Volume 56, Issue 33 p. 9920-9923
Communication

Highly Bent 1,3‐Digerma‐2‐silaallene

Tomohiro Sugahara

Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto, 611-0011 Japan

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Prof. Dr. Takahiro Sasamori

Corresponding Author

Graduate School of Natural Sciences, Nagoya City University, Yamanohata 1, Mizuho-cho, Mizuho-ku, Nagoya, Aichi, 467-8501 Japan

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Prof. Dr. Norihiro Tokitoh

Corresponding Author

Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto, 611-0011 Japan

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First published: 03 July 2017
Citations: 15

Abstract

A 1,3‐digerma‐2‐silacyclopenta‐1,2‐diene, that is, a 1,3‐digerma‐2‐silaallene incorporated into a five‐membered ring system, was synthesized and obtained as a stable orange solid. Owing to incorporation into a cyclic framework, the 1,3‐digerma‐2‐silaallene moiety is highly bent, exhibiting a Si0 character for the central silicon moiety.

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