The full text of this article hosted at iucr.org is unavailable due to technical difficulties.

Advanced Engineering Materials

Volume 7, Issue 5
Communication

Thermoplastic Extrusion to Highly‐Loaded Thin Green Fibres Containing Pb(Zr,Ti)O3*

J. Heiber

E-mail address:juliane.heiber@EMPA.ch

Laboratory for High Performance Ceramics, Empa Materials Science and Technology, Ueberlandstrasse 129, CH‐8600 Duebendorf, Switzerland

Search for more papers by this author
F. Clemens

Laboratory for High Performance Ceramics, Empa Materials Science and Technology, Ueberlandstrasse 129, CH‐8600 Duebendorf, Switzerland

Search for more papers by this author
T. Graule

Laboratory for High Performance Ceramics, Empa Materials Science and Technology, Ueberlandstrasse 129, CH‐8600 Duebendorf, Switzerland

Search for more papers by this author
D. Hülsenberg

E-mail address:Dagmar.Huelsenberg@TU‐Ilmenau.de

Department for Glass and Ceramic Technologies, Technical University of Ilmenau, Gustav‐Kirchhoff‐Straße 6, D‐98684 Ilmenau, Germany

Search for more papers by this author
First published: 31 May 2005
https://doi.org/10.1002/adem.200500052
Cited by: 32
*

Thanks are extended to the Centre of Structure Technologies, ETH‐Zürich, for permitting access to their equipment, and to A. Belloli for assisting with the piezoelectric characterisation.

Abstract

en

Because of their piezoelectric properties lead zirconate titanate (PZT) fibres are used in several electronic applications. Such fibres can be produced by extrusion. Therefore the extrusion behaviour of highly loaded thermoplastic feedstocks (PZT‐polymer compound) has been investigated depending on the surfactant concentration and the powder preparation method. After sintering butterfly curves were measured for single fibres.

