Primitive substances in asteroid and meteorite materials represent a record of early solar system evolution. To allow the study of these materials, they must be collected and transferred to the laboratory. Collection during sample return missions requires an assessment of the size of samples needed. Meteorite falls or finds must be subdivided into appropriate subsamples for analysis by successive generations of scientists. It is essential, therefore, to determine a representative mass or volume at which the collected or allocated sample is representative of the whole. For the first time, we have used a Bayesian statistical approach and a selected meteorite sample, Murchison, to identify a recommended smallest sample mass that can be used without interferences from sampling bias. Enhancing background knowledge to inform sample selection and analysis is an effective means of increasing the probability of obtaining a positive scientific outcome. The influence of the subdivision mechanism when preparing samples for distribution has also been examined. Assuming a similar size distribution of fragments to that of the Murchison meteorite, cubes can be similarly representative as fragments, but at orders of magnitude smaller sizes. We find that: (1) at all defined probabilities (90%, 95%, and 99%), nanometer-sized particles (where the axes of a three-dimensional sample are less that a nanometer in length) are never representative of the whole; (2) at the intermediate and highest defined probabilities (95% and 99%), micrometer-sized particles are never representative of the whole; and (3) for micrometer-sized samples, the only sample that is representative of the whole is a cube and then only at a 90% probability. The difference between cubes and fragments becomes less important as sample size increases and any >0.5 mm-sized sample will be representative of the whole with a probability of 99.9%. The results provide guidance for sample return mission planners and curators or advisory boards that must distribute valuable samples for analysis.

The 3.6 Ma, 18-km-diameter El'gygytgyn impact structure (Arctic Russia) is unique among the currently known terrestrial impact craters in that it is the only one that was formed in acid volcanic rocks. Previous analyses of impactites from El'gygytgyn showed minor enrichments of the siderophile elements, including Ir, which, together with distinct Cr enrichments, gave rise to speculation that an achondritic projectile was involved. We studied the major and trace element composition in samples from the new ICDP drill core obtained near the center of the structure, as well as the chromium isotopic composition of an impact glass sample collected on the surface. Several suevitic breccias from the upper part of the suevite sequence in the drill core show higher Cr and Ni contents compared with felsic volcanic rocks in the lower part of the core and from surface samples. However, it is difficult to unambiguously establish a meteoritic component from trace element data, as input from (rare) mafic target rocks is a possibility. In contrast, the Cr isotopic composition of the impact glass sample yielded a nonterrestrial ε⁵⁴Cr value of −0.72 ± 0.31 (2 std. err.). This negative ε⁵⁴Cr is different from known carbonaceous chondrite values (ε⁵⁴Cr of +0.95 to +1.65), but is nearly identical to reported values for ureilites (approximately −0.77). The value is, however, also within analytical error of eucrites (approximately −0.38) and ordinary chondrites (approximately −0.42). Given the chemical signatures found in previous analyses of El'gytgytgyn impactites and the similarity of our Cr isotopic data to ureilites, we suggest that the impacting asteroid could have been an F-type asteroid of mixed composition, similar to the recent Almahata Sitta fall in Sudan.

Hyperbolic meteor orbits from the catalog of 64,650 meteors observed by the multistation video meteor network located in Japan (SonotaCo 2009) have been investigated with the aim of determining the relation between the frequency of hyperbolic and interstellar meteors. The proportion of hyperbolic meteors in the data decreased significantly (from 11.58% to 3.28%) after a selection of quality orbits, which shows its dependence on the quality of observations. Initially, the hyperbolic orbits were searched for meteors unbound due to planetary perturbation. It was determined that 22 meteors from the 7489 hyperbolic orbits in the catalog (and 2 from the selection of the orbits with the highest quality) had had a close encounter with a planet, none of which, however, produced essential changes in their orbits. Similarly, the fraction of hyperbolic orbits in the data, which could be hyperbolic by reason of a meteor's interstellar origin, was determined to be at most 3.9 × 10⁻². From the statistical point of view, the vast majority of hyperbolic meteors in the database have definitely been caused by inaccuracy in the velocity determination. This fact does not necessarily assume great measurement errors, since, especially near the parabolic limit, a small error in the value of the heliocentric velocity of a meteor can create an artificial hyperbolic orbit that does not really exist. The results show that the remaining 96% of meteoroids with apparent hyperbolic orbits belong to the solar system meteoroid population. This is also supported by their high abundance (about 50%) among the meteor showers.

