citation Reports © Ranking: 2014: 2/72 (Chemistry Applied); 6/58 (Chemistry Organic)

Online ISSN: 1615-4169

Associated Title(s): Angewandte Chemie International Edition, Asian Journal of Organic Chemistry, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemCatChem, European Journal of Organic Chemistry

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  1. 1 - 63
  1. Communications

    1. Copper-Catalyzed C[BOND]N Bond Formation via Oxidative Cross-Coupling of Amines with α-Aminocarbonyl Compounds

      Xing-Xing Liu, Zhao-Yang Wu, Yong-Qin He, Xiao-Qiang Zhou, Ting Hu, Chao-Wei Ma and Guo-Sheng Huang

      Article first published online: 27 APR 2016 | DOI: 10.1002/adsc.201600132

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  2. Full Papers

    1. Photocatalytic Reaction of Diazo Compounds with Aldehydes

      K. Rybicka-Jasińska, Ł. W. Ciszewski and D. Gryko

      Article first published online: 27 APR 2016 | DOI: 10.1002/adsc.201600084

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    2. Conjugated Vinylgold(I)-Vinylideneruthenium(II) Complexes and Related Organoruthenium Compounds: Stable Analogues of Intermediates Proposed in Dual Gold Catalysis

      Marcel Wieteck, Mie Højer Larsen née Vilhelmsen, Pascal Nösel, Jürgen Schulmeister, Frank Rominger, Matthias Rudolph, Markus Pernpointner and A. Stephen K. Hashmi

      Article first published online: 27 APR 2016 | DOI: 10.1002/adsc.201600255

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  3. Updates

    1. You have full text access to this OnlineOpen article
      Intercepting the Gold-Catalysed Meyer–Schuster Rearrangement by Controlled Protodemetallation: A Regioselective Hydration of Propargylic Alcohols

      Matthew N. Pennell, Michael P. Kyle, Samantha M. Gibson, Louise Male, Peter G. Turner, Richard S. Grainger and Tom D. Sheppard

      Article first published online: 27 APR 2016 | DOI: 10.1002/adsc.201600101

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  4. Full Papers

    1. Gold Functionalized Platinum M12L24-Nanospheres and Their Application in Cyclization Reactions

      Stefan H. A. M. Leenders, Maximillian Dürr, Ivana Ivanović-Burmazović and Joost N. H. Reek

      Article first published online: 27 APR 2016 | DOI: 10.1002/adsc.201600071

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  5. Communications

    1. One for Many: A Universal Reagent for Acylation Processes

      Hyun Kyung Moon, Gi Hyeon Sung, Bo Ram Kim, Jong Keun Park, Yong-Jin Yoon and Hyo Jae Yoon

      Article first published online: 27 APR 2016 | DOI: 10.1002/adsc.201501177

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  6. Full Papers

    1. Self-Assembled Multilayer-Stabilized Nickel Nanoparticle Catalyst for Ligand-Free Cross-Coupling Reactions: in situ Metal Nanoparticle and Nanospace Simultaneous Organization

      Naoyuki Hoshiya, Katsumasa Fujiki, Takahisa Taniguchi, Tetsuo Honma, Yusuke Tamenori, Mincen Xiao, Nozomi Saito, Mami Yokoyama, Akira Ishii, Hiromichi Fujioka, Satoshi Shuto, Yoshihiro Sato and Mitsuhiro Arisawa

      Article first published online: 27 APR 2016 | DOI: 10.1002/adsc.201600024

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  7. Updates

    1. Rhodium-Catalyzed [2+2+2] Cycloadditions of Diynes with Morita–Baylis–Hillman Adducts: A Stereoselective Entry to Densely Functionalized Cyclohexadiene Scaffolds

      Martí Fernández, Magda Parera, Teodor Parella, Agustí Lledó, Jean Le Bras, Jacques Muzart, Anna Pla-Quintana and Anna Roglans

      Article first published online: 27 APR 2016 | DOI: 10.1002/adsc.201600039

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  8. Full Papers

    1. Construction of 2,3,4,7-Tetrahydro-1,2,4,5-oxatriazepines via [4+3] Cycloadditions of α-Halogeno Hydrazones with Nitrones

