© WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Editor: Michael Rowan; Editorial Board Chairs: Uwe Bornscheuer, Luis A. Oro, Bert Weckhuysen
Impact Factor: 4.556
ISI Journal Citation Reports © Ranking: 2014: 31/139 (Chemistry Physical)
Online ISSN: 1867-3899
March 24, 2015
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Recently Published Articles
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Prof. Dr. Yiguo Su, Junyu Lang, Prof. Dr. Chunfang Du, Dr. Fenggang Bian and Prof. Dr. Xiaojing Wang
Article first published online: 2 JUL 2015 | DOI: 10.1002/cctc.201500128
In short order: A short-ordered NaxTaOy⋅n H2O catalyst exhibits exceptional and efficient photocatalytic reactivity toward aerobic oxidation. The results discovered in this study may help to develop novel short-ordered catalytic systems with better photocatalytic properties. SR-WAXS=synchrotron radiation wide-angle X-ray scattering.
- Computational Investigation on the Mechanism of Amide Bond Formation by using Phosphine-Based Redox Catalysis
Dr. Emanuela Di Santo, Dr. Marta E. Alberto, Prof. Nino Russo and Prof. Marirosa Toscano
Article first published online: 2 JUL 2015 | DOI: 10.1002/cctc.201500209
Going around in circles: The catalytic cycle of the phosphine-catalyzed Staudinger ligation of benzoic acid and benzyl azide involves several steps. All of them are explored at the density functional level. The results confirm the involvement of a phosphonium intermediate that is crucial to activate the carboxylate for nucleophilic acyl substitution.
- You have free access to this contentPalladium Catalysis: A Special Issue Aiming to Cross Borders
Dr. Mario Pagliaro and Prof. Paolo Fornasiero
Article first published online: 2 JUL 2015 | DOI: 10.1002/cctc.201500620
Special Issue Editorial: Palladium-catalyzed reactions are now routinely employed by industry to make valued drugs, synthons, liquid crystals, polymer precursors, fragrances, hormones, and many other valued chemical products. This special issue is dedicated to palladium-catalysis research.
- A Metallosalen-based Porous Organic Polymer for Olefin Epoxidation
Tao-Tao Liu, Zu-Jin Lin, Peng-Chao Shi, Tao Ma, Yuan-Biao Huang and Rong Cao
Article first published online: 2 JUL 2015 | DOI: 10.1002/cctc.201500374
Salen POP: A new salen-(Mn)-based porous organic polymer (Mn-POP) was synthesized by Sonogashira–Hagihara reaction. Further olefin epoxidation experiments proved that Mn-POP is a good solid catalyst for olefin epoxidation with high activity (up to 99 % conversion) and excellent selectivity (up to 96 %) when O2 acts as oxidizer. Mn-POP catalyst is easily recoverable and can be reused for at least five times without loss of activity and selectivity.
- N-Heterocyclic Carbene–Pd Polymers as Reusable Precatalysts for Cyanation and Ullmann Homocoupling of Aryl Halides: The Role of Solvent in Product Distribution
Prof. Dr. Babak Karimi, Dr. Majid Vafaeezadeh and Dr. Pari Fadavi Akhavan
Article first published online: 1 JUL 2015 | DOI: 10.1002/cctc.201500383
Switch the solvent: An NHC-Pd polymer with an N-dodecyl group was found to be a highly efficient and recyclable catalyst for cyanation and the Ullmann homocoupling reaction. The employed solvent exhibited a critical influence in the product distribution.