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Editor: Michael Rowan; Editorial Board Chairs: Uwe Bornscheuer, Luis A. Oro, Bert Weckhuysen
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Online ISSN: 1867-3899
March 24, 2015
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Recently Published Articles
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Mathias Pickl, Dr. Michael Fuchs, Dr. Silvia M. Glueck and Prof. Dr. Kurt Faber
Article first published online: 3 SEP 2015 | DOI: 10.1002/cctc.201500589
Five enzymes are better than one: Biocatalytic amination of ω-functionalized (fatty) primary alcohols is achieved, with up to >99 % conversion, by means of a one-pot cascade reaction that employs a long-chain alcohol oxidase and a transaminase.
- An Eco-friendly Soft Template Synthesis of Mesostructured Silica-Carbon Nanocomposites for Acid Catalysis
Ruyi Zhong, Li Peng, Filip de Clippel, Cedric Gommes, Bart Goderis, Xiaoxing Ke, Gustaaf Van Tendeloo, Pierre A. Jacobs and Bert F. Sels
Article first published online: 3 SEP 2015 | DOI: 10.1002/cctc.201500728
Tintin and the sulfurous nanocatalysts: Sulfonic acid groups can be readily introduced to mesostructured silica-carbon nanocatalysts to reveal excellent acid-catalytic activities and selectivities for the dimerization of styrene to produce 1,3-diphenyl-1-butene and the dimerization of α-methylstyrene.
- Allenic Esters from Cyclopropenones by Lewis Base Catalysis: Substrate Scope, the Asymmetric Variant from the Dynamic Kinetic Asymmetric Transformation, and Mechanistic Studies
Dr. Yin Wei, Wen-Tao Zhao, Dr. Yuan-Liang Yang, Dr. Zhen Zhang and Prof. Dr. Min Shi
Article first published online: 3 SEP 2015 | DOI: 10.1002/cctc.201500466
Axially chiral allenes: The reactions of cyclopropenones with a variety of nucleophiles are catalyzed by different Lewis bases, affording the allenic esters in moderate to excellent yields. Axially chiral allenes are given in moderate to good yields and ee values, catalyzed by multifunctional chiral phosphines in a dynamic kinetic asymmetric transformation. The reaction mechanism is disclosed through NMR tracing experiments, MS, and DFT calculations. CP*=Chiral phosphine.
- You have free access to this contentCarbon in the Catalysis Community
Prof. An-Hui Lu and Prof. Xinhe Bao
Article first published online: 3 SEP 2015 | DOI: 10.1002/cctc.201500953
Dedication to carbon: There are a tremendous number of research projects on carbon, many of which extend into different catalysis fields. The roles of carbon cover many aspects from feedstock, catalysts, catalyst supports and reaction media and it is involved in a range of reactions including organic synthesis, biomass conversion, electrocatalysis, photocatalysis and energy conversion.
- Catalytic Semireduction of Internal Alkynes with All-Metal Aromatic Complexes
Pierre-Alexandre Deyris, Dr. Tatiana Cañeque, Dr. Yanlan Wang, Pascal Retailleau, Prof. Franca Bigi, Prof. Raimondo Maggi, Dr. Giovanni Maestri and Prof. Max Malacria
Article first published online: 3 SEP 2015 | DOI: 10.1002/cctc.201500729
Full metal jacket: We report the application of all-metal aromatic frameworks as complexes in catalytic reactions. Suitable C3 symmetric, 44 core valence electrons, triangular Pd clusters are efficient precatalysts for the semihydrogenation of alkynes to (Z)-alkenes. These reactions proceed under mild conditions and show complete chemoselectivity for the reduction of CC bonds.