Volume 44, Issue 28
Communication

Multinuclear Copper Triethanolamine Complexes as Selective Catalysts for the Peroxidative Oxidation of Alkanes under Mild Conditions

Alexander M. Kirillov

Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049‐001, Lisbon, Portugal, Fax: (+351) 21‐846‐4455

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Maximilian N. Kopylovich Dr.

Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049‐001, Lisbon, Portugal, Fax: (+351) 21‐846‐4455

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Marina V. Kirillova

Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049‐001, Lisbon, Portugal, Fax: (+351) 21‐846‐4455

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Matti Haukka Dr.

Department of Chemistry, University of Joensuu, P.O. Box 111, FIN‐80101, Joensuu, Finland

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M. Fátima C. Guedes da Silva Dr.

Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049‐001, Lisbon, Portugal, Fax: (+351) 21‐846‐4455

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Armando J. L. Pombeiro Prof.

E-mail address: pombeiro@ist.utl.pt

Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, 1049‐001, Lisbon, Portugal, Fax: (+351) 21‐846‐4455

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First published: 04 July 2005
Citations: 188

This work has been partially supported by the Fundação para a Ciência e a Tecnologia and its POCTI programme (FEDER funded) (project POCTI/QUI/43415/2001), Portugal, and by a Human Resources and Mobility Marie‐Curie Research Training Network (AQUACHEM project, CMTN‐CT‐2003‐503864).

Abstract

Rich activity from a few coppers : Di‐, tri‐, tetra‐, and polynuclear copper triethanolamine complexes are easily prepared and are selective and efficient catalysts for alkane peroxidative oxidation under mild conditions (see picture).

Number of times cited according to CrossRef: 188

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