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October 15, 2014

VIP: Non-Invasive Probing of Nanoparticle Electrostatics

Dr. Kristina Tschulik, Dr. Wei Cheng, Dr. Christopher Batchelor-McAuley, Stuart Murphy, Dr. Dario Omanović and Prof. Dr. Richard G. Compton

Non-Invasive Probing of Nanoparticle ElectrostaticsNot what you might think: A new and non-invasive technique to probe the electrostatic interaction between surface-charged nanoparticles and a charged metal/solution interface shows that electrostatic effects are insignificant in all but very dilute electrolytes.

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    Thumbnail image of graphical abstract

    Simultaneous collection of powder neutron diffraction data and electrochemical data has been used to determine a new discharge mechanism for a thermal battery utilising NiS2 as a cathode, which does not involve Ni7S6. The evolution of the crystalline phases during battery discharge has been studied and four different nickel-containing phases were observed (NiS2, NiS, Ni3S2 and Ni).