      Hong-Wu Zhao, Hai-Liang Pang, Ting Tian, Bo Li, Xiao-Qin Chen, Xiu-Qing Song, Wei Meng, Zhao Yang, Yue-Yang Liu and Yu-Di Zhao

      Article first published online: 26 APR 2016 | DOI: 10.1002/adsc.201600093

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    2. Sustainable Micellar Gold Catalysis – Poly(2-oxazolines) as Versatile Amphiphiles

      Linda Lempke, Andrea Ernst, Fabian Kahl, Ralf Weberskirch and Norbert Krause

      Article first published online: 25 APR 2016 | DOI: 10.1002/adsc.201600139

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  9. Communications

  10. Commentaries

    1. Gold Catalysis – Steadily Increasing in Importance

      Antonio M. Echavarren, A. Stephen K. Hashmi and F. Dean Toste

      Article first published online: 25 APR 2016 | DOI: 10.1002/adsc.201600381

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  11. Communications

    1. Very Important Publication

      Gold-Catalyzed Aminoalkenylation of β-Amino-1,n-Diynols to Cycloalkyl-, Piperidinyl- and Pyranyl-Fused Pyrroles

      Prasath Kothandaraman, Yichao Zhao, Bo Ra Lee, Clarrisa Jia Le Ng, Jun Yi Lee, Benjamin James Ayers and Philip Wai Hong Chan

      Article first published online: 25 APR 2016 | DOI: 10.1002/adsc.201600011

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  12. Updates

    1. Zinc Iodide-Mediated Direct Synthesis of 2,3-Dihydroisoxazoles from Alkynes and Nitrones

      Zu-Feng Xiao, Ting-Hui Ding, Sheng-Wei Mao, Xiao-Shan Ning and Yan-Biao Kang

      Article first published online: 25 APR 2016 | DOI: 10.1002/adsc.201600044

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  13. Communications

  14. Full Papers

  15. Communications

  16. Full Papers

  17. Reviews

    1. Gold-Catalyzed Cycloisomerizations of 1,n-Diyne Carbonates and Esters

      David Philip Day and Philip Wai Hong Chan

      Article first published online: 24 APR 2016 | DOI: 10.1002/adsc.201600005

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  18. Updates

    1. Gold-Catalyzed Cyclizations of Alkynyl Silyl Enol Ethers: An Easy Access to Bicyclo[3.2.1]octanone Derivatives

      Amandine Carrër, Christophe Péan, Françoise Perron-Sierra, Olivier Mirguet and Véronique Michelet

      Article first published online: 24 APR 2016 | DOI: 10.1002/adsc.201501135

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  19. Full Papers

    1. Efficient Modular Synthesis of Isomeric Mono- and Bispyridyl[2.2]paracyclophanes by Palladium-Catalyzed Cross- Coupling Reactions

      Carolin Braun, Eduard Spuling, Niklas B. Heine, Murat Cakici, Martin Nieger and Stefan Bräse

      Article first published online: 24 APR 2016 | DOI: 10.1002/adsc.201600066

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  20. Cover Pictures

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      A Chiral Disulfoxide Ligand for the Efficient Rhodium-Catalyzed 1,2-Addition of Arylboroxines to N-Tosylarylimines

      Guang-Zhen Zhao, Gellért Sipos, Alvaro Salvador, Arnold Ou, Pengchao Gao, Brian W. Skelton and Reto Dorta

      Article first published online: 21 APR 2016 | DOI: 10.1002/adsc.201600322

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      The front cover image, provided by Dorta and co-workers, illustrates how to access diarylmethylamines in high yields and enantioselectivities through the use of a chiral disulfoxide/rhodium precatalyst that effects the 1,2-addition of arylboroxines to aromatic imines. The system is very simple and combines ease of synthesis of the chiral ligand with low catalyst loadings, mild reaction conditions without requiring any external bases or other additives. Details can be found in the full paper on pages xxxx–xxxx (G.-Z. Zhao, G. Sipos, A. Salvador, A. Ou, P. Gao, B. W. Skelton, R. Dorta, Adv. Synth. Catal.­ 2016, 358, xxxx–xxxx; DOI: 10.1002/adsc.201500975).