We experimentally studied hydrogen (H)–deuterium (D) substitution reactions of solid methylamine (CH₃NH₂) under astrophysically relevant conditions. We also calculated the potential energy surface for the H–D substitution reactions of methylamine isotopologues using quantum chemical methods. Despite the relatively large energy barrier of more than 18 kJ mol⁻¹, CH₃NH₂ reacted with D atoms to yield deuterated methylamines at 10 K, suggesting that the H–D substitution reaction proceeds through quantum tunneling. Deuterated methylamines reacted with H atoms as well. On the basis of present results, we propose that methylamine has potential for D enrichment through atomic surface reactions on interstellar grains at very low temperatures in molecular clouds. D enrichment would occur in particular in the methyl group of methylamine.

Comet 1P/Halley has the unique distinction of having a very comprehensive set of observational records for almost every perihelion passage from 240 B.C. This has helped to constrain theoretical models pertaining to its orbital evolution. Many previous works have shown the active role of mean motion resonances (MMR) in the evolution of various meteoroid streams. Here, we look at how various resonances, especially the 1:6 and 2:13 MMR with Jupiter, affect comet 1P/Halley and thereby enhance the chances of meteoroid particles getting trapped in resonance, leading to meteor outbursts in some particular years. Comet Halley itself librated in the 2:13 resonance from 240 B.C. to 1700 A.D. and in the 1:6 resonance from 1404 B.C. to 690 B.C., while stream particles can survive for time scales of the order of 10,000 yr and 1,000 yr in the 1:6 and 2:13 resonances, respectively. This determines the long-term dynamical evolution and stream structure, influencing the occurrence of Orionid outbursts. Specifically, we are able to correlate the occurrence of enhanced meteor phenomena seen between 1436–1440, 1933–1938, and 2006–2010 with the 1:6 resonance and meteor outbursts in 1916 and 1993 with the 2:13 resonance. Ancient as well as modern observational records agree with these theoretical simulations to a very good degree.

Presented here are results from photometric analysis on broadband images taken of comet 21P/Giacobini-Zinner from May 24, 2011 to October 24, 2011. As the parent body of the Draconids, a meteor shower known for outbursting, 21P was studied for its dust production activity, Afρ, focusing on how it changes with heliocentric distance. An expected increase in dust production with a decrease in heliocentric distance was observed. The comet went from heliocentric distance of 3.05 –1.77 AU during the observed time that corresponded to an apparent magnitude of 19.61 to 15.72 and Afρ of 16.48 cm to 284.17 cm. These values can be extrapolated to estimate a peak Afρ value at perihelion of 3824 cm. The images were obtained using a 0.5-meter f/8.1 Ritchey-Chrétien telescope located in Mayhill, New Mexico.

Comet C/2009 P1 (Garradd) was observed by imaging polarimetry for nearly 5 months from October 2011 to March 2012, over an intermediate phase angle range (28°–35°). Two months before perihelion and one month after, dust particles seem to be ejected all around the optocenter and jets extend to distances greater than 40,000 km. An increase of activity is noticed in intensity and polarization after perihelion. Two months before perihelion and one month after, the dust emission seems to be all around the optocenter. Two and three months after perihelion the jets are mainly toward the solar direction with an extension of more than 20,000 km projected on the sky. The values of the aperture polarization are comparable to those of other comets. On the polarization maps in October 2011 and January 2012 the higher polarization zones extend in large regions perpendicularly to the solar direction where jets are also observed. In February and March 2012, the polarization in the jets is larger in the solar direction than in the surrounding coma. By its activity visible on intensity images and polarization maps at large distances from the nucleus, comet Garradd probably belongs to the high-P_max class of comets.

On the basis of observations using Cs-corrected STEM, we identified three types of surface modification probably formed by space weathering on the surfaces of Itokawa particles. They are (1) redeposition rims (2–3 nm), (2) composite rims (30–60 nm), and (3) composite vesicular rims (60–80 nm). These rims are characterized by a combination of three zones. Zone I occupies the outermost part of the surface modification, which contains elements that are not included in the unchanged substrate minerals, suggesting that this zone is composed of sputter deposits and/or impact vapor deposits originating from the surrounding minerals. Redeposition rims are composed only of Zone I and directly attaches to the unchanged minerals (Zone III). Zone I of composite and composite vesicular rims often contains nanophase (Fe,Mg)S. The composite rims and the composite vesicular rims have a two-layered structure: a combination of Zone I and Zone II, below which Zone III exists. Zone II is the partially amorphized zone. Zone II of ferromagnesian silicates contains abundant nanophase Fe. Radiation-induced segregation and in situ reduction are the most plausible mechanisms to form nanophase Fe in Zone II. Their lattice fringes indicate that they contain metallic iron, which probably causes the reddening of the reflectance spectra of Itokawa. Zone II of the composite vesicular rims contains vesicles. The vesicles in Zone II were probably formed by segregation of solar wind He implanted in this zone. The textures strongly suggest that solar wind irradiation damage and implantation are the major causes of surface modification and space weathering on Itokawa.

