Asian Journal of Organic Chemistry

Cover image for Vol. 4 Issue 5

Editor: Richard Threlfall; Editorial Board Chairs: Sung Ho Kang, Keiji Maruoka, Deqing Zhang

Impact Factor: 2.292

ISI Journal Citation Reports © Ranking: 2013: 27/58 (Chemistry Organic)

Online ISSN: 2193-5815

Associated Title(s): Advanced Synthesis & Catalysis, Chemistry – An Asian Journal, ChemNanoMat, European Journal of Organic Chemistry

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January 13, 2015

Special Issue on Molecular Devices and Machines

The new special issue "Multicomponent Molecular-Level Devices and Machines" is now online.

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Recently Published Articles

  1. Geometrical Dependence of the Highest Occupied Molecular Orbital in Bicyclic Systems: π-Facial Stereoselectivity of Bicyclic and Tricyclic Olefins

    Motonori Tsuji

    Article first published online: 29 MAY 2015 | DOI: 10.1002/ajoc.201500054

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    Choosing sides: An interpretation of the stereochemical preference of electrophilic attacks of olefins in bicyclic and tricyclic systems is proposed. The selectivity of these systems is thought to be controlled by two types of HOMO, which are formed by a combination of different orbitals, depending on the geometrical conditions.

  2. Effective Synthesis of α-d-GlcN-(1[RIGHTWARDS ARROW]4)-d-GlcA/l-IdoA Glycosidic Linkage under Gold(I) Catalysis

    Dr. Jiakun Li, Yuanwei Dai, Dr. Wei Li, Dr. Stéphane Laval, Dr. Peng Xu and Prof. Dr. Biao Yu

    Article first published online: 29 MAY 2015 | DOI: 10.1002/ajoc.201500113

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    Gold rush: Direct glycosylations between 2-deoxy-2-azido-d-glucopyranosyl (d-GlcN) ortho-hexynylbenzoate donors and uronate acceptors (d-GlcA/l-IdoA) under gold(I) catalysis were performed in high yields with α selectivity, thus constituting an alternative method to construct the difficult α-d-GlcN-(1[RIGHTWARDS ARROW]4)-d-GlcA/l-IdoA glycosidic linkage occurring in heparin and heparan sulfate. PG=protecting group.

  3. Facile Synthesis and Phase Behaviors of Monofunctionalized Hexa-peri-hexabenzocoronenes

    Yu Zhou, Meng-Yao Zhang, Ke-Hua Gu, Yu-Feng Zhu, Xing-He Fan and Zhihao Shen

    Article first published online: 29 MAY 2015 | DOI: 10.1002/ajoc.201500131

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    The one and only: A method for synthesizing monofunctionalized hexa-peri-hexabenzocoronenes was developed by loading dialkyl-diphenylacetylenes and asymmetric diphenylacetylene derivatives at the same time catalyzed by [Co2(CO)8].

  4. Copper-Catalyzed β-Selective Hydroborylation of Ynamides: A Facile Access to (E)-β-Alkenylamide Boronates

    Prof. Dr. Yihui Bai, Fang Zhang, Jiajia Shen, Fang Luo and Prof. Dr. Gangguo Zhu

    Article first published online: 29 MAY 2015 | DOI: 10.1002/ajoc.201500119

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    On the beta: A Cu-catalyzed, highly β-selective hydroboration of ynamides with bis(pinacolato)diboron as the hydroboration reagent is reported, providing a good complementary regioselectivity to the existing methods.

  5. Suppression Mechanism for Enol-Enol Isomerization of 2-Substituted Dimedones

    Hideyasu CHINA and Yutaka Okada

    Accepted manuscript online: 28 MAY 2015 08:56AM EST | DOI: 10.1002/ajoc.201500069

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