Strain Sensors with a High Sensitivity and a Wide Sensing Range Based on a Ti3C2Tx (MXene) Nanoparticle–Nanosheet Hybrid Network
Abstract
A high sensitivity and large stretchability are desirable for strain sensors in wearable applications. However, these two performance indicators are contradictory, since the former requires a conspicuous structural change under a tiny strain, whereas the latter demands morphological integrity upon a large deformation. Developing strain sensors with both a high sensitivity (gauge factor (GF) > 100) and a broad strain range (>50%) is a considerable challenge. Herein, a unique Ti3C2Tx MXene nanoparticle–nanosheet hybrid network is constructed. The migration of nanoparticles leads to a large resistance variation while the wrapping of nanosheet bridges the detached nanoparticles to maintain the connectivity of the conductive pathways in a large strain region. The synergetic motion of nanoparticles and nanosheets endows the hybrid network with splendid electrical–mechanical performance, which is reflected in its high sensitivity (GF > 178.4) over the entire broad range (53%), the super low detection limit (0.025%), and a good cycling durability (over 5000 cycles). Such high performance endows the strain sensor with the capability for full‐range human motion detection.
Citing Literature
Number of times cited according to CrossRef: 14
- Yiran Li, Na Li, Shijun Zhao, Jun Fan, Ji-Jung Kai, Strain-tunable electronic properties and lithium storage of 2D transition metal carbide (MXene) Ti 2 CO 2 as a flexible electrode , Journal of Materials Chemistry A, 10.1039/C9TA09185H, (2020).
- Hyejin Hwang, Yohann Kim, Jae‐Hoon Park, Unyong Jeong, 2D Percolation Design with Conductive Microparticles for Low‐Strain Detection in a Stretchable Sensor, Advanced Functional Materials, 10.1002/adfm.201908514, 30, 13, (2020).
- Hao Tang, Yina Yang, Ranran Wang, Jing Sun, Improving the properties of 2D titanium carbide films by thermal treatment, Journal of Materials Chemistry C, 10.1039/C9TC07018D, (2020).
- Jun-Hong Pu, Xing Zhao, Xiang-Jun Zha, Wu-Di Li, Kai Ke, Rui-Ying Bao, Zheng-Ying Liu, Ming-Bo Yang, Wei Yang, A strain localization directed crack control strategy for designing MXene-based customizable sensitivity and sensing range strain sensors for full-range human motion monitoring, Nano Energy, 10.1016/j.nanoen.2020.104814, (104814), (2020).
- Xiaoxu Xie, Hong Huang, Jing Zhu, Junrong Yu, Yan Wang, Zuming Hu, A spirally layered carbon nanotube-graphene/polyurethane composite yarn for highly sensitive and stretchable strain sensor, Composites Part A: Applied Science and Manufacturing, 10.1016/j.compositesa.2020.105932, (105932), (2020).
- Xiaoyong Chen, Yaoyu Zhao, Longzhi Li, Yuhang Wang, Jiale Wang, Jijun Xiong, Shuanli Du, Ping Zhang, Xiaorong Shi, Jinhong Yu, MXene/Polymer Nanocomposites: Preparation, Properties, and Applications, Polymer Reviews, 10.1080/15583724.2020.1729179, (1-36), (2020).
- Ming Xin, Jiean Li, Zhong Ma, Lijia Pan, Yi Shi, MXenes and Their Applications in Wearable Sensors, Frontiers in Chemistry, 10.3389/fchem.2020.00297, 8, (2020).
- Yanjing Zhang, Pei He, Meng Luo, Xiaowen Xu, Guozhang Dai, Junliang Yang, Highly stretchable polymer/silver nanowires composite sensor for human health monitoring, Nano Research, 10.1007/s12274-020-2730-z, (2020).
- Hyo‐Ryoung Lim, Hee Seok Kim, Raza Qazi, Young‐Tae Kwon, Jae‐Woong Jeong, Woon‐Hong Yeo, Advanced Soft Materials, Sensor Integrations, and Applications of Wearable Flexible Hybrid Electronics in Healthcare, Energy, and Environment, Advanced Materials, 10.1002/adma.201901924, 32, 15, (2019).
- Hu Liu, Qianming Li, Yibing Bu, Na Zhang, Chunfeng Wang, Caofeng Pan, Liwei Mi, Zhanhu Guo, Chuntai Liu, Changyu Shen, Stretchable conductive nonwoven fabrics with self-cleaning capability for tunable wearable strain sensor, Nano Energy, 10.1016/j.nanoen.2019.104143, (104143), (2019).
- Yangchengyi Liu, Hanghai Fan, Kan Li, Nie Zhao, Shangda Chen, Yinji Ma, Xiaoping Ouyang, Xiufeng Wang, Strain‐Isolation Bridge Structure to Improve Stretchability of Highly Sensitive Strain Sensors, Advanced Materials Technologies, 10.1002/admt.201900309, 4, 9, (2019).
- Tao Huang, Peng He, Ranran Wang, Siwei Yang, Jing Sun, Xiaoming Xie, Guqiao Ding, Porous Fibers Composed of Polymer Nanoball Decorated Graphene for Wearable and Highly Sensitive Strain Sensors, Advanced Functional Materials, 10.1002/adfm.201903732, 29, 45, (2019).
- Yina Yang, Zherui Cao, Peng He, Liangjing Shi, Guqiao Ding, Ranran Wang, Jing Sun, Ti3C2Tx MXene-graphene composite films for wearable strain sensors featured with high sensitivity and large range of linear response, Nano Energy, 10.1016/j.nanoen.2019.104134, (104134), (2019).
- Conor S Boland, Stumbling through the Research Wilderness, Standard Methods to Shine Light on Electrically Conductive Nanocomposites for Future Health-Care Monitoring, ACS Nano, 10.1021/acsnano.9b06847, (2019).




