© WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Editor: Michael Rowan; Editorial Board Chairs: Uwe Bornscheuer, Luis A. Oro, Bert Weckhuysen
Impact Factor: 4.724
ISI Journal Citation Reports © Ranking: 2015: 29/144 (Chemistry Physical)
Online ISSN: 1867-3899
March 24, 2015
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Recently Published Articles
- Reduced Graphene Oxide as a Metal-Free Catalyst for the Light-Assisted Fenton-Like Reaction
Juan C. Espinosa, Dr. Sergio Navalón, Prof. Mercedes Álvaro and Prof. Hermenegildo García
Version of Record online: 22 JUL 2016 | DOI: 10.1002/cctc.201600364
Radical idea: Reduced graphene oxide acts as photo-Fenton catalyst to generate hydroxyl radicals from H2O2 upon sunlight irradiation.
- Design of Raspberry-Shaped Microcarriers with Adjustable Protrusions and Functional Groups for the Improvement of Lipase Immobilization and Biocatalysis: Environmentally Friendly Esterification of Oleic Acid for Biodiesel
Lei Tian, Panpan Zhao, Xue Li, Zafar Ali, Xiangjie Li, Baoliang Zhang, Hepeng Zhang and Prof. Qiuyu Zhang
Version of Record online: 22 JUL 2016 | DOI: 10.1002/cctc.201600413
Raspberry ripple: Raspberry-shaped microparticles with adjustable protrusions are designed and synthesized for lipase immobilization. Herein, we show that (1) the protrusion of the structure plays the role of a spacer arm; (2) carboxylic acid activation is beneficial to improve the immobilized lipase; (3) an eco-friendly and highly efficient biocatalytic process for the esterification of oleic acid for biodiesel under mild conditions can be developed.
- Copper-Catalyzed Skeletal Rearrangement of O-Propargyl Oximes: A Mechanistic Manifold
Marta González Comesaña, Prof. Dr. Olalla Nieto Faza, Prof. Dr. María Magdalena Cid and Prof. Dr. Carlos Silva López
Version of Record online: 22 JUL 2016 | DOI: 10.1002/cctc.201600473
Skeleton in the closet: The Cu-mediated skeletal rearrangement of O-propargyl oximes features a mechanistic manifold that yields different compounds. Strategic modification of the substituent at the oxime moiety (R3) allows the selection of a preferred mechanistic route that leads to azete oxides/amidodienes (if R3 is an electron-poor/-rich aryl group) or to pyridine N-oxides (if R3 is an olefin). In the present work, we explore the mechanism that leads to each product.
- Novel (−)-β-Pinene-Derived Triazolium Salts: Synthesis and Application in the Asymmetric Stetter Reaction
Dr. Zbigniew Rafiński
Version of Record online: 21 JUL 2016 | DOI: 10.1002/cctc.201600498
Dual enantioselective control: Pseudoenantiomeric triazolium salts prepared from a single precursor, (−)-β-pinene, promote opposite enantiofacial selectivity in the intramolecular Stetter reaction to afford the desired products in excellent yields with excellent stereoselectivity.
- Sulfoxide-Chelated Ruthenium Benzylidene Catalyst: a Synthetic Study on the Utility of Olefin Metathesis
Karolina Żukowska, Łukasz Pączek and Prof. Karol Grela
Version of Record online: 21 JUL 2016 | DOI: 10.1002/cctc.201600538
A new industry's darling? The stable and universal sulfoxide-chelated ruthenium olefin metathesis catalyst [RuCl2(SIMes)(=CH−C6H4−S(O)Ph)] is introduced and its application profile in metathesis with respect to relevant target natural compounds studied. The catalyst offers great functional group tolerance, compatibility with multiple solvents, and air and moisture stability.