Feature Article
Split square‐wave voltammograms of surface redox reactions
Abstract
A fast and simple method for the estimation of kinetic parameters of surface redox reactions, based on the splitting of their square‐wave voltammograms, is proposed. A mathematical procedure for simulation of these processes is developed. The method can be applied for the fast and chemically reversible redox reactions which are characterized by the kinetic parameter K ≥ 0.8 (K = ks/f). The standard rate constant, transfer coefficient and standard redox potential of the redox reaction of alizarine‐red S adsorbed on the mercury electrode in pH 9 medium are ks = 60 ± 10s−1, α = 0.45 ± 0.03 and E° = −0.810 ± 0.005V (vs. Ag/AgCl‐KCl).
Citing Literature
Number of times cited: 53
- Philippe Dauphin-Ducharme, Netzahualcóyotl Arroyo-Currás, Martin Kurnik, Gabriel Ortega, Hui Li and Kevin W. Plaxco, Simulation-Based Approach to Determining Electron Transfer Rates Using Square-Wave Voltammetry, Langmuir, 33, 18, (4407), (2017).
- Gabriela Krepper, Gastón D. Pierini, Marcelo F. Pistonesi and María S. Di Nezio, “In-situ” antimony film electrode for the determination of tetracyclines in Argentinean honey samples, Sensors and Actuators B: Chemical, 241, (560), (2017).
- Valentin Mirceski, Sylwia Smarzewska and Dariusz Guziejewski, Measuring the Electrode Kinetics of Vitamin B2 at a Constant Time Window of a Square Wave Voltammetric Experiment, Electroanalysis, 28, 2, (385-393), (2015).
- Cecilia Bonazzola and Gabriel Gordillo, Advanced analysis for electrode kinetic studies of surface reactions by applying square-wave voltammetry, Electrochimica Acta, 10.1016/j.electacta.2016.07.137, 213, (613-619), (2016).
- Valentin Mirceski, Dariusz Guziejewski, Monika Bozem and Ivan Bogeski, Characterizing electrode reactions by multisampling the current in square-wave voltammetry, Electrochimica Acta, 10.1016/j.electacta.2016.07.128, 213, (520-528), (2016).
- Megan A. Mann and Lawrence A. Bottomley, Cyclic Square Wave Voltammetry of Surface-Confined Quasireversible Electron Transfer Reactions, Langmuir, 31, 34, (9511), (2015).
- Dariusz Guziejewski, Valentin Mirceski and Dijana Jadresko, Measuring the Electrode Kinetics of Surface Confined Electrode Reactions at a Constant Scan Rate, Electroanalysis, 27, 1, (67-73), (2014).
- Francisco W.P. Ribeiro, Glaydson L.F. Mendonça, Janete E.S. Soares, Valder N. Freire, Djenaine De Souza, Paulo N.S. Casciano, Pedro de Lima-Neto and Adriana N. Correia, Exploiting the Reduction of Haloperidol: Electrochemical and Computational Studies Using Silver Amalgam and HMDE Electrodes, Electrochimica Acta, 10.1016/j.electacta.2014.06.037, 137, (564-574), (2014).
- Renata A.G. Silva, Luiz A.J. Silva, Rodrigo A.A. Munoz, Eduardo M. Richter and Aline C. Oliveira, Fast and direct determination of mancozeb through batch injection analysis with amperometric detection on boron-doped diamond electrodes, Journal of Electroanalytical Chemistry, 10.1016/j.jelechem.2014.09.025, 733, (85-90), (2014).
- Valentin Mirceski, Rubin Gulaboski, Milivoj Lovric, Ivan Bogeski, Reinhard Kappl and Markus Hoth, Square‐Wave Voltammetry: A Review on the Recent Progress, Electroanalysis, 25, 11, (2411-2422), (2013).
- Valentin Mirceski, Dariusz Guziejewski and Kiril Lisichkov, Electrode kinetic measurements with square-wave voltammetry at a constant scan rate, Electrochimica Acta, 10.1016/j.electacta.2013.10.046, 114, (667-673), (2013).
