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Editor: Michael Rowan; Editorial Board Chairs: Uwe Bornscheuer, Luis A. Oro, Bert Weckhuysen
Impact Factor: 4.556
ISI Journal Citation Reports © Ranking: 2014: 31/139 (Chemistry Physical)
Online ISSN: 1867-3899
March 24, 2015
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Recently Published Articles
- Performance of Recombinant-Whole-Cell-Catalyzed Reductions in Deep-Eutectic-Solvent–Aqueous-Media Mixtures
Christoph R. Müller, Iván Lavandera, Vicente Gotor-Fernández and Pablo Domínguez de María
Article first published online: 31 JUL 2015 | DOI: 10.1002/cctc.201500428
DESirable biocatalysis: Several enzymes, like Ralstonia sp. alcohol dehydrognase (RasADH) overexpressed in Escherichia coli, remain active for the stereoselective reduction of ketones in various deep-eutectic-solvents (DES)–buffer solutions. Furthermore, the ee values obtained for a broad range of aromatic substrates increase significantly if the DES mixture is added.
- An Empirical Study of Phosphine Ligands for the Methoxycarbonylation of Medium-Chain Alkenes
Prof. Cedric Holzapfel and Dr. Tyler Bredenkamp
Article first published online: 31 JUL 2015 | DOI: 10.1002/cctc.201500464
The cat’s out of the bag: A comparative study of various phosphine ligands is undertaken to discern the necessary requirements for a suitable catalyst for the methoxycarbonylation of higher aliphatics. Our findings demonstrate that a number of ligand structural motifs can facilitate the reaction effectually and that the most promising ligands bear one bulky electron-rich P atom and one bulky electron-poor P atom, demonstrating a catopdative-like effect.
- Highly Active and Stable Palladium Nanoparticles Encapsulated in a Mesoporous Silica Yolk–Shell Nanoreactor for Suzuki–Miyaura Reactions
Fang Wei, Dr. Changyan Cao, Yongbin Sun, Shuliang Yang, Peipei Huang and Prof. Dr. Weiguo Song
Article first published online: 29 JUL 2015 | DOI: 10.1002/cctc.201500600
Core catalysis: A yolk–shell nanoreactor with nitrogen-doped carbon spheres as the yolk and mesoporous silica (mSiO2) as the shell, together with Pd nanoparticles uniformly encapsulated in the void space, showed excellent catalytic activity and stability in the Suzuki–Miyaura reaction. CTAB=Hexadecyl trimethyl ammonium bromide, PDA=Polydopamine, TEOS=Tetraethyl orthosilicate.
- Enhancement of Photoelectrochemical Performance in Water Oxidation over Bismuth Vanadate Photoanodes by Incorporation with Reduced Graphene Oxide
Yingfei Hu, Yao Su, Huiting Huang, Qinfeng Qian, Zhongjie Guan, Dr. Jianyong Feng, Prof. Zhaosheng Li and Prof. Zhigang Zou
Article first published online: 29 JUL 2015 | DOI: 10.1002/cctc.201500485
Change the channel: Reduced graphene oxide (RGO) sheets with excellent electronic conductivity are introduced to bismuth vanadate photoanode films to provide an effective channel for electron transport. The proposed mechanism of charge transport for the reduced graphene oxide–bismuth vanadate photoelectrode under irradiation is depicted. FTO=Fluorine-doped tin oxide.
- Highly Selective Hydrodecarbonylation of Oleic Acid into n-Heptadecane over a Supported Nickel/Zinc Oxide–Alumina Catalyst
Dr. Guangci Li, Feng Zhang, Dr. Lei Chen, Chuanhui Zhang, Dr. He Huang and Prof. Dr. Xuebing Li
Article first published online: 28 JUL 2015 | DOI: 10.1002/cctc.201500418
Basic rules! A suitable amount of basicity on the support is favorable for the conversion of oleic acid into n-alkanes mainly through hydrodecarbonylation with relatively low hydrogen consumption.