Number of times cited: 32

  • Tony Lusiola, Alberto Soppelsa, Fernando Rubio-Marcos, José F. Fernandez and Frank Clemens, The impact of microstructure in (K,Na)NbO3-based lead-Free piezoelectric fibers: From processing to device production for structural health monitoring, Journal of the European Ceramic Society, 10.1016/j.jeurceramsoc.2016.04.009, 36, 11, (2745-2754), (2016).
    Crossref
  • Laricy Janaína Dias do Amaral, Fernanda Trindade Gonzalez Dias, Janete Eunice Zorzi and Robinson Carlos Dudley Cruz, Obtenção de amidos termoplásticos para a extrusão de pós cerâmicos, Polímeros, 26, spe, (60), (2016).
    Crossref
  • Tony Lusiola and Frank Clemens, Fabrication of One‐Dimensional Ferroelectric Nano‐ and Microstructures by Different Spinning Techniques and Their Characterization, Nanoscale Ferroelectrics and Multiferroics, (232-268), (2016).
    Wiley Online Library
  • Lucjan Kozielski, F. Clemens, T. Lusiola and M. Pilch, Uniaxial extrusion as an enhancement method of piezoelectric properties of ceramic micro fibers, Journal of Alloys and Compounds, 687, (604), (2016).
    Crossref
  • D.K. Ramachandran, K. Kwok, M. Søgaard, F. Clemens, A.J. Glasscock and A. Kaiser, The role of sacrificial fugitives in thermoplastic extrusion feedstocks on properties of MgO supports for oxygen transport membranes, Journal of the European Ceramic Society, 35, 5, (1527), (2015).
    Crossref
  • Vaia Adamaki, A. Sergejevs, C. Clarke, F. Clemens, F. Marken and C. R. Bowen, Sub-stoichiometric functionally graded titania fibres for water-splitting applications, Journal of Semiconductors, 36, 6, (063001), (2015).
    Crossref
  • Mehdi Salehi, Ewald M. Pfaff, Anke Kaletsch, Thomas Graule, Frank Clemens and Bernard Grobéty, Manufacturing of Tubular Dead‐End Membranes by Continuous Thermoplastic Extrusion, International Journal of Applied Ceramic Technology, 12, S2, (E13-E18), (2013).
    Wiley Online Library
  • Francesca Bortolani, Marina Ismael Michen, Thomas Graule and Frank Clemens, Small and large signal ferroelectric properties of single lead zirconium titanate fibers, Journal of Intelligent Material Systems and Structures, 26, 7, (865), (2015).
    Crossref
  • D.K. Ramachandran, F. Clemens, A.J. Glasscock, M. Søgaard and A. Kaiser, Tailoring the microstructure of porous MgO supports for asymmetric oxygen separation membranes: Optimization of thermoplastic feedstock systems, Ceramics International, 40, 7, (10465), (2014).
    Crossref
  • Horng-Yi Chang, Chung-Hao Yi, Chia-Hsin Lin and Syh-Yuh Cheng, Surface-condensed piezoelectric fibers and composites, Materials Chemistry and Physics, 148, 3, (512), (2014).
    Crossref
  • Lucjan Kozielski, Elena Buixaderas and Frank Clemens, Rhombohedral PLZT piezoelectric microfibers: a combined Raman and X-ray diffraction study, Phase Transitions, 87, 10-11, (982), (2014).
    Crossref
  • Vaia Adamaki, Frank Clemens, John Taylor, Tim J. Mays and Christopher R. Bowen, Re-oxidation mechanism and kinetics of fine scale Ti-Magnéli phases in fibre form using thermo-gravimetric analysis, Journal of Materials Science, 49, 21, (7597), (2014).
    Crossref
  • John W. Halloran, Nonconventional Polymers in Ceramic Processing: Thermoplastics and Monomers, Ceramics Science and Technology, (395-413), (2014).
    Wiley Online Library
  • T. Lusiola, D. Scharf, T. Graule and F. Clemens, Low shear compounding process for thermoplastic fabrication of ferroelectric lead-free fibres, Journal of the European Ceramic Society, 34, 10, (2265), (2014).
    Crossref
  • V. Adamaki, F. Clemens, P. Ragulis, S. R. Pennock, J. Taylor and C. R. Bowen, Manufacturing and characterization of Magnéli phase conductive fibres, J. Mater. Chem. A, 2, 22, (8328), (2014).
    Crossref
  • R.T. Cruz, S.R. Bragança, C.P. Bergmann, T. Graule and F. Clemens, Preparation of Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) feedstocks with different thermoplastic binders and their use in the production of thin tubular membranes by extrusion, Ceramics International, 40, 5, (7531), (2014).
    Crossref