- Alvaro Yamil Tesio, Sebastián Noel Robledo, Héctor Fernández and María Alicia Zon, Electrochemical oxidation of butein at glassy carbon electrodes, Bioelectrochemistry, 91, (62), (2013).
- Valentin Mirceski, Bine Sebez, Maja Jancovska, Bozidar Ogorevc and Samo B. Hocevar, Mechanisms and kinetics of electrode processes at bismuth and antimony film and bare glassy carbon surfaces under square-wave anodic stripping voltammetry conditions, Electrochimica Acta, 105, (254), (2013).
- Francisco W.P. Ribeiro, Thiago M.B.F. Oliveira, Francisco L.F. da Silva, Glaydson L.F. Mendonça, Paula Homem-de-Mello, Helena Becker, Pedro de Lima-Neto, Adriana N. Correia and Valder Nogueira Freire, Sensitive voltammetric responses and mechanistic insights into the determination of residue levels of endosulfan in fresh foodstuffs and raw natural waters, Microchemical Journal, 110, (40), (2013).
- Valentin Mirceski, Eduardo Laborda, Dariusz Guziejewski and Richard G. Compton, New Approach to Electrode Kinetic Measurements in Square-Wave Voltammetry: Amplitude-Based Quasireversible Maximum, Analytical Chemistry, 85, 11, (5586), (2013).
- Eliana María Maza, Marcela Beatriz Moressi, Héctor Fernández and María Alicia Zon, Electrochemical oxidation of fisetin: Studies related to its adsorption on glassy carbon electrodes, Journal of Electroanalytical Chemistry, 675, (11), (2012).
- Valentin Mirceski, Samo B. Hocevar, Bozidar Ogorevc, Rubin Gulaboski and Ivan Drangov, Diagnostics of Anodic Stripping Mechanisms under Square-Wave Voltammetry Conditions Using Bismuth Film Substrates, Analytical Chemistry, 84, 10, (4429), (2012).
- Rubin Gulaboski, Valentin Mirčeski, Ivan Bogeski and Markus Hoth, Protein film voltammetry: electrochemical enzymatic spectroscopy. A review on recent progress, Journal of Solid State Electrochemistry, 16, 7, (2315), (2012).
- Patricio René Perrotta, Nelio Roberto Vettorazzi, Fernando Javier Arévalo, Adrián Marcelo Granero, Sofía Noemí Chulze, María Alicia Zón and Héctor Fernández, Electrochemical Studies of Ochratoxin A Mycotoxin at Gold Electrodes Modified with Cysteamine Self‐Assembled Monolayers. Its Ultrasensitive Quantification in Red Wine Samples, Electroanalysis, 23, 7, (1585-1592), (2011).
- Francisco Eduardo Aragão Catunda, Marcelo Francisco de Araujo, Adrian Marcelo Granero, Fernando Javier Arévalo, Mario Geraldo de Carvalho, María Alicia Zón and Héctor Fernández, The redox thermodynamics and kinetics of flavonoid rutin adsorbed at glassy carbon electrodes by stripping square wave voltammetry, Electrochimica Acta, 56, 27, (9707), (2011).
- Manuela Rueda Rueda and Francisco Prieto Dapena, Application of electrochemical impedance spectroscopy to the study of surface processes, Collection of Czechoslovak Chemical Communications, 76, 12, (1825), (2011).
- Rubin Gulaboski and Ljupčo Mihajlov, Catalytic mechanism in successive two-step protein-film voltammetry—Theoretical study in square-wave voltammetry, Biophysical Chemistry, 155, 1, (1), (2011).
- Francisco Prieto, Manuela Rueda, José Hidalgo, Elisa Martínez and Inmaculada Navarro, Electrochemical impedance spectroscopy study of a surface confined redox reaction: The reduction of azobenzene on mercury in the absence of diffusion, Electrochimica Acta, 10.1016/j.electacta.2010.12.061, 56, 23, (7916-7922), (2011).
