ChemSusChem

Cover image for Vol. 11 Issue 1

Editor: David Smith; Editorial Board Chairs: Matthias Beller, Gabriele Centi, Licheng Sun

Impact Factor: 7.226

ISI Journal Citation Reports © Ranking: 2016: 3/31 (Green & Sustainable Science & Technology); 24/166 (Chemistry Multidisciplinary)

Online ISSN: 1864-564X

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemCatChem, ChemElectroChem, ChemPhysChem, Energy Technology

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January 19, 2018

VIP: 2-(N-Methylbenzyl)pyridine: A Potential Liquid Organic Hydrogen Carrier with Fast H2 Release and Stable Activity in Consecutive Cycles

Jinho Oh, Kwanyong Jeong, Tae Wan Kim, Hyunguk Kwon, Prof. Dr. Jeong Woo Han, Dr. Ji Hoon Park and Prof. Dr. Young-Woong Suh

2-(N-Methylbenzyl)pyridine: A Potential Liquid Organic Hydrogen Carrier with Fast H2 Release and Stable Activity in Consecutive Cycles

It could've been a brilliant carrier: A new liquid organic hydrogen carrier is designed by adding N atom into the benzene ring of a benchmark heat-transfer fluid. The crossover between H2-lean and H2-rich forms of the title material is reversible in repeated runs. Notably, the reduced dehydrogenation enthalpy, owing to the presence of N, leads to very fast H2 release, indicating excellent potential for efficient H2 storage.

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Recently Published Articles

  1. Carbon Molecular Sieve Membranes Derived from Tröger's Base-Based Microporous Polyimide for Gas Separation

    Jian Jin, Zhenggong Wang, Huiting Ren, Shenxiang Zhang and Feng Zhang

    Accepted manuscript online: 19 JAN 2018 03:30AM EST | DOI: 10.1002/cssc.201702243

  2. Deep Eutectic Solvent Aqueous Solutions as Efficient Media for the Solubilization of Hardwood Xylans

    Eduarda S. Morais, Patrícia V. Mendonça, Prof. Jorge F. J. Coelho, Dr. Mara G. Freire, Dr. Carmen S. R. Freire, Prof. João A. P. Coutinho and Prof. Armando J. D. Silvestre

    Version of Record online: 18 JAN 2018 | DOI: 10.1002/cssc.201702007

    Thumbnail image of graphical abstract

    New media provides the solution: Deep eutectic solvents formed by choline chloride and urea in aqueous solutions display excellent ability to solubilize hardwood xylans and show great potential for the extraction of these polysaccharides from hardwoods in an integrated biorefinery context.

  3. N-modified NiO Surface for Superior Alkaline Hydrogen Evolution

    Le Zhang, Peng Fei Liu, Yu Hang Li, Meng Yang Zu, Xu Li, Zheng Jiang, Yun Wang, Huijun Zhao and Huagui Yang

    Accepted manuscript online: 18 JAN 2018 07:55AM EST | DOI: 10.1002/cssc.201702371

  4. 2-(N-Methylbenzyl)pyridine: A Potential Liquid Organic Hydrogen Carrier with Fast H2 Release and Stable Activity in Consecutive Cycles

    Jinho Oh, Kwanyong Jeong, Tae Wan Kim, Hyunguk Kwon, Prof. Dr. Jeong Woo Han, Dr. Ji Hoon Park and Prof. Dr. Young-Woong Suh

    Version of Record online: 18 JAN 2018 | DOI: 10.1002/cssc.201702256

    Thumbnail image of graphical abstract

    It could've been a brilliant carrier: A new liquid organic hydrogen carrier is designed by adding N atom into the benzene ring of a benchmark heat-transfer fluid. The crossover between H2-lean and H2-rich forms of the title material is reversible in repeated runs. Notably, the reduced dehydrogenation enthalpy, owing to the presence of N, leads to very fast H2 release, indicating excellent potential for efficient H2 storage.

  5. Bismuth Vanadate Photoelectrodes with High Photovoltage as Photoanode and Photocathode in Photoelectrochemical Cells for Water Splitting

    Dr. Wayler S. dos Santos, Dr. Mariandry Rodriguez, Júlia M. O. Khoury, Luíza A. Nascimento, Rebecca J. P. Ribeiro, Prof. Dr. João P. Mesquita, Prof. Dr. Adilson C. Silva, Prof. Dr. Francisco G. E. Nogueira and Prof. Márcio C. Pereira

    Version of Record online: 17 JAN 2018 | DOI: 10.1002/cssc.201701929

    Thumbnail image of graphical abstract

    Danger! High voltage: Dual-photoelectrode photoelectrochemical (PEC) devices based on earth-abundant metal oxides are an attractive means of producing green H2 by water splitting. A dual-photoelectrode PEC cell, incorporating a 1 mol % W-doped BiVO4/Bi4V2O11 photoanode and an undoped BiVO4/Bi4V2O11 photocathode, generates photovoltages of 1.54 V to drive unassisted water splitting with 0.95 % efficiency.

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