ChemSusChem

Cover image for Vol. 9 Issue 22

Editor: David Smith; Editorial Board Chairs: Matthias Beller, Gabriele Centi, Licheng Sun

Impact Factor: 7.116

ISI Journal Citation Reports © Ranking: 2015: 2/29 (Subject); 20/163 (Chemistry Multidisciplinary)

Online ISSN: 1864-564X

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemCatChem, ChemElectroChem, ChemPhysChem, Energy Technology

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November 30, 2016

VIP: Adsorption and Reactive Desorption on Metal–Organic Frameworks: A Direct Strategy for Lactic Acid Recovery

Timothée Stassin, Dr. Helge Reinsch, Dr. Ben Van de Voorde, Dr. Stefan Wuttke, Dr. Dana D. Medina, Prof. Dr. Norbert Stock, Prof. Dr. Thomas Bein, Prof. Dr. Rob Ameloot and Prof. Dr. Dirk De Vos

Adsorption and Reactive Desorption on Metal–Organic Frameworks: A Direct Strategy for Lactic Acid Recovery

MOFs to the rescue: The current fermentative production of biomass-derived lactic acid requires a tedious, non-sustainable, multi-step separation process. The adsorption and desorption of lactic acid on high-affinity porous crystalline metal–organic frameworks opens a direct and gypsum-waste-free alternative recovery route.

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Recently Published Articles

  1. Enhancing Electrocatalytic Performance of Bifunctional Cobalt–Manganese-Oxynitride Nanocatalysts on Graphene

    Yang Li, Dr. Kurian A. Kuttiyiel, Dr. Lijun Wu, Dr. Yimei Zhu, Dr. Etsuko Fujita, Dr. Radoslav R. Adzic and Dr. Kotaro Sasaki

    Version of Record online: 5 DEC 2016 | DOI: 10.1002/cssc.201601188

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    Nitrogen makes the difference: A nitriding treatment to generate graphene-supported cobalt–manganese-oxynitride nanocatalysts (CoMnON/G) from spinel compound CoMnO increases the catalysts′ oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) activities considerably. The most active material catalyzes the ORR with only a 30 mV half-wave potential difference from the commercial carbon-supported platinum (Pt/C) in alkaline media. The catalyst also exhibits intrinsic stability that outperforms Pt/C.

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    Gastón O Larrazábal, Antonio J Martín, Frank Krumeich, Roland Hauert and Javier Pérez-Ramírez

    Accepted manuscript online: 2 DEC 2016 08:56AM EST | DOI: 10.1002/cssc.201601578

  3. Orderly layered Zr-benzylphosphonate nanohybrids for efficient acid/base-mediated bifunctional/cascade catalysis

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    Accepted manuscript online: 2 DEC 2016 07:51AM EST | DOI: 10.1002/cssc.201601570

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    Prof. Dr. Birgit Kamm, Sebastian Leiß, Petra Schönicke and Matthias Bierbaum

    Version of Record online: 2 DEC 2016 | DOI: 10.1002/cssc.201601511

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    Dilute ammonia, get more sugars: Wheat straw is first pretreated using a modified ammonia fiber expansion (AFEX) process using a diluted aqueous ammonia solution. Extracting proteins from the reaction mixture has a distinct influence on the subsequent enzymatic hydrolysis, which produces fermentable sugars. This modified AFEX process using aqueous ammonia represents a simpler and less expensive variant of the AFEX process usually described in literature.

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