The full text of this article hosted at iucr.org is unavailable due to technical difficulties.

Zuschrift

Cadiot–Chodkiewicz Active Template Synthesis of Rotaxanes and Switchable Molecular Shuttles with Weak Intercomponent Interactions*

José Berná Dr.

School of Chemistry, The University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh EH9 3JJ, UK, Fax: (+44) 131‐650‐6453 http://www.catenane.net

Search for more papers by this author
Stephen M. Goldup Dr.

School of Chemistry, The University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh EH9 3JJ, UK, Fax: (+44) 131‐650‐6453 http://www.catenane.net

Search for more papers by this author
Ai‐Lan Lee Dr.

School of Chemistry, The University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh EH9 3JJ, UK, Fax: (+44) 131‐650‐6453 http://www.catenane.net

Search for more papers by this author
David A. Leigh Prof.

E-mail address:David.Leigh@ed.ac.uk

School of Chemistry, The University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh EH9 3JJ, UK, Fax: (+44) 131‐650‐6453 http://www.catenane.net

Search for more papers by this author
Mark D. Symes

School of Chemistry, The University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh EH9 3JJ, UK, Fax: (+44) 131‐650‐6453 http://www.catenane.net

Search for more papers by this author
Gilberto Teobaldi Dr.

Dipartimento di Chimica “G. Ciamician”, Università di Bologna via F. Selmi 2, 40126 Bologna, Italy, Fax: (+39) 051‐209‐9456 http://www.ciam.unibo.it/sitcon/

Search for more papers by this author
Francesco Zerbetto Prof.

E-mail address:Francesco.Zerbetto@unibo.it

Dipartimento di Chimica “G. Ciamician”, Università di Bologna via F. Selmi 2, 40126 Bologna, Italy, Fax: (+39) 051‐209‐9456 http://www.ciam.unibo.it/sitcon/

Search for more papers by this author
First published: 29 April 2008
Cited by: 18
*

This work was supported by the European Union project STAG and the EPSRC. D.A.L. is an EPSRC Senior Research Fellow and holds a Royal Society‐Wolfson Research Merit Award.

Abstract

Zügiger Pendelverkehr: Schwach wechselwirkende, schaltbare, rotaxanbasierte molekulare Shuttles, in denen die Stationen des Makrocyclus jeweils durch eine einzige Wasserstoffbrücke fixiert sind, entstehen durch selektive Aktivtemplat‐Heterokupplung von funktionalisierten Alkinen mithilfe der Cadiot‐Chodkiewicz‐Reaktion.

Number of times cited: 18

  • , Cross‐Coupling Reactions to sp Carbon Atoms, Metal‐Catalyzed Cross‐Coupling Reactions and More, (665-762), (2013).
  • , Molecular Shuttling of a Compact and Rigid H‐Shaped [2]Rotaxane, Angewandte Chemie International Edition, 51, 9, (2168-2172), (2012).
  • , Energy Transfer and Concentration‐Dependent Conformational Modulation: A Porphyrin‐Containing [3]Rotaxane, Chemistry – An Asian Journal, 7, 10, (2429-2437), (2012).
  • , Molecular Shuttling of a Compact and Rigid H‐Shaped [2]Rotaxane, Angewandte Chemie, 124, 9, (2210-2214), (2012).
  • , [2]Catenanes Built Around Octahedral Transition‐Metal Complexes that Contain Two Intertwined Endocyclic but Non‐sterically Hindering Tridentate Ligands, Chemistry – A European Journal, 18, 18, (5565-5573), (2012).
  • , Strategien und Taktiken für die metallgesteuerte Synthese von Rotaxanen, Knoten, Catenanen und Verschlingungen höherer Ordnung, Angewandte Chemie, 123, 40, (9428-9499), (2011).
  • , Active‐Metal Template Synthesis of a Molecular Trefoil Knot, Angewandte Chemie, 123, 51, (12488-12492), (2011).
  • , Macrocycle Size Matters: “Small” Functionalized Rotaxanes in Excellent Yield Using the CuAAC Active Template Approach, Angewandte Chemie International Edition, 50, 18, (4151-4155), (2011).
  • , Active‐Metal Template Synthesis of a Molecular Trefoil Knot, Angewandte Chemie International Edition, 50, 51, (12280-12284), (2011).
  • , Macrocycle Size Matters: “Small” Functionalized Rotaxanes in Excellent Yield Using the CuAAC Active Template Approach, Angewandte Chemie, 123, 18, (4237-4241), (2011).
  • , Strategies and Tactics for the Metal‐Directed Synthesis of Rotaxanes, Knots, Catenanes, and Higher Order Links, Angewandte Chemie International Edition, 50, 40, (9260-9327), (2011).
  • , Efficient synthesis of a hetero[4]rotaxane by a “threading-stoppering-followed-by-clipping” approach, Organic & Biomolecular Chemistry, 10.1039/c001343a, 8, 11, (2594), (2010).
  • , Synthesis of [2]Catenanes by Oxidative Intramolecular Diyne Coupling Mediated by Macrocyclic Copper(I) Complexes, Angewandte Chemie, 121, 3, (512-515), (2008).
  • , Synthesis of [2]Catenanes by Oxidative Intramolecular Diyne Coupling Mediated by Macrocyclic Copper(I) Complexes, Angewandte Chemie International Edition, 48, 3, (504-507), (2008).
  • , Gold(I)‐Template Catenane and Rotaxane Synthesis, Angewandte Chemie, 120, 37, (7107-7111), (2008).
  • , An Ion‐Pair Template for Rotaxane Formation and its Exploitation in an Orthogonal Interaction Anion‐Switchable Molecular Shuttle, Angewandte Chemie, 120, 42, (8156-8159), (2008).
  • , An Ion‐Pair Template for Rotaxane Formation and its Exploitation in an Orthogonal Interaction Anion‐Switchable Molecular Shuttle, Angewandte Chemie International Edition, 47, 42, (8036-8039), (2008).
  • , Gold(I)‐Template Catenane and Rotaxane Synthesis, Angewandte Chemie International Edition, 47, 37, (6999-7003), (2008).