  21. Full Papers

    1. A Continuous-Flow Cascade Reactor System for Subtilisin A- Catalyzed Dynamic Kinetic Resolution of N-tert-Butyloxycarbonylphenylalanine Ethyl Thioester with Benzylamine

      Péter Falus, Lorenzo Cerioli, Gabriella Bajnóczi, Zoltán Boros, Diána Weiser, József Nagy, Davide Tessaro, Stefano Servi and László Poppe

      Article first published online: 19 APR 2016 | DOI: 10.1002/adsc.201500902

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  22. Communications

    1. Very Important Publication

      Catalytic α-Allylation of Enones with Alcohols via [Gold(I)]-Mediated [3,3]-Sigmatropic Rearrangement of Propargylic Carboxylates

      Elisabetta Manoni, Mario Daka, Marco M. Mastandrea, Assunta De Nisi, Magda Monari and Marco Bandini

      Article first published online: 18 APR 2016 | DOI: 10.1002/adsc.201600113

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  23. Full Papers

  24. Communications

    1. Direct Conversion of Internal Alkynes into α-Iodoenones: One-Step Collaborative Iodination and Oxidation

      Youliang Wang, Alexandre Genoux, Subir Ghorai, Hongyi Chen, Robert Todd and Liming Zhang

      Article first published online: 15 APR 2016 | DOI: 10.1002/adsc.201600027

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    2. Enantioselective Carbene Cascade: An Effective Approach to Cyclopentadienes and Applications in Diels–Alder Reactions

      Xiangbo Wang, Yunfei Zhou, Lihua Qiu, Ruwei Yao, Yang Zheng, Cheng Zhang, Xiaoguang Bao and Xinfang Xu

      Article first published online: 15 APR 2016 | DOI: 10.1002/adsc.201501106

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  25. Updates

    1. Direct Decarboxylative Alkynylation of α,α-Difluoroarylacetic Acids under Transition Metal-Free Conditions

      Xiang Li, Siyu Li, Suyan Sun, Fan Yang, Weiguo Zhu, Yu Zhu, Yusheng Wu and Yangjie Wu

      Article first published online: 15 APR 2016 | DOI: 10.1002/adsc.201501028

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    2. (Pentamethylcyclopentadienyl)cobalt(III)-Catalyzed Oxidative [4+2] Annulation of N[BOND]H Imines with Alkynes: Straightforward Synthesis of Multisubstituted Isoquinolines

      Shang-Shi Zhang, Xu-Ge Liu, Shi-Yong Chen, Dong-Hang Tan, Chun-Yong Jiang, Jia-Qiang Wu, Qingjiang Li and Honggen Wang

      Article first published online: 15 APR 2016 | DOI: 10.1002/adsc.201600025

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  26. Full Papers

    1. Very Important Publication

      Ligand-Assisted Palladium(II)/(IV) Oxidation for sp3 C[BOND]H Fluorination

      Huan Sun, Yi Zhang, Ping Chen, Yun-Dong Wu, Xinhao Zhang and Yong Huang

      Article first published online: 13 APR 2016 | DOI: 10.1002/adsc.201600015

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  27. Communications

    1. Stereoselective Monoamine Oxidase-Catalyzed Oxidative Aza-Friedel–Crafts Reactions of meso-Pyrrolidines in Aqueous Buffer

      Corien de Graaff, Barry Oppelaar, Olivier Péruch, Christophe M. L. Vande Velde, Beatrice Bechi, Nicholas J. Turner, Eelco Ruijter and Romano V. A. Orru

      Article first published online: 13 APR 2016 | DOI: 10.1002/adsc.201600038

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  28. Cover Pictures

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      Recent Advances in Gold-Catalyzed N- and O-Functionalizations of Alkynes with Nitrones, Nitroso, Nitro and Nitroxy Species

      Deepak B. Huple, Satish Ghorpade and Rai-Shung Liu

      Article first published online: 4 APR 2016 | DOI: 10.1002/adsc.201600302

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      The front cover picture, provided by Rai-Shung Liu and co-workers, illustrates recent progress to implement N- and O-functionalization of alkynes with common N-O containing species including nitrone, nitroso, nitro and other nitroxy derivatives. The reported reactions include the following three topics: (i) 1,2-difunctionalizations, (ii) cyclizations and (iii) cycloaddition or annulation reactions. The review is organized according to the types of nucleophiles, followed by reactions of the types. Enantioselective functionalizations of alkynes with these nitroxy nucleophiles are included. Details can be found in the Review on pages XXXX-XXXX (D. B. Huple, S. Ghorpade, R.-S. Liu, Adv. Synth. Catal.­ 2016, 358, XXXX-XXXX; DOI: 10.1002/adsc.201600018).