The El'gygytgyn impact structure in northeast Russia was drilled in 2008/2009. The 3.5 Ma old structure has a rim-to-rim diameter of 18 km and is the only known impact structure that has been formed on a siliceous volcanic target. The petrophysical, rock- and paleomagnetic properties, including attempted reorientation of samples, along the El'gygytgyn drill core were analyzed. Physical properties, such as bulk density, porosity, seismic velocity, and electrical conductivity, clearly showed the propagation of shock and the associated fracturing. The grain density, however, was probably influenced by the postimpact hydrothermal activity and/or the distribution of impact melt. The highest values of electrical conductivity coincided with higher concentrations of particular metals as indicated by Raschke et al. (2012a). The rock- and paleomagnetic investigations showed iron-titanium oxides with varying oxidation/reduction states as the main magnetic fraction in the core samples and indicated them as carriers for remanent magnetization. With few exceptions, most samples showed normal polarity of characteristic remanent magnetization and confirmed that the impact occurred after the Gauss/Gilbert (approximately 3.596 Ma) reversal. Shallower inclinations than that expected for a 3.5 Ma dipole field were probably due to impact-related block movements and/or compaction.

The Košice meteorite fall occurred in eastern Slovakia on February 28, 2010, 22:25 UT. The very bright bolide was imaged by three security video cameras from Hungary. Detailed bolide light curves were obtained through clouds by radiometers on seven cameras of the European Fireball Network. Records of sonic waves were found on six seismic and four infrasonic stations. An atmospheric dust cloud was observed the next morning before sunrise. After careful calibration, the video records were used to compute the bolide trajectory and velocity. The meteoroid, of estimated mass of 3500 kg, entered the atmosphere with a velocity of 15 km s⁻¹ on a trajectory with a slope of 60° to the horizontal. The largest fragment ceased to be visible at a height of 17 km, where it was decelerated to 4.5 km s⁻¹. A maximum brightness of absolute stellar magnitude about −18 was reached at a height of 36 km. We developed a detailed model of meteoroid atmospheric fragmentation to fit the observed light curve and deceleration. We found that Košice was a weak meteoroid, which started to fragment under the dynamic pressure of only 0.1 MPa and fragmented heavily under 1 MPa. In total, 78 meteorites were recovered in the predicted fall area during official searches. Other meteorites were found by private collectors. Known meteorite masses ranged from 0.56 g to 2.37 kg. The meteorites were classified as ordinary chondrites of type H5 and shock stage S3. The heliocentric orbit had a relatively large semimajor axis of 2.7 AU and aphelion distance of 4.5 ± 0.5 AU. Backward numerical integration of the preimpact orbit indicates possible large variations of the orbital elements in the past due to resonances with Jupiter.

Asteroid 2201 Oljato passed through perihelion inside the orbit of Venus near the time of its conjunction with Venus in 1980, 1983, and 1986. During those three years, many interplanetary field enhancements (IFEs) were observed by the Pioneer Venus Orbiter (PVO) in the longitude sector where the orbit of Oljato lies inside Venus' orbit. We attribute IFEs to clouds of fine-scale, possibly highly charged dust picked up by the solar wind after an interplanetary collision between objects in the diameter range of 10–1000 m. We interpret the increase rate in IFEs at PVO in these years as due to material in Oljato's orbit colliding with material in, or near to, Venus' orbital plane and producing a dust-anchored structure in the interplanetary magnetic field. In March 2012, almost 30 yr later, with Venus Express (VEX) now in orbit, the Oljato-Venus geometry is similar to the one in 1980. Here, we compare IFEs detected by VEX and PVO using the same IFE identification criteria. We find an evolution with time of the IFE rate. In contrast to the results in the 1980s, the recent VEX observations reveal that at solar longitudes in which the Oljato orbit is inside that of Venus, the IFE rate is reduced to the level even below the rate seen at solar longitudes where Oljato's orbit is outside that of Venus. This observation implies that Oljato not only lost its co-orbiting material but also disrupted the “target material,” with which the co-orbiting material was colliding, near Venus.

The Dawn mission was designed to test our hypothesis about the origin and evolution of the early solar system by visiting the largest differentiated basaltic asteroid, 4 Vesta, believed to be a survivor from the earliest times of rocky body formation. Observations from orbit show that Vesta is the parent body of the Howardite, Eucrite, Diogenite meteorites. Vesta has an iron core and a eucritic–diogenitic crust. Its surface is characterized by abundant impact craters but with no evident volcanic features. It has two ancient impact basins in the southern hemisphere that are associated with circum-planetary troughs. The northern hemisphere is the more heavily cratered and contains the oldest terrains. The surface of Vesta is diverse, with north-south and east-west dichotomies in the eucrite-to-diogenite ratio. Its surface contains both very bright and very dark material, and its color varies strongly from region to region. Both the mineralogical and the elemental compositions agree with that expected for the HED parent body. Significant OH or H may be present in the upper crust and the presence of pits in “fresh” craters is consistent with the devolatilization of the surface after a collision either brought to or tapped a source of water on Vesta. The presence of dark material on the surface of Vesta suggests efficient transport pathways for organic material, and the mixing of the dark material with the more pristine pyroxene explains the varying albedo across the surface. Vesta has proven to be a reliable witness to the formation of the solar system.

