Ferrocene: Ironclad History or Rashomon Tale?
Abstract
What really happened? To recount a pivotal 20th century chemical discovery, the assignment of its structure to ferrocene, ain't easy! One might have thought that telling the story would be straightforward, from published papers and correspondence with some of their authors. Not so. One emerges with a good bit of sympathy for historians of science—who did just what and why is pretty hard to determine, even when less than fifty years have elapsed.
Number of times cited: 40
- Matthias Reiners, Dirk Baabe, Peter Schweyen, Matthias Freytag, Peter G. Jones and Marc D. Walter, Teaching Ferrocenium How to Relax: A Systematic Study on Spin–Lattice Relaxation Processes in tert‐Butyl‐Substituted Ferrocenium Derivatives, European Journal of Inorganic Chemistry, 2017, 2, (388-400), (2016).
- Didier Astruc, Why is Ferrocene so Exceptional?, European Journal of Inorganic Chemistry, 2017, 1, (6-29), (2016).
- Petr Štěpnička, The Multifaceted Chemistry of Ferrocene, European Journal of Inorganic Chemistry, 2017, 2, (215-216), (2016).
- Jun Okuda, Ferrocene – 65 Years After, European Journal of Inorganic Chemistry, 2017, 2, (217-219), (2016).
- Alexander Yu. Rulev, Serendipity or the art of making discoveries, New Journal of Chemistry, 10.1039/C7NJ00182G, 41, 11, (4262-4268), (2017).
- Olga A. Gapurenko, Ruslan M. Minyaev and Vladimir I. Minkin, Nonclassical Organosilicon Compounds, Organosilicon Compounds, 10.1016/B978-0-12-801981-8.00001-0, (3-24), (2017).
- Alba Vargas-Caamal, Sudip Pan, Filiberto Ortiz-Chi, Jose Luis Cabellos, Roberto A. Boto, Julia Contreras-Garcia, Albeiro Restrepo, Pratim K. Chattaraj and Gabriel Merino, How strong are the metallocene–metallocene interactions? Cases of ferrocene, ruthenocene, and osmocene, Physical Chemistry Chemical Physics, 18, 1, (550), (2016).
- Haibin Gu, Roberto Ciganda, Sylvain Gatard, Feng Lu, Pengxiang Zhao, Jaime Ruiz and Didier Astruc, Reprint of: On metallocene-containing macromolecules and their applications, Journal of Organometallic Chemistry, 10.1016/j.jorganchem.2016.09.012, 821, (54-61), (2016).
- Errol G. Lewars, Some “Special” Topics: (Section 8.1) Solvation, (Section 8.2) Singlet Diradicals, (Section 8.3) A Note on Heavy Atoms and Transition Metals, Computational Chemistry, 10.1007/978-3-319-30916-3_8, (565-612), (2016).
- Haibin Gu, Roberto Ciganda, Sylvain Gatard, Feng Lu, Pengxiang Zhao, Jaime Ruiz and Didier Astruc, On metallocene-containing macromolecules and their applications, Journal of Organometallic Chemistry, 10.1016/j.jorganchem.2016.04.016, 813, (95-102), (2016).
- Jeffrey I. Seeman and Stuart Cantrill, Wrong but seminal, Nature Chemistry, 8, 3, (193), (2016).
- Luca Cappelletti, Luca Vaghi, Laura Rinaldi, Laura Rotolo, Giovanni Palmisano, Giancarlo Cravotto and Andrea Penoni, One-pot sonochemical synthesis of ferrocenyl derivatives via a three-component reaction in aqueous media, Ultrasonics Sonochemistry, 10.1016/j.ultsonch.2015.04.013, 27, (30-36), (2015).
- Lifen Li, Chang Xu, Baokang Jin and Longjiu Cheng, Ferrocene analogues of sandwich M(CrB 6 H 6 ) 2 : a theoretical investigation , Dalton Trans., 10.1039/C4DT01106F, 43, 30, (11739-11744), (2014).
- Gernot Frenking and Sason Shaik, Front Matter, The Chemical Bond, (I-XXV), (2014).
- Robert H. Crabtree, Pi‐Complexes, The Organometallic Chemistry of the Transition Metals, (134-162), (2014).
- Hai‐Shun Wu, Caihong Guo, Jianfeng Jia, Uwe Rosenthal and Haijun Jiao, Strain‐Free [N]Ferrocenylenes and Cyclo[10]ferrocenylene, ChemPhysChem, 14, 17, (3902-3905), (2013).
- Jennifer Malberg, Elizabeth Lupton, Eva-Maria Schnöckelborg, Bas de Bruin, Jörg Sutter, Karsten Meyer, František Hartl and Robert Wolf, Synthesis and Electronic Structure of Dissymmetrical, Naphthalene-Bridged Sandwich Complexes [Cp′Fe(μ-C 10 H 8 )MCp*] x ( x = 0, +1; M = Fe, Ru; Cp′ = η 5 -C 5 H 2 -1,2,4- t Bu 3 ; Cp* = η 5 -C 5 Me 5 ) , Organometallics, 10.1021/om4005862, 32, 20, (6040-6052), (2013).
- Helmut Werner, At Least 60 Years of Ferrocene: The Discovery and Rediscovery of the Sandwich Complexes, Angewandte Chemie International Edition, 51, 25, (6052-6058), (2012).
