Communication
Synthesis and Thermal Properties of Epoxidized Vegetable Oil
Abstract
Summary: The novel potential epoxy resins, epoxidized soybean oil (ESO) and epoxidized castor oil (ECO), were synthesized and characterized. The cationic polymerization of ESO and ECO with a latent thermal catalyst, N‐benzylpyrazinium hexafluoroantimonate (BPH), was initiated at 80 and 50 °C, respectively. The cured ECO samples showed a higher Tg and lower coefficient of thermal expansion than those of ESO, due to the higher intermolecular interaction in the ECO/BPH system.
Citing Literature
Number of times cited: 128
- Tao Fei, James A. Walker, Kevin L. Vickerman, Levi M. Stanley, Darren Jarboe and Tong Wang, Synthesis and characterization of soybean oil-based waxes and their application as paraffin substitute for corrugated coating, Journal of Industrial and Engineering Chemistry, 58, (113), (2018).
- Sushanta K. Sahoo, Vinay Khandelwal and Gaurav Manik, Development of toughened bio‐based epoxy with epoxidized linseed oil as reactive diluent and cured with bio‐renewable crosslinker, Polymers for Advanced Technologies, 29, 1, (565-574), (2017).
- Sushanta K. Sahoo, Vinay Khandelwal and Gaurav Manik, Development of completely bio‐based epoxy networks derived from epoxidized linseed and castor oil cured with citric acid, Polymers for Advanced Technologies, 29, 7, (2080-2090), (2018).
- Audrey Llevot, Sustainable Synthetic Approaches for the Preparation of Plant Oil‐Based Thermosets, Journal of the American Oil Chemists' Society, 94, 2, (169-186), (2016).
- Rachapudi B.N. Prasad and Bhamidipati V.S.K. Rao, Chemical Derivatization of Castor Oil and Their Industrial Utilization, Fatty Acids, 10.1016/B978-0-12-809521-8.00008-8, (279-303), (2017).
- O Gómez-Jiménez-Aberasturi, Eco-Friendly Materials for Chemical Products Manufacturing: Adhesives Derived from Biomass and Renewable Resources, Handbook of Ecomaterials, 10.1007/978-3-319-48281-1_154-1, (1-16), (2017).
- Debora Puglia, Fabrizio Sarasini, Carlo Santulli and José M. Kenny, Manufacturing of Natural Fiber/Agrowaste Based Polymer Composites, Green Biocomposites, 10.1007/978-3-319-46610-1_6, (125-147), (2016).
- Naci Uysal, Gokhan Acik and Mehmet Atilla Tasdelen, Soybean oil based thermoset networks via photoinduced CuAAC click chemistry, Polymer International, 66, 7, (999-1004), (2017).
- Anderson M. M. S. Medeiros, Fabricio Machado, Joel C. Rubim and Timothy F. L. McKenna, Bio‐based copolymers obtained through miniemulsion copolymerization of methyl esters of acrylated fatty acids and styrene, Journal of Polymer Science Part A: Polymer Chemistry, 55, 8, (1422-1432), (2017).
- Ghodsieh Mashouf Roudsari, Manjusri Misra and Amar K. Mohanty, A study of mechanical properties of biobased epoxy network: Effect of addition of epoxidized soybean oil and poly(furfuryl alcohol), Journal of Applied Polymer Science, 134, 1, (2016).
- Prasanta Baishya, Moon Mandal, Pankaj Gogoi and Tarun K. Maji, Natural Polymer‐Based Nanocomposites: A Greener Approach for the Future, Handbook of Composites from Renewable Materials, (433-459), (2017).
- Thomas I. J. Dugmore, James H. Clark, Julen Bustamante, Joseph A. Houghton and Avtar S. Matharu, Valorisation of Biowastes for the Production of Green Materials Using Chemical Methods, Topics in Current Chemistry, 10.1007/s41061-017-0133-8, 375, 2, (2017).
- Kemal Karadeniz, Yakup Çalıkoğlu and Mustafa Yasin Sen, A novel polyurethanes from epoxidized soybean oil synthesized by ring opening with bifunctional compounds, Polymer Bulletin, 10.1007/s00289-016-1867-0, 74, 7, (2819-2839), (2016).
- Tao Fei and Tong Wang, A review of recent development of sustainable waxes derived from vegetable oils, Current Opinion in Food Science, 16, (7), (2017).
