Volume 58, Issue 15
Communication

Converting Thioether Waste into Organic Semiconductors by Carbon–Sulfur Bond Activation

Ting Zhu

Center of Materials Science and Optoelectronics Engineering, College of Materials Science and Opto-Electronic Technology & CAS Center for Excellence in Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University of Chinese Academy of Sciences, Beijing, 100049 P. R. China

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Longfeng Jiang

Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China

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Dr. Ying Li

Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China

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Prof. Zengqi Xie

School of Materials Science and Engineering, South China University of Technology, Guangzhou, 510640 China

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Zijie Li

Center of Materials Science and Optoelectronics Engineering, College of Materials Science and Opto-Electronic Technology & CAS Center for Excellence in Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University of Chinese Academy of Sciences, Beijing, 100049 P. R. China

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Lei Lv

Center of Materials Science and Optoelectronics Engineering, College of Materials Science and Opto-Electronic Technology & CAS Center for Excellence in Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University of Chinese Academy of Sciences, Beijing, 100049 P. R. China

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Hao Chen

Center of Materials Science and Optoelectronics Engineering, College of Materials Science and Opto-Electronic Technology & CAS Center for Excellence in Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University of Chinese Academy of Sciences, Beijing, 100049 P. R. China

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Zhiyuan Zhao

Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China

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Prof. Lang Jiang

Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190 P. R. China

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Prof. Benzhong Tang

Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China

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Prof. Hui Huang

Corresponding Author

E-mail address: huihuang@ucas.ac.cn

Center of Materials Science and Optoelectronics Engineering, College of Materials Science and Opto-Electronic Technology & CAS Center for Excellence in Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University of Chinese Academy of Sciences, Beijing, 100049 P. R. China

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First published: 22 February 2019
Citations: 2

Abstract

A goal for human society is to convert organic waste into valuable materials. Herein, 2‐(methylthio)‐bezothiazole (MTBT), an important organic waste in urban runoff, was catalytically converted into a series of organic semiconductors through carbon–sulfur bond activation. The efficient conversion of various substrates with different aromatic moieties and reacting functional groups (tin and boron) proved the generality of this novel diarylation Liebeskind–Srogl methodology. Moreover, the resulting organic semiconductors showed excellent performance in field effect transistors and cell imaging. This contribution presents an excellent example of converting organic waste into valuable materials and may open a new avenue to utilizing widely available aromatic thioethers.

Number of times cited according to CrossRef: 2

  • Transition-metal mediated carbon–sulfur bond activation and transformations: an update, Chemical Society Reviews, 10.1039/C9CS00837C, (2020).
  • Influences of Structural Modification of Naphthalenediimides with Benzothiazole on Organic Field-Effect Transistor and Non-Fullerene Perovskite Solar Cell Characteristics, ACS Applied Materials & Interfaces, 10.1021/acsami.9b13894, (2019).

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