Article
A Cathodic Stripping Square‐Wave Voltammetry of a Second‐Order Redox Reaction and Its Application to the Mercury‐Cysteine System
First published: 09 February 1999
Abstract
A model of cathodic stripping square‐wave voltammetry of a second‐order redox reaction is developed. Both reversible and quasireversible redox reactions are considered. The relationships between the properties of SWV response and both parameters of the redox reaction and the SWV excitation signal are analyzed. The effect of the concentration of the reacting ligand on the SW voltammograms is discussed. The phenomenon of a quasireversible maximum is demonstrated. Numerical simulations are compared qualitatively with the cathodic stripping square‐wave voltammetric response of cysteine.
Citing Literature
Number of times cited: 4
- Valentin Mirčeski, Dariusz Guziejewski and Witold Ciesielski, Theoretical Treatment of a Cathodic Stripping Mechanism of an Insoluble Salt Coupled with a Chemical Reaction in Conditions of Square Wave Voltammetry. Application to 6‐Mercaptopurine‐9‐D‐Riboside in the Presence of Ni(II), Electroanalysis, 23, 6, (1365-1375), (2011).
- Fernando Cruz Moraes, Sonia Tomie Tanimoto, Giancarlo Richard Salazar‐Banda, Sergio Antonio Spinola Machado and Lucia Helena Mascaro, A New Indirect Electroanalytical Method to Monitor the Contamination of Natural Waters with 4‐Nitrophenol Using Multiwall Carbon Nanotubes, Electroanalysis, 21, 9, (1091-1098), (2009).
- Valentin Mirčeski, Sławomira Skrzypek and Milivoj Lovrić, Cathodic Stripping Voltammetry of Uracil. Experimental and Theoretical Study Under Conditions of Square‐Wave Voltammetry, Electroanalysis, 21, 1, (87-95), (2008).
- Rubin Gulaboski, Valentin Mirčeski and Šebojka Komorsky‐Lovrić , Square‐Wave Voltammetry of a Second Order Cathodic Stripping Process Coupled by Adsorption of the Reacting Ligand, Electroanalysis, 14, 5, (345-355), (2002).
