Converting Thioether Waste into Organic Semiconductors by Carbon–Sulfur Bond Activation
Abstract
A goal for human society is to convert organic waste into valuable materials. Herein, 2‐(methylthio)‐bezothiazole (MTBT), an important organic waste in urban runoff, was catalytically converted into a series of organic semiconductors through carbon–sulfur bond activation. The efficient conversion of various substrates with different aromatic moieties and reacting functional groups (tin and boron) proved the generality of this novel diarylation Liebeskind–Srogl methodology. Moreover, the resulting organic semiconductors showed excellent performance in field effect transistors and cell imaging. This contribution presents an excellent example of converting organic waste into valuable materials and may open a new avenue to utilizing widely available aromatic thioethers.
Citing Literature
Number of times cited according to CrossRef: 2
- Jiang Lou, Quannan Wang, Ping Wu, Hongmei Wang, Yong-Gui Zhou, Zhengkun Yu, Transition-metal mediated carbon–sulfur bond activation and transformations: an update, Chemical Society Reviews, 10.1039/C9CS00837C, (2020).
- Dada B Shaikh, Ahmed Ali Said, Zongrui Wang, Pedada Srinivasa Rao, Rajesh S Bhosale, Adrian Matthew Mak, Kexiang Zhao, Yu Zhou, Wenbo Liu, WEIBO GAO, Jian Xie, Sidhanath V Bhosale, Sheshanath V. Bhosale, Qichun Zhang, Influences of Structural Modification of Naphthalenediimides with Benzothiazole on Organic Field-Effect Transistor and Non-Fullerene Perovskite Solar Cell Characteristics, ACS Applied Materials & Interfaces, 10.1021/acsami.9b13894, (2019).




