Labeled 2‐deoxy‐D‐glucose analogs. 18F‐labeled 2‐deoxy‐2‐fluoro‐D‐glucose, 2‐deoxy‐2‐fluoro‐D‐mannose and 14C‐2‐deoxy‐2‐fluoro‐D‐glucose
Abstract
A convenient method for the synthesis of 18F‐2‐deoxy‐2‐fluoro‐D‐glucose (4) and 18F‐2‐deoxy‐2‐fluoro‐D‐mannose (8) by the direct fluorination of 3,4,6‐tri‐0‐acetyl‐D‐glucal with 18F‐F2 is described. 14C‐2‐deoxy‐2‐fluoro‐D‐glucose has been synthesized from 14C‐3,4,6‐tri‐0‐acetyl‐D‐glucal (from D‐[14c(U)]‐glucose) by fluorination with F2 (Method 1) and CF3OF (Method 2). These labeled analogs of 2‐deoxy‐D‐glucose were required for the study of local cerebral glucose metabolism.
Number of times cited: 191
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