- Moon Mandal and Tarun K. Maji, Comparative study on the properties of wood polymer composites based on different modified soybean oils, Journal of Wood Chemistry and Technology, 37, 2, (124), (2017).
- Suheyla Kocaman, Mustafa Karaman, Mehmet Gursoy and Gulnare Ahmetli, Chemical and plasma surface modification of lignocellulose coconut waste for the preparation of advanced biobased composite materials, Carbohydrate Polymers, 10.1016/j.carbpol.2016.12.016, 159, (48-57), (2017).
- M. Wasim Akhtar, Yun Seon Lee, Dong Jin Yoo and Jong Seok Kim, Alumina-graphene hybrid filled epoxy composite: Quantitative validation and enhanced thermal conductivity, Composites Part B: Engineering, 131, (184), (2017).
- Chaoqun Zhang, Thomas F. Garrison, Samy A. Madbouly and Michael R. Kessler, Recent advances in vegetable oil-based polymers and their composites, Progress in Polymer Science, 10.1016/j.progpolymsci.2016.12.009, 71, (91-143), (2017).
- N. Karak, Biopolymers for paints and surface coatings, Biopolymers and Biotech Admixtures for Eco-Efficient Construction Materials, 10.1016/B978-0-08-100214-8.00015-4, (333-368), (2016).
- Ashley Johns, Luke Gibbons, Madeline Smith, Kyle Edwards and Rafael L. Quirino, Plant Oil-Based Polyhydroxyurethanes, Bio-Based Plant Oil Polymers and Composites, 10.1016/B978-0-323-35833-0.00004-9, (55-71), (2016).
- Tolibjon S. Omonov and Jonathan M. Curtis, Plant Oil-Based Epoxy Intermediates for Polymers, Bio-Based Plant Oil Polymers and Composites, 10.1016/B978-0-323-35833-0.00007-4, (99-125), (2016).
- Chetan Tambe, Daniel Graiver and Ramani Narayan, Moisture resistance coating of packaging paper from biobased silylated soybean oil, Progress in Organic Coatings, 101, (270), (2016).
- Irum Rafique, Ayesha Kausar, Zanib Anwar and Bakhtiar Muhammad, Exploration of Epoxy Resins, Hardening Systems, and Epoxy/Carbon Nanotube Composite Designed for High Performance Materials: A Review, Polymer-Plastics Technology and Engineering, 10.1080/03602559.2015.1070874, 55, 3, (312-333), (2015).
- Yuge Zhang, Yifan Sun, Ke Xu, Zuanru Yuan, Jing Zhang, Ru Chen, Hongfeng Xie and Rongshi Cheng, Brucite modified epoxy mortar binders: Flame retardancy, thermal and mechanical characterization, Construction and Building Materials, 93, (1089), (2015).
- Yonghui Li, Donghai Wang and Xiuzhi Susan Sun, Oxirane Cleavage Kinetics of Epoxidized Soybean Oil by Water and UV‐Polymerized Resin Adhesion Properties, Journal of the American Oil Chemists' Society, 92, 1, (121-131), (2014).
- Jean‐Mathieu Pin, Nicolas Sbirrazzuoli and Alice Mija, From Epoxidized Linseed Oil to Bioresin: An Overall Approach of Epoxy/Anhydride Cross‐Linking, ChemSusChem, 8, 7, (1232-1243), (2015).
- Ming He, Jianjun Zhou, Huan Zhang, Zhenyang Luo and Jianfeng Yao, Microcrystalline cellulose as reactive reinforcing fillers for epoxidized soybean oil polymer composites, Journal of Applied Polymer Science, 132, 36, (2015).
- Soo-Jin Park, Gun-Young Heo and Fan-Long Jin, Thermal and cure shrinkage behaviors of epoxy resins cured by thermal cationic catalysts, Macromolecular Research, 10.1007/s13233-015-3028-y, 23, 2, (156-160), (2015).
- Fan-Long Jin and Soo-Jin Park, Preparation and characterization of carbon fiber-reinforced thermosetting composites: a review, Carbon letters, 16, 2, (67), (2015).
- In Kwon Hong, Gil Song Jeon and Seung Bum Lee, Thermal Durability of Neon Transformer with Diluent Mixing Ratio, Applied Chemistry for Engineering, 26, 4, (452), (2015).