- Francisco W.P. Ribeiro, Janete E.S. Soares, Helena Becker, Djenaine De Souza, Pedro de Lima-Neto and Adriana N. Correia, Electrochemical mechanism and kinetics studies of haloperidol and its assay in commercial formulations, Electrochimica Acta, 56, 5, (2036), (2011).
- Eduardo Alejandro Ramírez, María Alicia Zón, Paola Andrea Jara Ulloa, Juan Arturo Squella, Luis Nuñez Vergara and Héctor Fernández, Adsorption of ochratoxin A (OTA) anodic oxidation product on glassy carbon electrodes in highly acidic reaction media: Its thermodynamic and kinetics characterization, Electrochimica Acta, 55, 3, (771), (2010).
- Michael J. Bonné, Ewan Galbraith, Tony D. James, Matthew J. Wasbrough, Karen J. Edler, A. Toby A. Jenkins, Matthew Helton, Anthony McKee, Wim Thielemans, Elefteria Psillakis and Frank Marken, Boronic aciddendrimerreceptor modified nanofibrillar cellulose membranes, J. Mater. Chem., 10.1039/B918308F, 20, 3, (588-594), (2010).
- Robert W. French and Frank Marken, Growth and characterisation of diffusion junctions between paired gold electrodes: diffusion effects in generator–collector mode, Journal of Solid State Electrochemistry, 10.1007/s10008-008-0698-9, 13, 4, (609-617), (2008).
- Robert W. French, Sergey N. Gordeev, Paul R. Raithby and Frank Marken, Paired gold junction electrodes with submicrometer gap, Journal of Electroanalytical Chemistry, 632, 1-2, (206), (2009).
- Rubin Gulaboski, Surface ECE mechanism in protein film voltammetry—a theoretical study under conditions of square-wave voltammetry, Journal of Solid State Electrochemistry, 13, 7, (1015), (2009).
- Rubin Gulaboski, Milivoj Lovrić, Valentin Mirčeski, Ivan Bogeski and Markus Hoth, Protein-film voltammetry: A theoretical study of the temperature effect using square-wave voltammetry, Biophysical Chemistry, 137, 1, (49), (2008).
- Fabiana D’Eramo, María Alicia Zón, Héctor Fernández, Leonides Sereno and Alejandro Heraldo Arévalo, Studies of a novel conducting polymer by cyclic and square wave voltammetries: Its synthesis and characterization, Electrochimica Acta, 53, 24, (7182), (2008).
- Himadri Roy Ghatak, Satish Kumar and P.P. Kundu, Electrode processes in black liquor electrolysis and their significance for hydrogen production, International Journal of Hydrogen Energy, 33, 12, (2904), (2008).
- Rubin Gulaboski, Milivoj Lovrić, Valentin Mirceski, Ivan Bogeski and Markus Hoth, A new rapid and simple method to determine the kinetics of electrode reactions of biologically relevant compounds from the half-peak width of the square-wave voltammograms, Biophysical Chemistry, 138, 3, (130), (2008).
- Biljana Nigović, Šebojka Komorsky‐Lovrić and Branimir Šimunić, Electroanalytical Studies of Biologically Active Azosalicylic Acid at a Hanging Mercury Drop Electrode, Electroanalysis, 17, 10, (839-845), (2005).
- Valentin Mirčeski, Sławomira Skrzypek, Witold Ciesielski and Adam Sokołowski, Theoretical and experimental study of the catalytic hydrogen evolution reaction in the presence of an adsorbed catalyst by means of square-wave voltammetry, Journal of Electroanalytical Chemistry, 585, 1, (97), (2005).
- Nancy Cristina Marchiando, María Alicia Zón and Héctor Fernández, Determination of cercosporin (CER) phytotoxin isolated from infected peanut leaves by using adsorptive stripping square wave voltammetry, Analytica Chimica Acta, 550, 1-2, (199), (2005).
- François Quentel and Valentin Mirčeski, Catalytic Adsorptive Stripping Voltammetry of Molybdenum: Redox Kinetic Measurements, Electroanalysis, 16, 20, (1690-1696), (2004).
