Communication
Transformation of Dipeptide‐Based Organogels into Chiral Crystals by Cryogenic Treatment
Abstract
Controlled molecular assembly is an important approach for the synthesis of single‐component materials with diverse functions. Unlike traditional heat treatment or solvent modulation, cryogenic treatment at 77 K enabled the tunable transition of a self‐assembled diphenylalanine organogel into a hexagonal crystal. Under these conditions, the assembled molecules undergo an internal rearrangement in the solid state to form a well‐defined chiral crystal structure. Moreover, these assemblies exhibit enhanced emission. This strategy for the synthesis of single‐component supramolecular assemblies can create new functions by manipulating phase transitions.
Citing Literature
Number of times cited according to CrossRef: 54
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