Shock metamorphic features at the Saarijärvi (D > 2 km) and Söderfjärden (D = 6.5 km) structures in Finland have so far only been studied tentatively, although both are considered to be proven impact structures. This work presents the first detailed universal stage study of planar deformation features (PDFs), feather feature lamellae (FFL), and planar fractures (PFs) in quartz grains from a polymict impact breccia dike from Söderfjärden, and from sedimentary crater-fill rocks from Saarijärvi. Planar microstructures, particularly PDFs, are very rare and poorly developed or preserved in Saarijärvi, whereas in Söderfjärden they are much more common and well defined. Miller–Bravais indices of the planar microstructures in both Saarijärvi and Söderfjärden are indicative of relatively low-shock pressure but high shear conditions, only compatible with an impact origin for these structures. Although a Proterozoic age for Saarijärvi cannot be ruled out, the observations of shock features throughout the sedimentary crater-fill sequence and a brecciated sedimentary dike below the crater floor are more consistent with a Lower Cambrian (or younger) impact age.

We investigated exterior and interior subsamples from the Martian shergottite meteorites Allan Hills (ALH) A77005 and Roberts Massif (RBT) 04261 for secondary minerals, oxygen isotopes, Ar-Ar, and noble gas signatures. Electron microprobe investigations revealed that RBT 04261 does not contain any visible alteration even in its most exterior fractures, whereas fracture fillings in ALHA77005 penetrate into the meteorite up to 300 μm, beyond which the fractures are devoid of secondary minerals. Light noble gases seem to be almost unaffected by terrestrially induced alteration in both meteorites. Thus, a shock metamorphic overprint of 30–35 GPa can be deduced from the helium measurements in RBT 04261. Oxygen isotopes also seem unaffected by terrestrially weathering and variations can easily be reconciled with the differences in modal mineralogy of the exterior and interior subsamples. The measurements on irradiated samples (Ar-Ar) showed a clear Martian atmospheric contribution in ALHA77005, but this is less apparent in our sample of RBT 04261. Exterior and interior subsamples show slight differences in apparent ages, but the overall results are very similar between the two. In contrast, krypton and xenon are severely affected by terrestrial contamination, demonstrating the ubiquitous presence of elementally fractionated air in RBT 04261. Although seemingly contradictory, our results indicate that RBT 04261 was more affected by contamination than ALHA77005. We conclude that irrespective of on which planet the alteration occurred, exposure of Martian rocks to atmosphere (or brine) introduces noble gases with signatures elementally fractionated relative to the respective atmospheric composition into the rock, and relationships of that process with oxygen isotopes or mineralogical observations are not straightforward.

Negative ions (anions) were identified in the coma of comet 1P/Halley during in situ Electron Electrostatic Analyzer measurements performed by the Giotto spacecraft in 1986. These anions were detected with masses in the range 7–110 amu, but with insufficient mass resolution to permit unambiguous identification. We present details of a new chemical-hydrodynamic model for the coma of comet Halley that includes—for the first time—atomic and molecular anions, in addition to a comprehensive hydrocarbon chemistry. Anion number densities are calculated as a function of radius in the coma, and compared with the Giotto results. Important anion production mechanisms are found to include radiative electron attachment, polar photodissociation, dissociative electron attachment, and proton transfer. The polyyne anions C₄H⁻ and C₆H⁻ are found to be likely candidates to explain the Giotto anion mass spectrum in the range 49–73 amu. The CN⁻ anion probably makes a significant contribution to the mass spectrum at 26 amu. Larger carbon-chain anions such as C₈H⁻ can explain the peak near 100 amu provided there is a source of large carbon-chain-bearing molecules from the cometary nucleus.

This review starts with a brief historical overview of the subject, after which some recent papers attempting to improve the understanding of comet injection from the Oort Cloud and the origin of new comets are discussed. Special attention is paid to the importance of nongravitational effects in comet orbit determination, the synergy between stellar encounters and the galactic tides for the injection dynamics, and the role of planetary perturbations. The field is thus shown to be advancing rapidly, and brief comments on possible implications for studying the origin of the cloud are made.