- Soo-Jin Park, Kyong Yop Rhee and Fan-Long Jin, Improvement of hydrophilic properties of electrospun polyamide-imide fibrous mats by atmospheric-pressure plasma treatment, Journal of Physics and Chemistry of Solids, 78, (53), (2015).
- Mylène Stemmelen, Vincent Lapinte, Jean-Pierre Habas and Jean-Jacques Robin, Plant oil-based epoxy resins from fatty diamines and epoxidized vegetable oil, European Polymer Journal, 68, (536), (2015).
- Fan-Long Jin, Xiang Li and Soo-Jin Park, Synthesis and application of epoxy resins: A review, Journal of Industrial and Engineering Chemistry, 10.1016/j.jiec.2015.03.026, 29, (1-11), (2015).
- Soo-Jin Park, Gun-Young Heo and Fan-Long Jin, Cure behaviors and thermal stabilities of tetrafunctional epoxy resin toughened by polyamideimide, Macromolecular Research, 10.1007/s13233-015-3051-z, 23, 4, (320-324), (2015).
- Kemal Karadeniz, Hatice Akı, Mustafa Yasin Sen and Yakup Çalıkoğlu, Ring Opening of Epoxidized Soybean Oil with Compounds Containing Two Different Functional Groups, Journal of the American Oil Chemists' Society, 92, 5, (725-731), (2015).
- Zsolt Rapi, Beáta Szolnoki, Péter Bakó, Péter Niedermann, Andrea Toldy, Brigitta Bodzay, György Keglevich and György Marosi, Synthesis and characterization of biobased epoxy monomers derived from d-glucose, European Polymer Journal, 67, (375), (2015).
- Soo-Jin Park, Gun-Young Heo, Fan-Long Jin and Kyong Yop Rhee, Effect of urethane functionality and number of epoxide groups on cure and mechanical behaviors of epoxy resins, Macromolecular Research, 10.1007/s13233-015-3015-3, 23, 2, (134-138), (2015).
- Mitsuhiro Shibata, Biocomposites Composed of Bio-Based Epoxy Resins, Bio-Based Polyphenols and Lignocellulosic Fibers, Green Biorenewable Biocomposites, 10.1201/b18092-5, (111-160), (2015).
- Pu-You Jia, Cai-Ying Bo, Li-Qiang Zhang, Li-Hong Hu, Meng Zhang and Yong-Hong Zhou, Synthesis of castor oil based plasticizers containing flame retarded group and their application in poly (vinyl chloride) as secondary plasticizer, Journal of Industrial and Engineering Chemistry, 10.1016/j.jiec.2015.02.017, 28, (217-224), (2015).
- Nacú Hernández, Mengguo Yan, R. Christopher Williams and Eric Cochran, Thermoplastic Elastomers from Vegetable Oils via Reversible Addition-Fragmentation Chain Transfer Polymerization, Green Polymer Chemistry: Biobased Materials and Biocatalysis, 10.1021/bk-2015-1192.ch012, (183-199), (2015).
- Fan-Long Jin, Qing-Qing Pang, Tian-Yi Zhang and Soo-Jin Park, Synergistic reinforcing of poly(lactic acid)-based systems by polybutylene succinate and nano-calcium carbonate, Journal of Industrial and Engineering Chemistry, 10.1016/j.jiec.2015.07.021, 32, (77-84), (2015).
- W. S. Chow, S. G. Tan, Z. Ahmad, K. H. Chia, N. S. Lau and K. Sudesh, Biodegradability of Epoxidized Soybean Oil Based Thermosets in Compost Soil Environment, Journal of Polymers and the Environment, 22, 1, (140), (2014).
- S.G. Tan, Z. Ahmad and W.S. Chow, Reinforcing ability and co-catalytic effects of organo-montmorillonite clay on the epoxidized soybean oil bio-thermoset, Applied Clay Science, 10.1016/j.clay.2014.01.005, 90, (11-17), (2014).
- Stefan Naumann and Michael R. Buchmeiser, Latent and Delayed Action Polymerization Systems, Macromolecular Rapid Communications, 35, 7, (682-701), (2014).
- Seah Guan Tan, Zulkifli Ahmad and Wen Shyang Chow, Interpenetrating polymer network structured thermosets prepared from epoxidized soybean oil/diglycidyl ether of bisphenol A, Polymer International, 63, 2, (273-279), (2013).
