ChemSusChem

Cover image for Vol. 9 Issue 22

Editor: David Smith; Editorial Board Chairs: Matthias Beller, Gabriele Centi, Licheng Sun

Impact Factor: 7.116

ISI Journal Citation Reports © Ranking: 2015: 2/29 (Subject); 20/163 (Chemistry Multidisciplinary)

Online ISSN: 1864-564X

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal, Chemistry – An Asian Journal, ChemCatChem, ChemElectroChem, ChemPhysChem, Energy Technology

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November 30, 2016

VIP: Adsorption and Reactive Desorption on Metal–Organic Frameworks: A Direct Strategy for Lactic Acid Recovery

Timothée Stassin, Dr. Helge Reinsch, Dr. Ben Van de Voorde, Dr. Stefan Wuttke, Dr. Dana D. Medina, Prof. Dr. Norbert Stock, Prof. Dr. Thomas Bein, Prof. Dr. Rob Ameloot and Prof. Dr. Dirk De Vos

Adsorption and Reactive Desorption on Metal–Organic Frameworks: A Direct Strategy for Lactic Acid Recovery

MOFs to the rescue: The current fermentative production of biomass-derived lactic acid requires a tedious, non-sustainable, multi-step separation process. The adsorption and desorption of lactic acid on high-affinity porous crystalline metal–organic frameworks opens a direct and gypsum-waste-free alternative recovery route.

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Recently Published Articles

  1. “Practical” Electrospinning of Biopolymers in Ionic Liquids

    Dr. Julia L. Shamshina, Dr. Oleksandra Zavgorodnya, Jonathan R. Bonner, Dr. Gabriela Gurau, Thomas Di Nardo and Prof. Robin D. Rogers

    Version of Record online: 6 DEC 2016 | DOI: 10.1002/cssc.201601372

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    Spinning round and round: A setup for multi-needle electrospinning of the biopolymer chitin using the ionic liquid 1-ethyl-3-methylimidazolium acetate is developed to realize electrospinning on a large scale. Biopolymers are relevant as a sustainable platform to potentially replace synthetic, non-biodegradable plastics. The scale-up of electrospinning from ionic liquids, which is demonstrated for chitin and shows potential for satisfying some requirements of industrial production, can be applied for virtually any biopolymer soluble in ionic liquids.

  2. Origin of the Excellent Performance of Ru on Nitrogen-Doped Carbon Nanofibers for CO2 Hydrogenation to CH4

    Dr. Laura Roldán, Yanila Marco and Dr. Enrique García-Bordejé

    Version of Record online: 6 DEC 2016 | DOI: 10.1002/cssc.201601217

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    Another use for C supports: Ru nanoparticles supported on nitrogen-doped carbon nanofibers provide competitive CH4 production rate and stability compared to Al2O3 supported catalysts thanks to its ability to store the highest amount of chemisorbed CO species among the different tested catalysts.

  3. A robust molecular catalyst generated in-situ for photo- and electrochemical water oxidation

    Hussein A. Younus, Nazir Ahmad, Adeel H. Chughtai, Matthias Vandichel, Michael Busch, Kristof Van Hecke, Mekhman Yusubov, Shaoxian Song and Francis Verpoort

    Accepted manuscript online: 5 DEC 2016 11:15PM EST | DOI: 10.1002/cssc.201601477

  4. High performance porphyrin-based dye-sensitized solar cells with both iodine and cobalt redox shuttles

    Huaide Xiang, Wei Fan, Jiahui Li, Tianyue Li, Neil Robertson, Xiongrong Song, Wenjun Wu, Zhaohui Wang, Weihong Zhu and He Tian

    Accepted manuscript online: 5 DEC 2016 11:21AM EST | DOI: 10.1002/cssc.201601617

  5. Enhancing Electrocatalytic Performance of Bifunctional Cobalt–Manganese-Oxynitride Nanocatalysts on Graphene

    Yang Li, Dr. Kurian A. Kuttiyiel, Dr. Lijun Wu, Dr. Yimei Zhu, Dr. Etsuko Fujita, Dr. Radoslav R. Adzic and Dr. Kotaro Sasaki

    Version of Record online: 5 DEC 2016 | DOI: 10.1002/cssc.201601188

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    Nitrogen makes the difference: A nitriding treatment to generate graphene-supported cobalt–manganese-oxynitride nanocatalysts (CoMnON/G) from spinel compound CoMnO increases the catalysts′ oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) activities considerably. The most active material catalyzes the ORR with only a 30 mV half-wave potential difference from the commercial carbon-supported platinum (Pt/C) in alkaline media. The catalyst also exhibits intrinsic stability that outperforms Pt/C.

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