Journal of the Chinese Chemical Society

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Recently Published Articles

  1. Palladium-Catalyzed Dehydrogenative Coupling Reaction of Terminal Alkynes with Unactivated Alkenes

    Akira Yada, Shoki Nishi, Yuta Sato, Sakina Ichinoseki and Masahiro Murakami

    Version of Record online: 19 OCT 2017 | DOI: 10.1002/jccs.201700268

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    Terminal alkynes having a bulky substituent dehydrogenatively couple with unactivated terminal alkenes with catalysis of palladium. The terminal sp carbon forms a bond with the internal sp2 carbon of the alkene regioselectively to produce branched conjugated 1,3-enynes with wide functional group tolerance.

  2. One-Pot Synthesis of Nitrogen-doped TiO2 Nanowires with Enhanced Photocurrent Generation

    Yin-Cheng Yen, Sheng Ou and Kuan-Jiuh Lin

    Version of Record online: 17 OCT 2017 | DOI: 10.1002/jccs.201700226

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    One-pot hydrothermal method using triethylamine as nitrogen source was used to successfully synthesize N-TiO2 nanowires. The optimized photocurrent density showed an improvement by a factor of 3.2 because of the optimized nitrogen doping, effectively improving the light absorption.

  3. A DFT/TDDFT Investigation of Excited State Dynamical Mechanism of (E)-1-((2,2-Diphenylhydrazono)methyl)naphthalen-2-ol

    Dapeng Yang, Jingyuan Wu, Min Jia and Xiaoyan Song

    Version of Record online: 16 OCT 2017 | DOI: 10.1002/jccs.201700253

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    The strengthening intramolecular hydrogen bond in the S1 state provides the possibility for the proton transfer process. The redistribution of charge upon the excitation facilitates the ESIPT reaction. The lower potential energy barrier in the S1 state promotes the ESIPT process, which successfully explains the fluorescence quenching phenomenon.

  4. Citric Acid-catalyzed Synthesis of 2,4-Disubstituted Thiazoles from Ketones via C–Br, C–S, and C–N Bond Formations in One Pot: A Green Approach

    Trivikram Reddy Gundala, Kumar Godugu and Chinna Gangi Reddy Nallagondu

    Version of Record online: 16 OCT 2017 | DOI: 10.1002/jccs.201700200

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    Citric acid-catalyzed one-pot synthesis of 2,4-disubstituted thiazoles from readily available ketones, NBS, and thiourea in a mixture of ethanol and water (3:1) is achieved under reflux conditions. This method has the advantages of freedom from the isolation of lachrymatory α-bromoketones and chromatographic purification, cleaner reaction profile, broad substrate scope, and suitability for large-scale applications in the chemical and pharmaceutical industries.

  5. Synthesis, Spectral Characterization, Antitumor, Antioxidant, and Antimicrobial Studies of New Potential ONS Schiff Base Complexes

    Amani S. Alturiqi, Abdel-Nasser M.A. Alaghaz and Reda A. Ammar

    Version of Record online: 13 OCT 2017 | DOI: 10.1002/jccs.201700072

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    Synthesis of chromonebased amine. Complexes of Co(II), Ni(II), Cu(II) and Zn(II) with [ML2] composition. Structural elucidation by the physicochemical and spectral studies.