- Valentin Mirčeski, Rubin Gulaboski and Fritz Scholz, Square-wave thin-film voltammetry: influence of uncompensated resistance and charge transfer kinetics, Journal of Electroanalytical Chemistry, 566, 2, (351), (2004).
- Valentin Mirčeski and Milivoj Lovrić, EC mechanism of an adsorbed redox couple. Volume vs surface chemical reaction, Journal of Electroanalytical Chemistry, 565, 2, (191), (2004).
- François Quentel and Valentin Mirčeski, Characterization of the Surface Electrode Reaction in the Presence of Uniform Interaction: The Case of Mo(VI) Reduction in the Presence of Phenanthroline and an Excess of Fulvic Acids, Electroanalysis, 15, 22, (1787-1794), (2003).
- Nancy Cristina Marchiando, María Alicia Zón and Héctor Fernández, Characterization of the Surface Redox Process of Adsorbed Cercosporin (CER) at Glassy Carbon Electrodes by Anodic Stripping Square‐Wave Voltammetry, Electroanalysis, 15, 1, (40-48), (2003).
- François Quentel, Valentin Mirčeski, André Laouenan, Catherine Elleouet and Christian Louis Madec, Square‐Wave Voltammetry of the Molybdenum‐1,10 Phenanthroline‐Fulvic Acids Complex: Redox Kinetics Measurements, Electroanalysis, 15, 4, (270-277), (2003).
- D.J. Gavaghan, D. Elton, K.B. Oldham and A.M. Bond, Analysis of ramped square-wave voltammetry in the frequency domain, Journal of Electroanalytical Chemistry, 512, 1-2, (1), (2001).
- Valentin Mirčeski and Milivoj Lovrić, Ohmic drop effects in square-wave voltammetry, Journal of Electroanalytical Chemistry, 497, 1-2, (114), (2001).
- Valentin Mirčeski and Rubin Gulaboski, Surface Catalytic Mechanism in Square‐Wave Voltammetry, Electroanalysis, 13, 16, (1326-1334), (2001).
- Valentin Mirčeski, Milivoj Lovrić and Rubin Gulaboski, Theoretical and experimental study of the surface redox reaction involving interactions between the adsorbed particles under conditions of square-wave voltammetry, Journal of Electroanalytical Chemistry, 515, 1-2, (91), (2001).
- Valentin Mirčeski, Square-wave voltammetry of an EC reaction of a partly adsorbed redox couple, Journal of Electroanalytical Chemistry, 508, 1-2, (138), (2001).
- Patricia Gabriela Molina, María Alicia Zón and Héctor Fernández, The Redox Kinetics of Adsorbed ATX‐I at Carbon Electrodes by Anodic Stripping Square‐Wave Voltammetry, Electroanalysis, 12, 10, (791-798), (2000).
- Arnold G. Fogg, M. Valnice B. Zanoni, Aquiles A. Barros, Jose A. Rodrigues and Brian J. Birch, Aspects of Cathodic Stripping Voltammetry at the Hanging Mercury Drop Electrode and in Non‐Mercury Disposable Sensors, Electroanalysis, 12, 15, (1227-1232), (2000).
- Valentin Mirčeski, Rubin Gulaboski, Blagoja Jordanoski and Šebojka Komorsky-Lovrić, Square-wave voltammetry of 5-fluorouracil, Journal of Electroanalytical Chemistry, 490, 1-2, (37), (2000).
- Valentin Mircčeski, Milivoj Lovrić and Blagoja Jordanoski, Redox Kinetics Measurements of Probucole Using Square‐Wave Voltammetry, Electroanalysis, 11, 9, (660-663), (1999).
- Valentin Mirčeski and Milivoj Lovrić, Square-wave voltammetry of a cathodic stripping reaction complicated by adsorption of the reacting ligand, Analytica Chimica Acta, 386, 1-2, (47), (1999).
- Dariusz Guziejewski, Square‐wave Amplitude Effect in Cathodic and Anodic Stripping Square‐wave Voltammetry, Electroanalysis, , (2018).
