Journal of the Chinese Chemical Society

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Recently Published Articles

  1. Photosensitivity of CuBiSe2 Thin Film Deposited by Vacuum Evaporation Technique

    Abirami Muthukannan, Pasunkili Prema, Johnson Henry, Kannusamy Mohanraj and Ganesan Sivakumar

    Version of Record online: 20 SEP 2016 | DOI: 10.1002/jccs.201600189

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    Novel CuBiSe2 thin film was deposited by the vacuum evaporation method. The films showed higher absorption in the visible region, and the Eg was found to be ~1.84 eV. Photosensitivity is 181%. The thin films can be used as an absorber layer in solar cells.

  2. Enhancement of Mercury Sorbent Using Metal Aluminate Carbonates with Chloride under Hydrothermal Conditions

    Ching-Tsung Yu and Hui-Mei Lin

    Version of Record online: 14 SEP 2016 | DOI: 10.1002/jccs.201600210

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    Illustration shows X-ray diffraction (XRD) patterns of 1:1–30:1 Mn/Al lamellar materials as Hg sorbent Mn–Al–CO3, which was synthesized by incorporating Mn2+, Al3+ in alkaline CO32−/OH solutions. Hausmannite (manganeseII,III oxide) contains Mn2+ and Mn4+ valence states, providing high Hg removal potential to this material. Mercury is strongly captured on Mn/Al sorbent, and the adsorption could be further enhanced by chemical reaction with chloride ions.

  3. Iron-catalyzed C−H Activation

    Miaoshen Su, Cheng Li and Jingjun Ma

    Version of Record online: 14 SEP 2016 | DOI: 10.1002/jccs.201600184

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    The review summarized research of the transition-metal-catalyzed aromatic propargyl ether 0 transition-metal-catalyzed aromatic propargyl ether 0 atomic key ortho sp3 C–H cross dehydrogenation coupling reaction.

  4. Sensitivity and Resolution Development of Spiropyran-based Molecular Photoswitches

    Maryam Heydaripour, Farahnaz Nourmohammadian and Naghi Saadatjoo

    Version of Record online: 7 SEP 2016 | DOI: 10.1002/jccs.201600159

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    Thus, 13 azospiropyran derivatives were synthesized and their spectroscopic and photokinetic behaviors were studied. The quality of photochromic reactions of the synthesized photochromic compounds were compared using a dose-response model. Interestingly, by replacing the nitro group in 6-nitrospiropyran with a simple phenylazo moiety, the SP form is still colorless and the color intensity of the merocyanine (MC) form is improved desirably by extending the conjugation length. The effect of different functional groups on photochromic behavior were reported.

  5. A Novel Method for the Synthesis of Newfangled Asymmetric Schiff Bases from α-amino Acids under Ultrasonic Conditions and in Aqueous Medium

    Kıvılcım Şendil, Turgay Tekin, Haydar Göksu, Mehmet Oğuz, Barış Anıl and Mehmet Serdar Gültekin

    Version of Record online: 6 SEP 2016 | DOI: 10.1002/jccs.201600094

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    The method developed for the synthesis of Schiff bases under ultrasonic conditions in water is practical, efficient and eco-friendly.