We have simulated asteroid lightcurves for simple shape models using a realistic surface scattering law. The scattering law includes a shadowing function computed with numerical ray-tracing. We computed lightcurves in a variety of illumination geometries for both the traditional Lommel–Seeliger law and our seminumerical law. We observe a shift in the rotational phase of the lightcurves, which depends on the parameters of the scattering law as well as the illumination geometry and the direction of the spin axis of the asteroid. This phase shift is always zero at opposition, and can be as large as 10° for illumination geometries typical for Main Belt asteroids. The phase shift has implications on the accuracy of other results which are based on asteroid lightcurve analysis, such as spin-state or shape determination.

The El'gygytgyn impact structure, 18 km in diameter and 3.6 Ma old, in Arctic Siberia, Russia, is the only impact structure on Earth mostly excavated in acidic volcanic rocks. The Late Cretaceous volcanic target includes lavas, tuffs, and ignimbrites of rhyolitic, dacitic, and andesitic composition, and local occurrence of basalt. Although the ejecta blanket around the crater is nearly completely eroded, bomb-shaped impact glasses, redeposited after the impact event, occur in lacustrine terraces within the crater. Here we present detailed petrographic descriptions of newly collected impact glass-bearing samples. The observed features contribute to constrain the formation of the melt and its cooling history within the framework of the impact process. The collected samples can be grouped into two types, characterized by specific features: (1) “pure” glasses, containing very few clasts or new crystals and which were likely formed during the early stages of cratering and (2) a second type, which represents composite samples with impact melt breccia lenses embedded in silicate glass. These mixed samples probably resulted from inclusion of unmelted impact debris during ejection and deposition. After deposition the glassy portions continued to deform, whereas the impact melt breccia inclusions that probably had already cooled down behaved as rigid bodies in the flow.

We have analyzed glasses in eight howardites with the aim of distinguishing their origins as impact melts or pyroclasts. Although theoretical calculations predict that pyroclastic eruptions could have taken place on Vesta, the occurrence of pyroclastic glasses in HED meteorites has not been documented. This study involved petrographic examination of textures, electron microprobe analysis of major and minor elements, and LA-ICP-MS analysis for selected trace elements. Previously documented textural and compositional differences between lunar impact-melt and pyroclastic glasses partly guided this study. This work yielded no positive identification of pyroclastic glasses. The most likely explanation is that pyroclastic glasses never formed, either because Vesta contains insufficient volatiles to have powered explosive eruptions, or because eruptive conditions produced optically dense fire-fountains that allowed melt drops to collect as lava ponds. The impact-melt glasses were grouped (low-alkali, Ca-rich, and K-rich) based on compositions. We suggest that these glasses are the result of impacts onto known HED lithologies. The low-alkali glasses are impact melts of bulk HED lithologies. We hypothesize that the Ca-rich and K-rich glasses result from oversampling of plagioclase and of mesostasis that experienced liquid immiscibility, respectively, during micrometeorite impacts into eucrite targets.

Meteorite fusion crusts form during the passage of a meteoroid through the Earth's atmosphere and are highly oxidized intergrowths as documented by the presence of e.g., oxides. The porous and irregular fusion crust surrounding the Almahata Sitta sulfide-metal assemblage MS-166 was found highly enriched in wüstite (Fe_1-xO). Frictional heating of the outer portions of the assemblage caused partial melting of predominantly the Fe-sulfide and minor amounts of the outer Ni-rich portions of the originally zoned metal in MS-166. Along with melting significant amounts of oxygen were incorporated into the molten fusion crust and mainly FeS was oxidized and desulfurized to form wüstite. Considerable amounts of FeS were lost due to ablation, whereas the cores of the large metal grains appear largely unmelted leaving behind metal grains and surrounding wüstite-rich material (matte). Metal grains along with the surrounding matte typically form an often highly porous framework of globules interconnected with the matte. Although textures and chemical composition suggest that melting of Fe,Ni metal occurred only partially (Ni-rich rims), there is a trace elemental imprint of siderophile element partitioning influenced by oxygen in the metallic melt as indicated by the behavior of W and Ga, the two elements significantly affected by oxygen in a metallic melt. It is remarkable that MS-166 survived the atmospheric passage as troilite inclusions in iron meteorites are preferentially destroyed.