- Chun Hua Zhao, Shun Jiang Wan, Lu Wang, Xiang Dong Liu and Takeshi Endo, Carbonyldiimidazole‐accelerated efficient cure of epoxidized soybean oil with dicyandiamide, Journal of Polymer Science Part A: Polymer Chemistry, 52, 3, (375-382), (2013).
- Yuge Zhang, Xingyu Pan, Yifan Sun, Wei Xu, Youqiang Pan, Hongfeng Xie and Rongshi Cheng, Flame retardancy, thermal, and mechanical properties of mixed flame retardant modified epoxy asphalt binders, Construction and Building Materials, 10.1016/j.conbuildmat.2014.06.028, 68, (62-67), (2014).
- Kayode Feyisetan Adekunle, Bio-Based Polymers for Technical Applications: A Review — Part 2, Open Journal of Polymer Chemistry, 04, 04, (95), (2014).
- Samy A. Madbouly, Kunwei Liu, Ying Xia and Michael R. Kessler, Semi-interpenetrating polymer networks prepared from in situ cationic polymerization of bio-based tung oil with biodegradable polycaprolactone, RSC Advances, 10.1039/c3ra46773b, 4, 13, (6710), (2014).
- Eung Su Lee, Sang Min Lee, Sang Bum Park, Jun Won Seo, Yong Han Yoon and Heon Park, Properties of Ozonized Soybean Oil/Polymeric Methylene-Diphenyl-4,4′-Diisocyanate Adhesives and Their Adhesion Performance for Wood, Forest Products Journal, 10.13073/FPJ-D-13-00029, 64, 3-4, (148-152), (2014).
- Rémi Auvergne, Sylvain Caillol, Ghislain David, Bernard Boutevin and Jean-Pierre Pascault, Biobased Thermosetting Epoxy: Present and Future, Chemical Reviews, 10.1021/cr3001274, 114, 2, (1082-1115), (2013).
- Nagarjuna Reddy Paluvai, Smita Mohanty and S. K. Nayak, Synthesis and Modifications of Epoxy Resins and Their Composites: A Review, Polymer-Plastics Technology and Engineering, 10.1080/03602559.2014.919658, 53, 16, (1723-1758), (2014).
- A.A. Abdelmalik, Chemically modified palm kernel oil ester: A possible sustainable alternative insulating fluid, Sustainable Materials and Technologies, 1-2, (42), (2014).
- Gaston Francucci, Francisco Cardona and Nathan W. Manthey, Cure kinetics of an acrylated epoxidized hemp oil‐based bioresin system, Journal of Applied Polymer Science, 128, 3, (2030-2037), (2012).
- Shu Wang, Sameer Vajjala Kesava, Enrique D. Gomez and Megan L. Robertson, Sustainable Thermoplastic Elastomers Derived from Fatty Acids, Macromolecules, 10.1021/ma4011846, 46, 18, (7202-7212), (2013).
- Vijay Thakur, Mahendra Thunga and Michael Kessler, Vegetable Oils for Green Composites, Green Composites from Natural Resources, 10.1201/b16076-17, (355-390), (2013).
- Geethanjali Gorla, Sony M. Kour, Korlipara V. Padmaja, Mallampalli S. L. Karuna and Rachapudi B. N. Prasad, Preparation and Properties of Lubricant Base Stocks from Epoxidized Karanja Oil and Its Alkyl Esters, Industrial & Engineering Chemistry Research, 10.1021/ie4024325, 52, 47, (16598-16605), (2013).
- Mitsuhiro Shibata, Bio‐Based Epoxy Resin/Clay Nanocomposites, Thermoset Nanocomposites, (189-209), (2013).
- Krzysztof Pielichowski and James Njuguna, Elastomers, Structural Materials and Processes in Transportation, (237-252), (2013).
- Juan C. Ronda, Gerard Lligadas, Marina Galià and Virginia Cádiz, A renewable approach to thermosetting resins, Reactive and Functional Polymers, 10.1016/j.reactfunctpolym.2012.03.015, 73, 2, (381-395), (2013).
