© WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Editor: Michael Rowan; Editorial Board Chairs: Uwe Bornscheuer, Luis A. Oro, Bert Weckhuysen
Impact Factor: 4.556
ISI Journal Citation Reports © Ranking: 2014: 31/139 (Chemistry Physical)
Online ISSN: 1867-3899
March 24, 2015
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Recently Published Articles
- Design of Artificial Metabolisms in Layered Nanomaterials for the Enzymatic Synthesis of Phosphorylated Sugars
Rima Mahdi, Dr. Christine Guérard-Hélaine, Dr. Vanessa Prévot, Dr. Véronique de Berardinis, Prof. Claude Forano and Prof. Marielle Lemaire
Article first published online: 1 SEP 2015 | DOI: 10.1002/cctc.201500606
Between the layers: We describe the design of an artificial metabolism by using enzymes co-immobilized in layered double hydroxides. The constructed nano-bioreactors are proven efficient in biocatalysis and are reusable. Dihydroxyacetone phosphate (DHAP) and C5- and C6-phosphorylated sugars are synthesized with these original biohybrids. AD(T)P=adenosine di(tri)phosphate; PEP=phosphoenolpyruvate.
- You have full text access to this OnlineOpen articleX-ray Fluorescence Tomography of Aged Fluid-Catalytic-Cracking Catalyst Particles Reveals Insight into Metal Deposition Processes
Sam Kalirai, Dr. Ulrike Boesenberg, Dr. Gerald Falkenberg, Dr. Florian Meirer and Prof. Dr. Bert M. Weckhuysen
Article first published online: 1 SEP 2015 | DOI: 10.1002/cctc.201500710
Cracking analysis: Complete Fluid-Catalytic-Cracking catalyst particles can be mapped by using X-ray micro-fluorescence tomography, revealing distribution and correlation of multiple elements. This provides insight into the deposition mechanisms of poison metals onto genuine industrial catalysts.
- Copper Nanoparticles Stabilized in a Porous Chitosan Aerogel as a Heterogeneous Catalyst for CS Cross-coupling
Sana Frindy, Prof. Abdelkrim el Kadib, Prof. Mohamed Lahcini, Dr. Ana Primo and Prof. Hermenegildo García
Article first published online: 1 SEP 2015 | DOI: 10.1002/cctc.201500565
Something fishy going on: The fibrils of chitosan, a natural polysaccharide from crustacean skins, define macropores in which Cu nanoparticles are stabilized, and the resulting solid promotes the reaction of thiophenol and iodobenzene.
- Identification of Active and Spectator Sn Sites in Sn-β Following Solid-State Stannation, and Consequences for Lewis Acid Catalysis
Dr. Ceri Hammond, Daniele Padovan, Abbas Al-Nayili, Dr. Peter. P. Wells, Dr. Emma K. Gibson and Dr. Nikolaos Dimitratos
Article first published online: 1 SEP 2015 | DOI: 10.1002/cctc.201500545
Site dependency: The solid-state stannation of zeolite beta leads to the formation of framework-substituted SnIV sites between loadings of 1 and 5 wt %, but may also lead to mixed Sn populations above these loadings. The consequences of this mixed population with regards to the catalytic reactions are identified.
- Preparation of Nickel Phosphide Hydrodesulfurization Catalysts Assisted by Supercritical Carbon Dioxide
Dr. Blanca Motos-Pérez, Dr. Denis Uzio and Dr. Cyril Aymonier
Article first published online: 1 SEP 2015 | DOI: 10.1002/cctc.201500755
A supercritical situation: A supercritical carbon dioxide (scCO2)-assisted method is developed to prepare silica-supported Ni2P nanoparticles. Flash injection and thermal decomposition of the precursors in scCO2 control the formation of the Ni2P active phase. Variation of the phosphorous precursors and the temperature allows modulating properties such as particle-size distribution and catalytic activity. Great results are observed for hydrodesulfurization (HDS).