ChemSusChem

Cover image for Vol. 11 Issue 4

Editor: David Smith; Editorial Board Chairs: Matthias Beller, Gabriele Centi, Licheng Sun

Impact Factor: 7.226

ISI Journal Citation Reports © Ranking: 2016: 3/31 (Green & Sustainable Science & Technology); 24/166 (Chemistry Multidisciplinary)

Online ISSN: 1864-564X

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemCatChem, ChemElectroChem, ChemPhysChem, Energy Technology

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January 19, 2018

VIP: 2-(N-Methylbenzyl)pyridine: A Potential Liquid Organic Hydrogen Carrier with Fast H2 Release and Stable Activity in Consecutive Cycles

Jinho Oh, Kwanyong Jeong, Tae Wan Kim, Hyunguk Kwon, Prof. Dr. Jeong Woo Han, Dr. Ji Hoon Park and Prof. Dr. Young-Woong Suh

2-(N-Methylbenzyl)pyridine: A Potential Liquid Organic Hydrogen Carrier with Fast H2 Release and Stable Activity in Consecutive Cycles

It could've been a brilliant carrier: A new liquid organic hydrogen carrier is designed by adding N atom into the benzene ring of a benchmark heat-transfer fluid. The crossover between H2-lean and H2-rich forms of the title material is reversible in repeated runs. Notably, the reduced dehydrogenation enthalpy, owing to the presence of N, leads to very fast H2 release, indicating excellent potential for efficient H2 storage.

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Recently Published Articles

  1. Sustainable Synthesis of Oxalic and Succinic Acid through Aerobic Oxidation of C6 Polyols Under Mild Conditions

    Dr. Maria Ventura, Dr. David Williamson, Francesco Lobefaro, Matthew D. Jones, Prof. Davide Mattia, Dr. Francesco Nocito, Prof. Michele Aresta and Prof. Angela Dibenedetto

    Version of Record online: 23 FEB 2018 | DOI: 10.1002/cssc.201702347

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    Clean made easy: Aerobic oxidative cleavage of C6 polyols (5-HMF, glucose, fructose and sucrose) to oxalic acid (overall yield 48–62 %) and succinic acid was achieved in water under mild conditions using M@CNT and M@NCNT (M=Fe, V; CNT=carbon nanotubes; NCNT=N-doped CNT), which were recoverable and reusable without any loss of efficiency. This process was clean and did not produce organic waste nor gas emissions.

  2. MoS2 Quantum Dots-Modified Covalent Triazine-Based Frameworks for Enhanced Photocatalytic Hydrogen Evolution

    Qianqian Jiang, Long Sun, Prof. Jinhong Bi, Dr. Shijing Liang, Dr. Liuyi Li, Prof. Yan Yu and Prof. Ling Wu

    Version of Record online: 23 FEB 2018 | DOI: 10.1002/cssc.201702220

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    Gathering MoS2: MoS2 quantum dots (QDs)-modified covalent triazine framework (CTF) composites were synthesized by an in situ photodeposition method from a (NH4)2MoS4 precursor. The interactions between the MoS2 QDs and the CTF distinctly enhanced the photocatalytic hydrogen production under visible light irradiation.

  3. Towards High-Performance Aqueous Na-ion Batteries: Stabilizing the Solid/Liquid Interface for NASICON-Type Na2VTi(PO4)3 via the Use of Concentrated Electrolytes

    Huang Zhang, Sangsik Jeong, Bingsheng Qin, Diogo Carvalho, Daniel Buchholz and Stefano Passerini

    Accepted manuscript online: 22 FEB 2018 04:31AM EST | DOI: 10.1002/cssc.201800194

  4. Low-temperature, Low-Energy, and High-Efficiency Pretreatment Technology for Large Wood Chips with a Redox Couple Catalyst

    Dr. Parikshit Gogoi, Dr. Zhe Zhang, Zhishuai Geng, Wei Liu, Weize Hu and Prof. Yulin Deng

    Version of Record online: 21 FEB 2018 | DOI: 10.1002/cssc.201702090

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    Chip off the old block: We report a simple, effective, and low-temperature (≈100 °C) process for the pretreatment of hardwood and softwood chips directly by using a catalytic system of FeCl3/NaNO3. A conversion of 71.53 and 70.66 % of cellulose to sugar could be obtained for the direct use of large hardwood and softwood chips.

  5. Aqueous hydrogenation of levulinic acid to 1,4-pentanediol over Mo-modified Ru/AC catalyst

    Jinglei Cui, Jingjing Tan, Yulei Zhu and Fangqin Cheng

    Accepted manuscript online: 19 FEB 2018 11:21PM EST | DOI: 10.1002/cssc.201800038

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