  • Francesca Bortolani, Adolfo del Campo, José F. Fernandez, Frank Clemens and Fernando Rubio-Marcos, High Strain in (K,Na)NbO 3 -Based Lead-Free Piezoelectric Fibers , Chemistry of Materials, 10.1021/cm501538x, 26, 12, (3838-3848), (2014).
    Crossref
  • Mehdi Salehi, Frank Clemens, Eugenio H. Otal, Davide Ferri, Thomas Graule and Bernard Grobéty, Debinding Mechanisms in Thermoplastic processing of a Ba0.5Sr0.5Co0.8Fe0.2O3−‐ Stearic Acid–Polystyrene Mixture, ChemSusChem, 6, 2, (336-344), (2012).
    Wiley Online Library
  • Robert Dittmer, Kyle G. Webber, Emil Aulbach, Wook Jo, Xiaoli Tan and Jürgen Rödel, Electric-field-induced polarization and strain in 0.94(Bi1/2Na1/2)TiO3–0.06BaTiO3 under uniaxial stress, Acta Materialia, 61, 4, (1350), (2013).
    Crossref
  • Lucjan Kozielski, Jiri Erhart and Frank Clemens, Light-Intensity-Induced Characterization of Elastic Constants and d33 Piezoelectric Coefficient of PLZT Single Fiber Based Transducers, Sensors, 13, 12, (2419), (2013).
    Crossref
  • Mehdi Salehi, Ewald M. Pfaff, Roberto Morkis Junior, Carlos P. Bergmann, Stefan Diethelm, Christoph Neururer, Thomas Graule, Bernard Grobéty and Frank Jörg Clemens, Ba0.5Sr0.5Co0.8Fe0.2O3−δ (BSCF) feedstock development and optimization for thermoplastic forming of thin planar and tubular oxygen separation membranes, Journal of Membrane Science, 10.1016/j.memsci.2013.04.051, 443, (237-245), (2013).
    Crossref
  • John W. Halloran, Nonconventional Polymers in Ceramic Processing: Thermoplastics and Monomers, Ceramics Science and Technology, (395-413), (2012).
    Wiley Online Library
  • Marina R. Ismael, Frank Clemens, Peter Wyss, Thomas Graule, Michael J. Hoffmann and N. Alford, Processing and Properties of Co‐Extruded Lead Zirconate Titanate Fibers, Journal of the American Ceramic Society, 95, 1, (108-116), (2011).
    Wiley Online Library
  • Nini Pryds, Frank Clemens, Mohan Menon, Pernille H. Nielsen, Karen Brodersen, Rasmus Bjørk, Christian R. H. Bahl, Kurt Engelbrecht, Kaspar K. Nielsen and Anders Smith, A Monolithic Perovskite Structure for Use as a Magnetic Regenerator, Journal of the American Ceramic Society, 94, 8, (2549-2555), (2011).
    Wiley Online Library
  • M.R. Ismael, F. Clemens, T. Graule and M.J. Hoffmann, Effects of different thermoplastic binders on the processability of feedstocks for ceramic co-extrusion process, Ceramics International, 37, 8, (3173), (2011).
    Crossref
  • F. Clemens, T. Comyn, J. Heiber, F. Nobre, A. C. E. Dent and C. R. Bowen, Processing and electromechanical properties of lanthanum-doped Pb(Zr,Ti)O3 extruded piezoelectric fibres, Journal of Materials Science, 46, 13, (4517), (2011).
    Crossref
  • R. Steinhausen, S. Kern, C. Pientschke, H. Beige, F. Clemens and J. Heiber, A new measurement method of piezoelectric properties of single ceramic fibres, Journal of the European Ceramic Society, 30, 2, (205), (2010).
    Crossref
  • L Kozielski, E Buixaderas, F Clemens and R Bujakiewicz-Korońska, PZT Microfibre defect structure studied by Raman spectroscopy, Journal of Physics D: Applied Physics, 43, 41, (415401), (2010).
    Crossref
    • 2009 18th IEEE International Symposium on the Applications of Ferroelectrics (ISAF) Xian, China 2009 18th IEEE International Symposium on the Applications of Ferroelectrics IEEE , (2009). M. R. Ismael, F. Clemens, P. Wyss, T. Graule and M. J. Hoffmann Processing, microstructure and electromechanical properties of Pb(Zr, Ti)O3 fibers obtained by thermoplastic co-extrusion , (2009). 1 4 5307603 , 10.1109/ISAF.2009.5307603 http://ieeexplore.ieee.org/document/5307603/
  • M.R. Ismael, F. Clemens, W.M. Bohac, T. Graule and M.J. Hoffmann, Effects of rheology on the interface of Pb(Zr, Ti)O3 monofilament composites obtained by co-extrusion, Journal of the European Ceramic Society, 29, 14, (3015), (2009).
    Crossref
  • Juliane Heiber, Alberto Belloli, Paolo Ermanni and Frank Clemens, Ferroelectric Characterization of Single PZT Fibers, Journal of Intelligent Material Systems and Structures, 20, 4, (379), (2009).
    Crossref
  • J. Heiber, F. Clemens, U. Helbig, A. de Meuron, Ch. Soltmann, T. Graule and D. Hülsenberg, Properties of Pb(Zr,Ti)O3 fibres with a radial gradient structure, Acta Materialia, 55, 19, (6499), (2007).
    Crossref