The fate of the impactor is an important aspect of the impact-cratering process. Defining impactor material as surviving if it remains solid (i.e., does not melt or vaporize) during crater formation, previous numerical modeling and experiments have shown that survivability decreases with increasing impact velocity, impact angle (with respect to the horizontal), and target density. Here, we show that in addition to these, impactor survivability depends on the porosity and shape of the impactor. Increasing impactor porosity decreases impactor survivability, while prolate-shaped (polar axis > equatorial axis) impactors survive impact more so than spherical and oblate-shaped (polar axis < equatorial axis) impactors. These results are used to produce a relatively simple equation, which can be used to estimate the impactor fraction shocked to a given pressure as a function of these parameters. By applying our findings to the Morokweng crater-forming impact, we suggest impact scenarios that explain the high meteoritic content and presence of unmolten fossil meteorites within the Morokweng crater. In addition to previous suggestions of a low-velocity and/or high-angled impact, this work suggests that an elongated and/or low porosity impactor may also help explain the anomalously high survivability of the Morokweng impactor.

The distribution of shock melts in four shergottites, having both vein and pocket geometry, has been defined and the conductive cooling time over the range 2500 °C to 900 °C calculated. Isolated 1 mm² pockets cool in 1.17 s and cooling times increase with pocket area. An isolated vein 1 × 7 mm in Northwest Africa (NWA) 4797 cools to 900 °C in 4.5 s. Interference between thermal haloes of closely spaced shock melts decreases the thermal gradient, extending cooling times by a factor of 1.4 to 100. This is long enough to allow differential diffusion of Ar and Xe from the melt. Small pockets (1 mm²) lose 2.2% Ar and 5.2% Xe during cooling, resulting in a small change in the Ar/Xe ratio of the dissolved gas over that originally trapped. With longer cooling times there is significant fractionation of Xe from Ar and the Ar/Xe ratio increases rapidly. The largest pockets show less variation of Ar/Xe and likely preserve the original trapped gas composition. Considering all of the model calculations, even the smallest isolated pockets have cooling times greater than the duration of the pressure pulse, i.e., >0.01 s. The crystallization products of these shock melts will be unrelated to the peak shock pressure experienced by the meteorite.

Crystalline impact-melt samples were created in high-temperature environments by relatively large craters and, as such, give additional constraints on the nature of the impacts that created them. This article provides new ⁴⁰Ar-³⁹Ar ages of impact-melt clasts in howardites and shows that these clasts formed on the HED parent body, 4 Vesta, within the time period 3.3–3.8 Ga. Rather than resulting from an increased number of impacts, however, impact-melted material in howardites may result from unusually high-velocity impacts occurring in the asteroid belt during this period. This scenario is similar to the late heavy bombardment of the Moon, pointing to an unusual dynamical event at this time across the inner solar system. Therefore, impact-melt rocks in howardites uniquely record a Vestan cataclysm.

The investigation into whether Mars contains signatures of past or present life is of great interest to science and society. Amino acids and nucleobases are compounds that are essential for all known life on Earth and are excellent target molecules in the search for potential Martian biomarkers or prebiotic chemistry. Martian meteorites represent the only samples from Mars that can be studied directly in the laboratory on Earth. Here, we analyzed the amino acid and nucleobase content of the shergottite Roberts Massif (RBT) 04262 using liquid chromatography-mass spectrometry. We did not detect any nucleobases above our detection limit in formic acid extracts; however, we did measure a suite of protein and nonprotein amino acids in hot-water extracts with high relative abundances of β-alanine and γ-amino-n-butyric acid. The presence of only low (to absent) levels of several proteinogenic amino acids and a lack of nucleobases suggest that this meteorite fragment is fairly uncontaminated with respect to these common biological compounds. The distribution of straight-chained amine-terminal n-ω-amino acids in RBT 04262 resembled those previously measured in thermally altered carbonaceous meteorites (Burton et al. 2012; Chan et al. 2012). A carbon isotope ratio of −24‰ ± 6‰ for β-alanine in RBT 04262 is in the range of reduced organic carbon previously measured in Martian meteorites (Steele et al. 2012). The presence of n-ω-amino acids may be due to a high temperature Fischer-Tropsch-type synthesis during igneous processing on Mars or impact ejection of the meteorites from Mars, but more experimental data are needed to support these hypotheses.

The high-pressure minerals of reidite and coesite have been identified in the moderately shock-metamorphosed gneiss (shock stage II, 35–45 GPa) and the strongly shock-metamorphosed gneiss (shock stage III, 45–55 GPa), respectively, from the polymict breccias of the Xiuyan crater, a simple impact structure 1.8 km in diameter in China. Reidite in the shock stage II gneiss displays lamellar textures developed in parental grains of zircon. The phase transformation of zircon to reidite likely corresponds to a martensitic mechanism. No coesite is found in the reidite-bearing gneiss. The shock stage III gneiss contains abundant coesite, but no reidite is identified in the rock. Coesite occurs as acicular, dendritic, and spherulitic crystals characteristic of crystallization from shock-produced silica melt. Zircon in the rock is mostly recrystallized. The postshock temperature in the shock stage III gneiss is too high for the preservation of reidite, whereas reidite survives in the shock stage II gneiss because of relatively low postshock temperature. Reidite does not occur together with coesite because of difference in shock-induced temperature between the shock stage II gneiss and the shock stage III gneiss.

