Cover image for Vol. 80 Issue 4

Editor: Marisa Spiniello

Impact Factor: 3.242

ISI Journal Citation Reports © Ranking: 2013: 38/148 (Chemistry Multidisciplinary)

Online ISSN: 2192-6506

Associated Title(s): Angewandte Chemie International Edition, Chemistry - A European Journal

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April 02, 2015

ChemPlusChem 4/2015: Applications in Medicine

Reseach with potential medicinal applications, in the broadest sense, set an unexpected accent in this issue. Narinder Singh reports the nanomolar detection of iodine in aqueous medium and also in urine samples based on the selective recognition behavior of a gold--organic nanoparticle sensor. Chelator-appended cyclodextrin derivatives devised by Gzaziella Vecchio show potential for the treatment of metal-associated neurogenerative diseases. In the research featured on the front cover Giuliano Giambastiani prepared a hetero-bifunctional cross-linker to decorate carbon nanotubes; these in turn can act as nanocarriers for potential biological probes (cover profile).

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Recently Published Articles

  1. Optimization and Insights into the Mechanism of Formation of Mechanically Interlocked Derivatives of Single-Walled Carbon Nanotubes

    Alberto de Juan, Dr.  M. Mar Bernal and Dr. Emilio M. Pérez

    Article first published online: 27 APR 2015 | DOI: 10.1002/cplu.201500115

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    Optimizing MINTs. The reaction conditions for the synthesis of mechanically interlocked derivatives of single-walled carbon nanotubes (MINTS, see figure) were varied systematically. Analysis of the macroscopic data helps shed light on the mechanism of formation of MINTs.

  2. Phenolated Oleic Acid Based Polybenzoxazine Derivatives as Corrosion Protection Layers

    Brindusa Bălănucă, Dr. Matei Raicopol, Dr. Artjom Maljusch, Dr. Sorina Garea, Dr. Anamaria Hanganu, Prof. Dr. Wolfgang Schuhmann and Dr. Corina Andronescu

    Article first published online: 27 APR 2015 | DOI: 10.1002/cplu.201500092

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    Leave your coat on: Benzoxazine derivatives based on phenolated methyl oleate and either aniline, 1,6-diaminohexane, or 4,4′-diaminodiphenylmethane are the basis for dense, hydrophobic coatings on Zn-Mg-Al alloy coated steel for passive corrosion protection. The polymer coatings invoke a substantial anodic shift of the open-circuit potential and the breakthrough potential in potentiodynamic measurements (see figure).

  3. Reduced Graphene Oxide Composite with Oxidizable Manganese/Cobalt Mixed Oxide for p-Cresol Oxidation by Using Molecular Oxygen

    Dr. Ajay Jha, Sagar H. Patil, Bhanu P. Solanki, Dr. Ana P. C. Ribeiro, Prof. Carlos A. N. Castro, Dr. Kashinath R. Patil, Prof. Alberto Coronas and Dr. Chandrashekhar V. Rode

    Article first published online: 27 APR 2015 | DOI: 10.1002/cplu.201500053

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    Composite doubles: A reduced graphene oxide (r-GO) composite with MnCo oxide nanoparticles increases the selective oxidation of p-cresol to form p-hydroxybenzaldehyde (PHBAld; see scheme, PHBAlc=p-hydroxybenzyl alcohol). The high catalytic activity of the r-GO–MnCo catalyst is related to the increase in the redox potential of the mixed oxide after being supporting on r-GO.

  4. Nanoflake-Modulated La2Se3 Thin Films Prepared for an Asymmetric Supercapacitor Device

    Swati J. Patil, Ravindra N. Bulakhe and Prof. Chandrakant D. Lokhande

    Article first published online: 27 APR 2015 | DOI: 10.1002/cplu.201500009

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    Flaking out: La2Se3 nanoflakes were prepared from an aqueous medium by means of a chemical-bath deposition method and then used as a supercapacitor electrode (see figure). An asymmetric supercapacitor device based on the La2Se3 electrode in aqueous electrolyte exhibited good specific capacitance, excellent charge/discharge properties, and superior long-term cycling stability.

  5. Targeted Delivery of Fluorescent High-Mannose-Type Oligosaccharide Cathepsin Inhibitor Conjugates

    Chung S. Wong, Dr. Sascha Hoogendoorn, Prof. Dr. Gijs A. van der Marel, Prof. Dr. Herman S. Overkleeft and Dr. Jeroen D. C. Codée

    Article first published online: 21 APR 2015 | DOI: 10.1002/cplu.201500004

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    Manno, manno! Fluorescent glycoconjugates composed of a peptide epoxysuccinate coupled via a BODIPY dye to oligomannosides (see figure) show mannose-receptor-dependent uptake and ensuing cathepsin inhibition in live dendritic cells. The size of the mannose oligosaccharides proved to influence the amount of inhibition.