- Fanica R. Mustata, Nita Tudorachi and Ioan Bicu, Biobased Epoxy Matrix from Diglycidyl Ether of Bisphenol A and Epoxidized Corn Oil, Cross-Linked with Diels–Alder Adduct of Levopimaric Acid with Acrylic Acid, Industrial & Engineering Chemistry Research, 10.1021/ie402221n, 52, 48, (17099-17110), (2013).
- Rajesh V. Sharma and Ajay K. Dalai, Synthesis of bio-lubricant from epoxy canola oil using sulfated Ti-SBA-15 catalyst, Applied Catalysis B: Environmental, 142-143, (604), (2013).
- Chao Li, Xiaoqing Liu, Jin Zhu, Chuanzhi Zhang and Jinshan Guo, Synthesis, Characterization of a Rosin-based Epoxy Monomer and its Comparison with a Petroleum-based Counterpart, Journal of Macromolecular Science, Part A, 50, 3, (321), (2013).
- Zhaoxing Liu, Lei Cao, Chunyan Bao, Shanfeng Dong, Kerong Dai and Linyong Zhu, Cross-linked vegetable oil with covalently loaded dexamethasone: linear drug release for osteogenic induction of hBMSCs in vitro, Soft Matter, 10.1039/c3sm50271f, 9, 23, (5609), (2013).
- Fan-Long Jin, Seul-Yi Lee and Soo-Jin Park, Polymer matrices for carbon fiber-reinforced polymer composites, Carbon letters, 14, 2, (76), (2013).
- Nathan W Manthey, Francisco Cardona, Gaston Francucci and Thiru Aravinthan, Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites, Journal of Reinforced Plastics and Composites, 10.1177/0731684413493030, 32, 19, (1444-1456), (2013).
- Vicent Fombuena, Sánchez‐Nácher L, Samper MD, Juárez D and Balart R, Study of the Properties of Thermoset Materials Derived from Epoxidized Soybean Oil and Protein Fillers, Journal of the American Oil Chemists' Society, 90, 3, (449-457), (2012).
- F. Mustata, N. Tudorachi and I. Bicu, Thermosetting resins obtained via sequential photo and thermal crosslinking of epoxy resins. Curing kinetics, thermal properties and morphology, Composites Part B: Engineering, 10.1016/j.compositesb.2013.07.023, 55, (470-478), (2013).
- Guozhen Yang, Brian J. Rohde and Megan L. Robertson, Hydrolytic degradation and thermal properties of epoxy resins derived from soybean oil, Green Materials, 10.1680/gmat.12.00023, 1, 2, (125-134), (2013).
- Jiwon Kim, Byung-seung Yim, Jong-min Kim and Jooheon Kim, The effects of functionalized graphene nanosheets on the thermal and mechanical properties of epoxy composites for anisotropic conductive adhesives (ACAs), Microelectronics Reliability, 10.1016/j.microrel.2011.11.002, 52, 3, (595-602), (2012).
- Kun Huang, Mei Li, Shouhai Li, Jianling Xia and Jinwen Zhang, Plant Oil-Based Curing Agents for Epoxies, Degradable Polymers and Materials: Principles and Practice (2nd Edition), 10.1021/bk-2012-1114.ch014, (225-234), (2012).
- B. Kollbe Ahn, Stefan Kraft and X. Susan Sun, Biobased Pressure-Sensitive Adhesive Derived from Epoxidized and Dihydroxylated Oleate with Phosphoric Acid and Its Chemical Pathways, Biobased Monomers, Polymers, and Materials, 10.1021/bk-2012-1105.ch002, (15-26), (2012).
- Nathan W. Manthey, Francisco Cardona and Thiru Aravinthan, Cure kinetic study of epoxidized hemp oil cured with a multiple catalytic system, Journal of Applied Polymer Science, 125, S2, (E511-E517), (2012).
- Byung-Seung Yim, Seung-Hoon Oh, Jiwon Kim, Jooheon Kim and Jong-Min Kim, Characteristics of Graphene-Filled Solderable Isotropically Conductive Adhesive (ICA), MATERIALS TRANSACTIONS, 53, 3, (578), (2012).
- Snežana Sinadinović-Fišer, Milovan Janković and Olga Borota, Epoxidation of castor oil with peracetic acid formed in situ in the presence of an ion exchange resin, Chemical Engineering and Processing: Process Intensification, 62, (106), (2012).