The Terny impact structure, located in central Ukraine, displays a variety of diagnostic indicators of shock metamorphism, including shatter cones, planar deformation features in quartz, diaplectic glass, selective melting of minerals, and whole rock melting. The structure has been modified by erosion and subsequently buried by recent sediments. Although there are no natural outcrops of the deformed basement rocks within the area, mining exploration has provided surface and subsurface access to the structure, exposing impact melt rocks, shocked parautochthonous target rocks, and allochthonous impact breccias, including impact melt-bearing breccias similar to suevites observed at the Ries structure. We have collected and studied samples from surface and subsurface exposures to a depth of approximately 750 m below the surface. This analysis indicates the Terny crater is centered on geographic coordinates 48.13° N, 33.52° E. The center location and the distribution of shock pressures constrain the transient crater diameter to be no less than approximately 8.4 km. Using widely accepted morphometric scaling relations, we estimate the pre-erosional rim diameter of Terny crater to be approximately 16–19 km, making it close in original size to the well-preserved El'gygytgyn crater in Siberia. Comparison with El'gygytgyn yields useful insights into the original morphology of the Terny crater and indicates that the amount of erosion Terny experienced prior to burial probably does not exceed 320 m.

Twelve samples belonging to the chassignite and nakhlite subgroups of Martian meteorites were investigated using a variety of micro-beam analytical techniques to gain insight into the petrogenesis of these two meteorite classes. There are a striking number of geochemical similarities between the chassignites and nakhlites, including mineralogy and petrology, crystallization age, cosmic-ray exposure age, and radiogenic isotopic compositions. However, there are also geochemical differences, namely in trace element systematics of pyroxenes, that have led some authors to conclude that the nakhlites are comagmatic with each other, but not comagmatic with the chassignites. On the basis of data presented here, we propose a model in which these differences can be reconciled by the addition of an exogenous Cl-rich fluid to the chassignite-nakhlite magma body shortly after the formation of the cumulate horizon that was sampled by the Chassigny meteorite. This model is supported by the textural and chemical associations of the volatile-bearing minerals apatite, amphibole, and biotite, which record a history starting with the addition of a Cl- and LREE-enriched fluid to the magma body. As the magma continued to crystallize, it eventually reached chloride saturation and degassed a Cl-rich fluid phase. Depending on the provenance of the Cl-rich fluid, this model could explain how the chassignites and nakhlites originated from an LREE-depleted source, yet all exhibit LREE-enriched bulk-rock patterns. Additionally, the model explains the range in oxygen fugacity that is recorded by the chassignites and nakhlites because eventual exsolution and loss of Cl-rich fluid phases near the end of crystallization of the nakhlite sequence leads to auto-oxidation of the magma body due to the preferential partitioning of Fe²⁺ into the fluid phase.

Knowledge of Martian igneous and mantle compositions is crucial for understanding Mars' mantle evolution, including early differentiation, mantle convection, and the chemical alteration at the surface. Primitive magmas provide the most direct information about their mantle source regions, but most Martian meteorites either contain cumulate olivine or crystallized from fractionated melts. The new Martian meteorite Northwest Africa (NWA) 6234 is an olivine-phyric shergottite. Its most magnesian olivine cores (Fo₇₈) are in Mg-Fe equilibrium with a magma of the bulk rock composition, suggesting that it represents a melt composition. Thermochemical calculations show that NWA 6234 not only represents a melt composition but is a primitive melt derived from an approximately Fo₈₀ mantle. Thus, NWA 6234 is similar to NWA 5789 and Y 980459 in the sense that all three are olivine-phyric shergottites and represent primitive magma compositions. However, NWA 6234 is of special significance because it represents the first olivine-phyric shergottite from a primitive ferroan magma. On the basis of Al/Ti ratio of pyroxenes in NWA 6234, the minor components in olivine and merrillite, and phosphorus zoning of olivine, we infer that the rock crystallized completely at pressures consistent with conditions in Mars' upper crust. The textural intergrowths of the two phosphates (merrillite and apatite) indicate that at a very last stage of crystallization, merrillite reacted with an OH-Cl-F-rich melt to form apatite. As this meteorite crystallized completely at depth and never erupted, it is likely that its apatite compositions represent snapshots of the volatile ratios of the source region without being affected by degassing processes, which contain high OH-F content.

