ChemSusChem

Cover image for Vol. 10 Issue 14

Editor: David Smith; Editorial Board Chairs: Matthias Beller, Gabriele Centi, Licheng Sun

Impact Factor: 7.226

ISI Journal Citation Reports © Ranking: 2016: 3/31 (Green & Sustainable Science & Technology); 22/166 (Chemistry Multidisciplinary)

Online ISSN: 1864-564X

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemCatChem, ChemElectroChem, ChemPhysChem, Energy Technology

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July 22, 2017

VIP: Comprehensive Insights into the Thermal Stability, Biodegradability, and Combustion Chemistry of Pyrrolidinium-Based Ionic Liquids

Dr. Gebrekidan Gebresilassie Eshetu, Dr. Sangsik Jeong, Dr. Pascal Pandard, Dr. Amandine Lecocq, Dr. Guy Marlair and Prof. Dr. Stefano Passerini

Comprehensive Insights into the Thermal Stability, Biodegradability, and Combustion Chemistry of Pyrrolidinium-Based Ionic Liquids

Toxic combustion: Ionic liquids (ILs), as electrolyte components for high-energy batteries, offer a series of advantages with respect to molecular, solvent-based, conventional electrolytes. A detailed investigation of the short- and long-term thermal stabilities, biodegradability, and combustion behavior of various pyrrolidinium-based ILs, with different alkyl chain lengths, counteranions, and cations, is described.

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    Accepted manuscript online: 23 JUL 2017 09:30PM EST | DOI: 10.1002/cssc.201701120

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  5. Understanding the Limiting Factors of Solvent-Annealed Small-Molecule Bulk-Heterojunction Organic Solar Cells from a Chemical Perspective

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    Version of Record online: 21 JUL 2017 | DOI: 10.1002/cssc.201700440

    Thumbnail image of graphical abstract

    Crystallite growth energetics: We give a detailed account of the limiting factors of a solvent-annealed bulk-heterojunction small-molecule organic solar cell. A mechanism for the formation of crystalline domains of donor molecules in the active layer is proposed, and microstructure features are related to the JV characteristics of the devices. The energetics of crystallite growth determine the establishment of a JV characteristics–structure relationship.

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