Cover image for Vol. 82 Issue 4

Editor: Marisa Spiniello. Editorial Board Chairs: Matthias Driess, Michal Hocek, Tetsuro Majima

Online ISSN: 2192-6506

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal

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April 21, 2017

ChemPlusChem 4/2017: Biofest Special Issue

ChemPlusChem 4/2017: Biofest Special Issue

This special issue organized by guest editors Silviu Balaban, Luisa DeCola, and Wolfgang Schuhmann focuses on bioinspired chemistry, biomaterials, and bioelectrochemistry. Particular highlights include: a VIP communication by Olaf Rüdiger on a hydrogenase for solar water splitting and HIP papers by Renate Bilewicz on lipidic nanoparticles used for drug delivery and by Sylvie Begin-Colin on iron oxide nanoparticles in imaging. Minireviews by Jean Weiss on porphyrins as hemoprotein models and molecular wires, Segey Schleev on the development of implanted fuel cells, and Ross Milton and Shelley Minteer on bioelectrosynthesis for ammonia production provide a broader context.

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Recently Published Articles

  1. Pyrrolo[3,2-b]pyrrole as Electron-Donor Central Core for Solution-Processed Organic Solar Cells

    Rocio Dominguez, Nuria F Montcada, Pilar de la Cruz, Emilio Palomares and Fernando Langa

    Accepted manuscript online: 27 APR 2017 04:07PM EST | DOI: 10.1002/cplu.201700158

  2. Self-Assembled Liquid-Crystalline Ion Conductors in Dye-Sensitized Solar Cells: Effects of Molecular Sensitizers on Their Performance

    Daniel Högberg, Dr. Bartolome Soberats, Assoc. Prof. Dr. Masafumi Yoshio, Yurika Mizumura, Prof. Dr. Satoshi Uchida, Prof. Dr. Lars Kloo, Prof. Dr. Hiroshi Segawa and Prof. Dr. Takashi Kato

    Version of Record online: 26 APR 2017 | DOI: 10.1002/cplu.201700099

    Thumbnail image of graphical abstract

    Bright future: Nanostructured liquid crystals forming self-assembled two-dimensional ion-transport pathways have been applied as electrolytes in dye-sensitized solar cells (DSSCs; see figure). DSSCs based on these liquid-crystalline (LC) electrolytes and organic dye sensitizers show more efficient energy conversion than LC-DSSCs based on ruthenium metal–organic dyes.

  3. Elucidation of Intramolecular Through-Space Electronic Communication in a Propeller-Shaped Molecule

    Takuya Kodama, Dr. Yasukazu Hirao, Dr. Tomohiko Nishiuchi and Prof. Dr. Takashi Kubo

    Version of Record online: 26 APR 2017 | DOI: 10.1002/cplu.201700045

    Thumbnail image of graphical abstract

    Talking in circles? Electronic communication among three blades in a propeller-shaped π-conjugated molecule is investigated by electrochemical and spectroscopic methods. The hopping rate of an unpaired electron among the blades in a radical cation species is altered by temperature change.

  4. Surfactant-Free Polar-to-Nonpolar Phase Transfer of Exfoliated MoS2 Two-Dimensional Colloids

    Dr. Emerson Giovanelli, Dr. Andres Castellanos-Gomez and Prof. Emilio M. Pérez

    Version of Record online: 25 APR 2017 | DOI: 10.1002/cplu.201700038

    Thumbnail image of graphical abstract

    Switching polarity in colloids: MoS2 nanosheets exfoliated from the bulk and well dispersed in a polar isopropanol/water mixture could be transferred efficiently to nonpolar chloroform by flocculation followed by centrifugation/redispersion sequences (see figure). In spite of partial aggregation, the resulting suspensions display notable colloidal stability, controlled by nanosheet lateral dimensions.

  5. Benzothiadiazole-Based Small-Molecule Semiconductors for Organic Thin-Film Transistors and Complementary-like Inverters

    Hyekyoung Kim, M. Rajeshkumar Reddy, Hyungsug Kim, Donghee Choi, Prof. Dr. Choongik Kim and Prof. Dr. SungYong Seo

    Version of Record online: 24 APR 2017 | DOI: 10.1002/cplu.201700070

    Thumbnail image of graphical abstract

    Making gains: New benzothiadiazole-based small-molecule organic semiconductors were synthesized and used as active layers in organic thin-film transistors with the highest hole mobility of 0.1 cm2 V−1 s−1. Bulk heterojunction ambipolar transistors were fabricated by blending the developed p-channel material with N,N′-1H,1H-perfluorobutyl dicyanoperylenediimide. Complementary-like inverters fabricated from the ambipolar transistors exhibited voltage gains as high as 84.