Chemistry – An Asian Journal

Cover image for Vol. 9 Issue 5

Editor: Theresa Kueckmann

Impact Factor: 4.572

ISI Journal Citation Reports © Ranking: 2012: 28/152 (Chemistry Multidisciplinary)

Online ISSN: 1861-471X

Associated Title(s): Angewandte Chemie International Edition, Asian Journal of Organic Chemistry, Chemistry - A European Journal, Chinese Journal of Chemistry, Journal of the Chinese Chemical Society, The Chemical Record

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EarlyViewNew Entangled Coordination Networks Based on Charge-Tunable Keggin-Type Polyoxometalates

Xiu-Li Hao, Yuan-Yuan Ma, Yong-Hui Wang,* Long-Yang Xu, Fu-Chen Liu,* Mao-Mao Zhang, and Yang-Guang Li*

The combination of transition metal ions, bis(triazole) bridging ligands, and various charge-tunable Keggin-type polyoxometalates (POMs) led to the isolation of new entangled coordination networks. The structures of the obtained compounds vary from “zipper-closing” packing to 3D polythreading, 3D polycatenation, and 3D self-penetration, respectively. An increase in the POM negative charges not only increased the number of nodes in the coordination networks but also led to increasingly complicated basic metal–organic building motifs.

Received October 14, 2013, published online January 08, 2014, DOI: 10.1002/asia.201301378 – read now.

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