- Zhaoxing Liu, Yaodong Xu, Lei Cao, Chunyan Bao, Huanghui Sun, Lei Wang, Kerong Dai and Linyong Zhu, Phosphoester cross-linked vegetable oil to construct a biodegradable and biocompatible elastomer, Soft Matter, 10.1039/c2sm25115a, 8, 21, (5888), (2012).
- Arunjunai Raj Mahendran, Günter Wuzella, Andreas Kandelbauer and Nicolai Aust, Thermal cure kinetics of epoxidized linseed oil with anhydride hardener, Journal of Thermal Analysis and Calorimetry, 107, 3, (989), (2012).
- Seung Bum Lee, Hyung Jin Lee and In Kwon Hong, Diluent filler particle size effect for thermal stability of epoxy type resin, Journal of Industrial and Engineering Chemistry, 18, 2, (635), (2012).
- N. Karak, Vegetable oil-based epoxies, Vegetable Oil-Based Polymers, 10.1533/9780857097149.180, (180-207), (2012).
- Mitsuhiro Shibata, Naozumi Teramoto and Kyohei Makino, Preparation and properties of biocomposites composed of epoxidized soybean oil, tannic acid, and microfibrillated cellulose, Journal of Applied Polymer Science, 120, 1, (273-278), (2010).
- Nathan W. Manthey, Francisco Cardona, Thiru Aravinthan and Tyson Cooney, Cure kinetics of an epoxidized hemp oil based bioresin system, Journal of Applied Polymer Science, 122, 1, (444-451), (2011).
- Michael A. R. Meier, Plant Oils as Renewable Feedstock for Polymer Science, Green Polymerization Methods, (9-27), (2011).
- Fanica Mustata, Nita Tudorachi and Dan Rosu, Curing and thermal behavior of resin matrix for composites based on epoxidized soybean oil/diglycidyl ether of bisphenol A, Composites Part B: Engineering, 10.1016/j.compositesb.2011.07.003, 42, 7, (1803-1812), (2011).
- Soo‐Jin Park and Fan‐Long Jin, Epoxy Resins: Fluorine Systems, Wiley Encyclopedia of Composites, (1-6), (2011).
- F. I. Altuna, L. H. Espósito, R. A. Ruseckaite and P. M. Stefani, Thermal and mechanical properties of anhydride‐cured epoxy resins with different contents of biobased epoxidized soybean oil, Journal of Applied Polymer Science, 120, 2, (789-798), (2010).
- Seung Woo Choi, Dong Wan Seo, Young Don Lim, Young Gi Jeong, M. S. Islam Mollah, Heon Park, Tae Whan Hong and Whan Gi Kim, Synthesis and properties of multihydroxy soybean oil from soybean oil and polymeric methylene‐diphenyl‐ 4,4′‐diisocyanate/multihydroxy soybean oil polyurethane adhesive to wood, Journal of Applied Polymer Science, 121, 2, (764-769), (2011).
- A.A. Abdelmalik, A.P. Abbott, J.C. Fothergill, S. Dodd and R.C. Harris, Synthesis of a base-stock for electrical insulating fluid based on palm kernel oil, Industrial Crops and Products, 33, 2, (532), (2011).
- A.P. Gupta, Sharif Ahmad and Anshu Dev, Modification of novel bio‐based resin‐epoxidized soybean oil by conventional epoxy resin, Polymer Engineering & Science, 51, 6, (1087-1091), (2011).
- Seung-Bum Lee and In-Kwon Hong, Thermal deformation of epoxy type resin for neon transformer housing, Journal of Industrial and Engineering Chemistry, 17, 3, (404), (2011).
- Rafael L. Quirino and Richard C. Larock, Bioplastics, Biocomposites, and Biocoatings from Natural Oils, Renewable and Sustainable Polymers, 10.1021/bk-2011-1063.ch003, (37-59), (2011).
- Amit Chatterjee, Thermoset Resins, Wiley Encyclopedia of Composites, (1-31), (2012).
- B. Kollbe Ahn, Stefan Kraft, D. Wang and X. Susan Sun, Thermally Stable, Transparent, Pressure-Sensitive Adhesives from Epoxidized and Dihydroxyl Soybean Oil, Biomacromolecules, 10.1021/bm200188u, 12, 5, (1839-1843), (2011).
