© WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Editor: Michael Rowan; Editorial Board Chairs: Uwe Bornscheuer, Luis A. Oro, Bert Weckhuysen
Impact Factor: 4.556
ISI Journal Citation Reports © Ranking: 2014: 31/139 (Chemistry Physical)
Online ISSN: 1867-3899
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March 24, 2015
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Recently Published Articles
- Electrocatalytic Performance of High-Surface-Area Platinum Catalysts Synthesized by Chemical Vapor Deposition for Water Splitting
Joachim Klett, Andreas Eva, Frederick Heinz, Dr. Bernhard Kaiser, Prof. Wolfram Jaegermann and Prof. Rolf Schäfer
Article first published online: 24 NOV 2015 | DOI: 10.1002/cctc.201501012
It’s electrifying! The deposition of Pt particles and films by chemical vapor deposition from platinum(II) acetylacetonate for electrochemical water splitting is presented. High-surface-area particles are obtained at substrate temperatures as low as 150 °C by this technique. Although oxygen leads to a crystalline film growth, hydrogen leads to an open structure of stacked Pt spheres showing small overvoltages for the hydrogen evolution reaction.
- Highly Efficient Hybrid Cobalt–Copper–Aluminum Layered Double Hydroxide/Graphene Nanocomposites as Catalysts for the Oxidation of Alkylaromatics
Dr. Renfeng Xie, Dr. Guoli Fan, Prof. Lan Yang and Prof. Feng Li
Article first published online: 24 NOV 2015 | DOI: 10.1002/cctc.201500890
Mega results for nanocomposites: The liquid-phase selective oxidation of alkylaromatics is conducted successfully on well-dispersed hybrid Co–Cu–Al layered double hydroxide/graphene nanocomposites, which show an excellent catalytic performance attributable to the synergy between the active Co–Cu–Al layered double hydroxide component and the graphene matrix in the unique hetero-nanostructure of the nanocomposites.
- Ruthenium and Formic Acid Based Tandem Catalytic Transformation of Bioderived Furans to Levulinic Acid and Diketones in Water
Ambikesh D. Dwivedi, Kavita Gupta, Deepika Tyagi, Rohit K. Rai, Dr. Shaikh M. Mobin and Dr. Sanjay K. Singh
Article first published online: 23 NOV 2015 | DOI: 10.1002/cctc.201501021
Ru and formic acid cooperation: Efficient water-based tandem catalytic transformations of bioderived furans to value-added levulinic acid and diketones were successfully achieved by using a system of highly active water-soluble arene–ruthenium homogeneous catalysts containing simple ethylenediamine-based ligands, and tuning the formic acid concentration. A mechanistic study revealed significant cooperation between the ruthenium catalyst and formic acid, as neither of the individual components alone can facilitate this reaction.
- Ceria-Containing Ordered Mesoporous Silica: Synthesis, Properties, and Applications
Dr. Nabanita Pal, Dr. Eun-Bum Cho, Dr. Astam K. Patra and Prof. Dr. Dukjoon Kim
Article first published online: 23 NOV 2015 | DOI: 10.1002/cctc.201500780
Materials for sustainable chemistry: Advanced mesoporous materials are set to be the next generation of catalysts. This contribution discusses the synthesis and functionalization of mesoporous ceria–silica materials and their wide range of catalytic applications in organic synthesis, electrocatalysis, bio-fuel, environmental cleaning, and photocatalysis.
- Selectivity Studies Towards the Synthesis of Novel Biaryl Ureas by (Hetero)Nanocatalysis: Size Control and Support Effects
Prof. Jaqueline D. Senra, Dr. Gil M. Viana, Prof. Luiz Fernando B. Malta, Prof. Alessandro B. C. Simas and Prof. Lucia C. S. Aguiar
Article first published online: 23 NOV 2015 | DOI: 10.1002/cctc.201500889
Nanoparticle urea synthesis: Palladium nanoparticles (PdNPs) stabilized by different cyclodextrins (CDs) are used as catalysts for the synthesis of novel biaryl ureas, high-value precursors of pharmaceuticals and supramolecular hosts. The catalytic results showed that particle sizes were not decisive, in contrast to the size of glyconanocavities. The catalytic results were improved by using a heterogeneous approach involving Pd-CD@doped ceria.