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Editor-in-Chief: Guido Kemeling; Editorial Board Chairs: Matthias Beller, Gabriele Centi, Licheng Sun
Impact Factor: 7.657
ISI Journal Citation Reports © Ranking: 2014: 18/157 (Chemistry Multidisciplinary)
Online ISSN: 1864-564X
May 26, 2016
VIP: Nature-Inspired Design of Artificial Solar-to-Fuel Conversion Systems based on Copper Phosphate Microflowers
Flower power: Phosphates play an important role in photosynthesis by mediating electron transport and furnishing energy for CO2 reduction. Mimicking plant photosynthesis, an artificial solar-to-fuel conversion system composed of versatile copper phosphate microflowers and titanium dioxide nanoparticles is shown to enhance hydrogen generation by photocatalytic water splitting.
Recently Published Articles
- Conversion of raw lignocellulosic biomass into branched long-chain alkanes through three tandem steps
Chunrui Li, Daqian Ding, Qineng Xia, Xiaohui Liu and Prof. Yanqin Wang
Version of Record online: 31 MAY 2016 | DOI: 10.1002/cssc.201600386
Woody′s three steps to glory: Synthesis of branched long-chain alkanes from renewable biomass has attracted considerable interest in recent years, but the feedstock for this synthesis is usually restricted to platform chemicals. We develop an effective and energy-efficient process to directly convert raw lignocellulosic biomass (e.g., corncob) into branched diesel-range alkanes using three tandem steps without having to purify the compounds between steps.
- Alternative Single-Solvent Electrolytes Based on Cyanoesters for Safer Lithium-Ion Batteries
Sebastian Brox, Dr. Stephan Röser, Tamara Husch, Stephan Hildebrand, Olga Fromm, Prof. Dr. Martin Korth, Prof. Dr. Martin Winter and Dr. Isidora Cekic-Laskovic
Version of Record online: 30 MAY 2016 | DOI: 10.1002/cssc.201600369
From sketchbook to safer electrolytes: Different cyanoester molecules are first screened using selected computational simulations and afterwards thoroughly investigated with regard to their physicochemical and electrochemical properties. The best candidate, methyl 3-cyanopropanoate, proves to be a viable alternative solvent for lithium-ion batteries. Results obtained by means of adiabatic rate calorimetry indicate a high thermal safety.
- Dependence of Excited-State Properties of a Low-Bandgap Photovoltaic Copolymer on Side-Chain Substitution and Solvent
Ning-Jiu Zhao, Dr. Mao-Jie Zhang, Dr. Ran Liang, Dr. Li-Min Fu, Dr. Wei Zhang, Prof. Xi-Cheng Ai, Prof. Jian-Hui Hou and Prof. Jian-Ping Zhang
Version of Record online: 25 MAY 2016 | DOI: 10.1002/cssc.201501690
Structure–property relationships: A photovoltaic donor–acceptor copolymer that contains meta-alkoxyphenyl groups is studied using spectroscopy and quantum chemical calculations to provide information on the charge photogeneration dynamics. The alkoxyphenyl substituent impacts the triplet formation and main chain conformation directly.
- Characterization of Platinum and Iridium Oxyhydrate Surface Layers from Platinum and Iridium Foils
Benjamin Johnson, Dr. Chinmoy Ranjan, Dr. Mark Greiner, Dr. Rosa Arrigo, Dr. Manfred Erwin Schuster, Dr. Britta Höpfner, Dr. Mihaela Gorgoi, Dr. Iver Lauermann, Dr. Marc Willinger, Dr. Axel Knop-Gericke and Prof. Robert Schlögl
Version of Record online: 25 MAY 2016 | DOI: 10.1002/cssc.201600143
Oxidized foils: Platinum and iridium polycrystalline foils are oxidized electrochemically through anodization to create thin platinum and iridium hydrous oxide layers, which are analyzed through X-ray photoelectron spectroscopy. The complexity of such hydrous oxide systems is discussed in detail.
- Synthesis of 2-Butanol by Selective Hydrogenolysis of 1,4-Anhydroerythritol over Molybdenum Oxide-Modified Rhodium-Supported Silica
Takahiro Arai, Dr. Masazumi Tamura, Dr. Yoshinao Nakagawa and Prof. Keiichi Tomishige
Version of Record online: 25 MAY 2016 | DOI: 10.1002/cssc.201600295
New route to 2-butanol: Transformation of biomass-derived chemicals to value-added chemicals is important from the viewpoints of green sustainable chemistry, and hence, development of new catalysts is important. Rh-MoOx/SiO2 (Mo/Rh=0.13) is an effective heterogeneous catalyst for the hydrogenolysis of 1,4-anhydroerythritol to 2-butanol. 1,4-Anhydroerythritol is a more suitable starting material than erythritol in terms of 2-butanol yield.