Hydrothermal processing on planetesimals in the early solar system produced new mineral phases, including those generated by the transformation of anhydrous silicates into their hydrated counterparts. Carbonaceous chondrites represent tangible remnants of such alteration products. Lithium isotopes are known to be responsive to aqueous alteration, yet previously recognized variability within whole rock samples from the same meteorite appears to complicate the use of these isotopes as indicators of processing by water. We demonstrate a new way to use lithium isotopes that reflects aqueous alteration in carbonaceous chondrites. Temperature appears to exert a control on the production of acetic acid-soluble phases, such as carbonates and poorly crystalline Fe-oxyhydroxides. Temperature and degree of water-rock interaction determines the amount of lithium isotope fractionation expressed as the difference between whole rock and acetic acid-leachable fractions. Using these features, the type 1 chondrite Orgueil (δ⁷Li_{(whole rock)} = 4.3‰; Δ⁷Li_{(acetic-whole)} = 1.2‰) can be distinguished from the type 2 chondrites Murchison (δ⁷Li_{(whole rock)} = 3.8; Δ⁷Li_{(acetic-whole)} = 8.8‰) and carbonate-poor Tagish Lake (δ⁷Li_{(whole rock)} = 4.3; Δ⁷Li_{(acetic-whole)} = 9.4‰). This initial study suggests that lithium isotopes have the potential to reveal the role of liquid water in the early solar system.

We have sampled sulfide grains from one pristine CM2 chondrite (Yamato [Y-] 791198), one thermally metamorphosed CM2 chondrite (Y-793321), and two anomalous, metamorphosed CM/CI-like chondrites (Y-86720 and Belgica [B-] 7904) by the focused ion beam (FIB) technique and studied them by analytical transmission electron microscopy (TEM). Our study aims at exploring the potential of sulfide assemblages and microstructures to decipher processes and conditions of chondrite petrogenesis. Complex exsolution textures of pyrrhotite (crystallographic NC-type with N ≈ 6), troilite, and pentlandite occur in grains of Y-791198 and Y-793321. Additionally, polycrystalline 4C-pyrrhotite-pentlandite-magnetite aggregates occur in Y-791198, pointing to diverse conditions of gas–solid interactions in the solar nebula. Coarser exsolution textures of Y-793321 grains indicate higher long-term average temperatures in the <100 °C range compared to Y-791198 and other CM chondrites. Sulfide mineralogy of Y-86720 and B-7904 is dominated by aggregates of pure troilite and metal, indicating metamorphic equilibration at sulfur fugacities (fS₂) of the iron-troilite buffer. Absence of magnetite in equilibrium with sulfide and metal in Y-86720 indicates higher peak temperatures compared with B-7904, in which coexistence of troilite, metal, and magnetite constrains metamorphic temperature to less than 570 °C. NC-pyrrhotite occurs in both meteorites as nm-wide rims on troilite grains and, together with frequent anhydrite, indicates a retrograde metamorphic stage at higher fS₂ slightly above the fayalite-magnetite-quartz-pyrrhotite buffer. Fine-grained troilite-olivine intergrowths in both meteorites suggest the pre-metamorphic presence of tochilinite-serpentine interlayer phases, pointing to mineralogical CM affinity. Pseudomorphs after euhedral pyrrhotite crystals in Y-86720 in turn suggest CI affinity as do previously published O isotopic data of both meteorites.

Organic nanoglobules are microscopic spherical carbon-rich objects present in chondritic meteorites and other astromaterials. We performed a survey of the morphology, organic functional chemistry, and isotopic composition of 184 nanoglobules in insoluble organic matter (IOM) residues from seven primitive carbonaceous chondrites. Hollow and solid nanoglobules occur in each IOM residue, as well as globules with unusual shapes and structures. Most nanoglobules have an organic functional chemistry similar to, but slightly more carboxyl-rich than, the surrounding IOM, while a subset of nanoglobules have a distinct, highly aromatic functionality. The range of nanoglobule N isotopic compositions was similar to that of nonglobular ¹⁵N-rich hotspots in each IOM residue, but nanoglobules account for only about one third of the total ¹⁵N-rich hotspots in each sample. Furthermore, many nanoglobules in each residue contained no ¹⁵N enrichment above that of bulk IOM. No morphological indicators were found to robustly distinguish the highly aromatic nanoglobules from those that have a more IOM-like functional chemistry, or to distinguish ¹⁵N-rich nanoglobules from those that are isotopically normal. The relative abundance of aromatic nanoglobules was lower, and nanoglobule diameters were greater, in more altered meteorites, suggesting the creation/modification of IOM-like nanoglobules during parent-body processing. However, ¹⁵N-rich nanoglobules, including many with highly aromatic functional chemistry, likely reflect preaccretionary isotopic fractionation in cold molecular cloud or protostellar environments. These data indicate that no single formation mechanism can explain all of the observed characteristics of nanoglobules, and their properties are likely a result of multiple processes occurring in a variety of environments.