ChemCatChem

Cover image for Vol. 9 Issue 13

Editor: Michael Rowan; Editorial Board Chairs: Uwe Bornscheuer, Hermenegildo García, A. Stephen K. Hashmi

Impact Factor: 4.803

ISI Journal Citation Reports © Ranking: 2016: 29/145 (Chemistry Physical)

Online ISSN: 1867-3899

Associated Title(s): Advanced Synthesis & Catalysis, Angewandte Chemie International Edition, Chemistry - A European Journal, ChemBioChem, ChemElectroChem, ChemPhotoChem, ChemPhysChem, ChemSusChem

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August 10, 2016

ChemCatChem Board Members receive Catalysis Awards

Two ChemCatChem board members have received prestigious awards at the 16th International Congress on Catalysis (ICC) in Beijing, P.R. China. Dr. David Farrusseng, IRCE Lyon, CNRS, (France) has received the International Catalysis Award 2016. He presented a Plenary Lecture entitled "Catalysis Inside a Box" at the ICC.

Prof. Paolo Fornasiero, University of Trieste (Italy) has received the Heinz Heinemann Award 2016. He presented a Plenary Lecture entitled "Hybrid Nanocatalysts for Energy Related Applications" at the ICC.

We congratulate both of them and thank them for their support!

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Recently Published Articles

  1. Palladium Copper Chromium Ternary Nanoparticles Constructed In situ within a Basic Resin: Enhanced Activity in the Dehydrogenation of Formic Acid

    Prof. Dr. Kohsuke Mori, Kohei Naka, Shinya Masuda, Kohei Miyawaki and Prof. Dr. Hiromi Yamashita

    Version of Record online: 24 JUL 2017 | DOI: 10.1002/cctc.201700595

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    Three's a crowd: PdCuCr ternary nanoparticles constructed in situ within a macroreticular basic resin act as a simple and efficient heterogeneous catalyst for the dehydrogenation of formic acid.

  2. Iron and Cobalt Corroles in Solution and on Carbon Nanotubes as Molecular Photocatalysts for Hydrogen Production by Water Reduction

    Dr. Miguel A. Morales Vásquez, Dr. Mariana Hamer, Dr. Nicolás I. Neuman, Dr. Alvaro Y. Tesio, Dr. Andrés Hunt, Dr. Horacio Bogo, Dr. Ernesto J. Calvo and Dr. Fabio Doctorovich

    Version of Record online: 24 JUL 2017 | DOI: 10.1002/cctc.201700349

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    Tubular potential: Cobalt and iron corrole complexes have been used as catalysts of H2O reduction to generate H2. Electro- and photocatalysis of water reduction occurred with dissolved corroles. Carbon nanotubes doped with corroles were used as photo-electrochemical catalysts with increased hydrogen production. The catalytic efficiency increased by five orders of magnitude if the molecular catalysts were adsorbed onto the carbon nanotubes.

  3. A Continuous-Flow Process for Palladium-Catalyzed Olefin Cleavage by using Oxygen within the Explosive Regime

    Dr. Christopher A. Hone, Anne O'Kearney-McMullan, Dr. Rachel Munday and Prof. Dr. C. Oliver Kappe

    Version of Record online: 24 JUL 2017 | DOI: 10.1002/cctc.201700671

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    On break: The development of a continuous-flow protocol for Pd-catalyzed olefin cleavage by using molecular oxygen as the sole oxidant to give carbonyl compounds is described. The applicability of the continuous-flow protocol is demonstrated on several olefin substrates. The continuous-flow process enables safe and scalable olefin cleavage by using pure O2. MFC= mass-flow controller, PTSA=p-toluenesulfonic acid, PEG400=poly(ethylene glycol) 400, 1 bar=0.1 MPa.

  4. One-Pot Biocatalytic Double Oxidation of α-Isophorone for the Synthesis of Ketoisophorone

    Michele Tavanti, Dr. Fabio Parmeggiani, Dr. J. Rubén Gómez Castellanos, Prof. Andrea Mattevi and Prof. Nicholas J. Turner

    Version of Record online: 24 JUL 2017 | DOI: 10.1002/cctc.201700620

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    Design of an enzymatic cascade: For the first biocatalytic one-pot double oxidation of α-isophorone to ketoisophorone, variants of the self-sufficient P450cam-RhFRed with improved activity are combined with Cm-ADH10 from Candida magnoliae. The reaction shows a productivity of up to 1.4 g L−1 d−1.

  5. Direct Insight into Ethane Oxidative Dehydrogenation over Boron Nitrides

    Dr. Rui Huang, Dr. Bingsen Zhang, Jia Wang, Dr. Kuang-Hsu Wu, Wen Shi, Yajie Zhang, Dr. Yuefeng Liu, Prof. Anmin Zheng, Prof. Robert Schlögl and Prof. Dang Sheng Su

    Version of Record online: 24 JUL 2017 | DOI: 10.1002/cctc.201700725

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    DOS and don'ts of dehydrogenation: In the dehydrogenation of alkanes, conventional metal-based catalysts enable the dissociation of O2 into dissociative oxygen species (DOS), and thereby the C−H bonds can be easily activated; however, DOS inevitably overoxidize the alkanes to CO2. Adsorbed O2 at the edges of boron nitride can abstract a hydrogen atom from ethane to deliver the corresponding alkene with 100 % selectivity (S).

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