- Helmut Werner, , Angewandte Chemie, 124, 25, (6156-6162), (2012).
- Kirill Yu. Monakhov, Christophe Gourlaouen and Pierre Braunstein, Stabilisation of a triply-bridging cyclopentadienyl ligand in a tetrapalladium cluster, Chemical Communications, 10.1039/c2cc32886k, 48, 67, (8317), (2012).
- Abril C. Castro, Mikael P. Johansson, Gabriel Merino and Marcel Swart, Chemical bonding in supermolecular flowers, Physical Chemistry Chemical Physics, 10.1039/c2cp42045g, 14, 43, (14905), (2012).
- Kelling J. Donald and Matthew Bober, Predicting the Relative Stability of Simple versus ansa‐Sandwich Systems Across Groups: Structure, Bonding, and (In)Stability in Tris(sandwich)benzene Complexes, Chemistry – A European Journal, 17, 6, (1936-1945), (2011).
- Caroline M. Knapp, Joseph S. Large, Nicholas H. Rees and Jose M. Goicoechea, The bis(hydrogenheptaphosphide)iron(ii) dianion: a Zintl ion analogue of ferrocene?, Chemical Communications, 47, 14, (4111), (2011).
- Johann T. B. H. Jastrzebski, Jaap Boersma and Gerard Koten, Structural Organozinc Chemistry, PATAI'S Chemistry of Functional Groups, (2009).
- Gerard Koten and Johann T. B. H. Jastrzebski, Structural Organocopper Chemistry, PATAI'S Chemistry of Functional Groups, (2011).
- Susanne Büschel, Thomas Bannenberg, Cristian G. Hrib, Andreas Glöckner, Peter G. Jones and Matthias Tamm, Adduct formation of [(η7-C7H7)Hf(η5-C5H5)] with isocyanides, phosphines and N-heterocyclic carbenes: An experimental and theoretical study, Journal of Organometallic Chemistry, 10.1016/j.jorganchem.2009.01.055, 694, 7-8, (1244-1250), (2009).
- Johann T. B. H. Jastrzebski, Jaap Boersma and Gerard Van Koten, Structural Organomagnesium Chemistry, PATAI'S Chemistry of Functional Groups, (2009).
- Bernd Wrackmeyer, Elena V. Klimkina, Heidi E. Maisel, Oleg L. Tok and Max Herberhold, 57Fe NMR spectroscopy of ferrocenes derived from aminoferrocene and 1,1′‐diaminoferrocene, Magnetic Resonance in Chemistry, 46, S1, (S30-S35), (2008).
- Marcella Gagliardo, Dennis J. M. Snelders, Preston A. Chase, Robertus J. M. Klein Gebbink, Gerard P. M. van Klink and Gerard van Koten, Organic Transformations on σ‐Aryl Organometallic Complexes, Angewandte Chemie International Edition, 46, 45, (8558-8573), (2007).
- Marcella Gagliardo, Dennis J. M. Snelders, Preston A. Chase, Robertus J. M. Klein Gebbink, Gerard P. M. van Klink and Gerard van Koten, Organische Umsetzungen an metallorganischen σ‐Aryl‐Komplexen, Angewandte Chemie, 119, 45, (8710-8726), (2007).
- Sason Shaik, Is my chemical universe localized or delocalized? is there a future for chemical concepts?, New Journal of Chemistry, 10.1039/b711641c, 31, 12, (2015), (2007).
- Antonio Frontera, David Quiñonero, Carolina Garau, Pere M. Deyà and Fabio Pichierri, Affinity of ferrocene and (1,1′)(3,3′)[3,3]ferrocenophane to cations, Chemical Physics Letters, 424, 1-3, (204), (2006).
- Teodoro S. Kaufman and Edmundo A. Rúveda, The Quest for Quinine: Those Who Won the Battles and Those Who Won the War, Angewandte Chemie International Edition, 44, 6, (854-885), (2005).
- Teodoro S. Kaufman and Edmundo A. Rúveda, Die Jagd auf Chinin: Etappenerfolge und Gesamtsiege, Angewandte Chemie, 117, 6, (876-907), (2005).
- Jay A. Labinger and Steve J. Weininger, , Angewandte Chemie, 116, 20, (2664-2672), (2004).
- Jay A. Labinger and Steve J. Weininger, Controversy in Chemistry: What Counts as Evidence?—Two Studies in Molecular Structure, Angewandte Chemie International Edition, 43, 20, (2612-2619), (2004).
- Holger Glas, Anna-Katharina Pleier, Eberhardt Herdtweck and Werner R Thiel, 2-(3-Ferrocenylpyrazol-1-yl)cyclohexanol: a new building block for ferrocenyl ligands, Journal of Organometallic Chemistry, 10.1016/S0022-328X(03)00773-3, 684, 1-2, (376-380), (2003).
- Martin Diefenbach and Helmut Schwarz, Cationic Transition Metal Arene Interactions, Encyclopedia of Computational Chemistry, (2004).
- Pierre Laszlo, Eine Geschichte des Diborans, Angewandte Chemie, 112, 12, (2151-2152), (2000).
- Pierre Laszlo and Roald Hoffmann, ChemInform Abstract: Ferrocene: Ironclad History or Rashomon Tale?, ChemInform, 31, 12, (2010).



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