    2. You have free access to this content
      Catalytic One-Pot Oxetane to Carbamate Conversions: Formal Synthesis of Drug Relevant Molecules

      Wusheng Guo, Victor Laserna, Jeroen Rintjema and Arjan W. Kleij

      Article first published online: 1 APR 2016 | DOI: 10.1002/adsc.201600298

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      The front cover picture, provided by Arjan Kleij and co-workers, illustrates oxetane-based carbamates: oxetane-based carbamate scaffolds are formed using an efficient aluminium catalyst. The process combines three reagents (CO2, oxetanes and amines) in a one-pot approach towards a wide diversity of carbamate structures. The methodology has been applied in the formal synthesis of drug-relevant molecules such as Carisoprodol and the mono-carbamate of Felbatol showing the utility of the new catalytic procedure. The work also illustrates the potential of oxetanes as versatile reagents in pharma-organic synthesis. Details can be found in the full paper on pages xxxx–xxxx (W. Guo, V. Laserna, J. Rintjema, A. W. Kleij, Adv. Synth. Catal.­ 2016, 358, xxxx–xxxx; DOI: 10.1002/adsc.201500895).

  29. Full Papers

    1. Very Important Publication

      An Improved Catalyst for Iodine(I/III)-Catalysed Intermolecular C[BOND]H Amination

      Nicola Lucchetti, Michelangelo Scalone, Serena Fantasia and Kilian Muñiz

      Article first published online: 31 MAR 2016 | DOI: 10.1002/adsc.201600191

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  30. Reviews

    1. Very Important Publication

  31. Communications

  32. Full Papers

    1. Very Important Publication

    2. Property-Guided Synthesis of Aza-Tricyclic Indolines: Development of Gold Catalysis En Route

      Patrick M. Barbour, Wei Wang, Le Chang, Kasey L. Pickard, Rana Rais, Barbara S. Slusher and Xiang Wang

      Article first published online: 3 MAR 2016 | DOI: 10.1002/adsc.201501101

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    3. Palladium-Catalyzed Tandem-Cyclization of Functionalized Ynamides: An Approach to Benzosultams

      Alla Siva Reddy, A. Leela Siva Kumari, Soumen Saha and K. C. Kumara Swamy

      Article first published online: 3 MAR 2016 | DOI: 10.1002/adsc.201500854

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    4. Hydrohydrazination of Arylalkynes Catalyzed by an Expanded Ring N-Heterocyclic Carbene (er-NHC) Gold Complex Under Solvent-Free Conditions

      Oleg S. Morozov, Pavel S. Gribanov, Andrey F. Asachenko, Pavel V. Dorovatovskii, Victor N. Khrustalev, Viktor B. Rybakov and Mikhail S. Nechaev

      Article first published online: 1 MAR 2016 | DOI: 10.1002/adsc.201500658

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    5. Very Important Publication

      Ligand Effects in the Gold Catalyzed Hydration of Alkynes

      Rene E. Ebule, Deepika Malhotra, Gerald B. Hammond and Bo Xu

      Article first published online: 22 FEB 2016 | DOI: 10.1002/adsc.201501079

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  33. Communications

  34. Full Papers

    1. Titania-Supported Gold Nanoparticles Catalyze the Selective Oxidation of Amines into Nitroso Compounds in the Presence of Hydrogen Peroxide

      Stella Fountoulaki, Petros L. Gkizis, Theodoros S. Symeonidis, Eleni Kaminioti, Athanasia Karina, Ioannis Tamiolakis, Gerasimos S. Armatas and Ioannis N. Lykakis

      Article first published online: 11 FEB 2016 | DOI: 10.1002/adsc.201500957

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    2. Very Important Publication

      A Chiral Disulfoxide Ligand for the Efficient Rhodium-Catalyzed 1,2-Addition of Arylboroxines to N-Tosylarylimines

      Guang-Zhen Zhao, Gellért Sipos, Alvaro Salvador, Arnold Ou, Pengchao Gao, Brian W. Skelton and Reto Dorta

      Article first published online: 26 JAN 2016 | DOI: 10.1002/adsc.201500975

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