- Marina Galià, Lucas Montero de Espinosa, Joan Carles Ronda, Gerard Lligadas and Virginia Cádiz, Vegetable oil‐based thermosetting polymers, European Journal of Lipid Science and Technology, 112, 1, (87-96), (2009).
- S. G. Tan and W. S. Chow, Biobased Epoxidized Vegetable Oils and Its Greener Epoxy Blends: A Review, Polymer-Plastics Technology and Engineering, 10.1080/03602559.2010.512338, 49, 15, (1581-1590), (2010).
- Xiaoqing Liu and Jinwen Zhang, High‐performance biobased epoxy derived from rosin, Polymer International, 59, 5, (607-609), (2010).
- Lucas Montero de Espinosa, Juan C. Ronda, Marina Galià and Virginia Cádiz, Quinoline‐containing networks from enone and aldehyde triglyceride derivatives, Journal of Polymer Science Part A: Polymer Chemistry, 48, 4, (869-878), (2010).
- Zoran S. Petrović, Yijin Xu, Jelena Milić, Gregory Glenn and Artur Klamczynski, Biodegradation of Thermoplastic Polyurethanes from Vegetable Oils, Journal of Polymers and the Environment, 10.1007/s10924-010-0194-z, 18, 2, (94-97), (2010).
- Ju-Long Chen, Fan-Long Jin and Soo-Jin Park, Thermal stability and impact and flexural properties of epoxy resins/epoxidized castor oil/nano-CaCO3 ternary systems, Macromolecular Research, 10.1007/s13233-010-0911-4, 18, 9, (862-867), (2010).
- Ying Xia and Richard C. Larock, Vegetable oil-based polymeric materials: synthesis, properties, and applications, Green Chemistry, 10.1039/c0gc00264j, 12, 11, (1893), (2010).
- Mitsuhiro Shibata, Naozumi Teramoto, Yoshihiro Someya and Sakuya Suzuki, Bio‐based nanocomposites composed of photo‐cured epoxidized soybean oil and supramolecular hydroxystearic acid nanofibers, Journal of Polymer Science Part B: Polymer Physics, 47, 7, (669-673), (2009).
- L. Montero de Espinosa, J. C. Ronda, M. Galià and V. Cádiz, A new route to acrylate oils: Crosslinking and properties of acrylate triglycerides from high oleic sunflower oil, Journal of Polymer Science Part A: Polymer Chemistry, 47, 4, (1159-1167), (2009).
- Yongshang Lu and Richard C. Larock, Novel Polymeric Materials from Vegetable Oils and Vinyl Monomers: Preparation, Properties, and Applications, ChemSusChem, 2, 2, (136-147), (2009).
- Yoshiro Takada, Kiyomi Shinbo, Yoshihiro Someya and Mitsuhiro Shibata, Preparation and properties of bio‐based epoxy montomorillonite nanocomposites derived from polyglycerol polyglycidyl ether and ε‐polylysine, Journal of Applied Polymer Science, 113, 1, (479-484), (2009).
- Varaporn Tanrattanakul and Pimchanok Saithai, Mechanical properties of bioplastics and bioplastic–organoclay nanocomposites prepared from epoxidized soybean oil with different epoxide contents, Journal of Applied Polymer Science, 114, 5, (3057-3067), (2009).
- Hatice Mutlu and Selim H. Kusefoglu, Synthesis and characterization of polymers from soybean oil and p‐dinitrosobenzene, Journal of Applied Polymer Science, 113, 3, (1925-1934), (2009).
- Gun-Young Heo and Soo-Jin Park, Effect of substituted trifluoromethyl groups on thermal and mechanical properties of fluorine-containing epoxy resin, Macromolecular Research, 17, 11, (870), (2009).
- Fan‐Long Jin and Soo‐Jin Park, Thermomechanical behavior of epoxy resins modified with epoxidized vegetable oils, Polymer International, 57, 4, (577-583), (2008).
- Lyubov Lukyanova, Roberto Castangia, Sophie Franceschi‐Messant, Emile Perez and Isabelle Rico‐Lattes, Soft Microporous Green Materials from Natural Soybean Oil, ChemSusChem, 1, 6, (514-518), (2008).
- L. Montero de Espinosa, J. C. Ronda, M. Galià and V. Cádiz, A new enone‐containing triglyceride derivative as precursor of thermosets from renewable resources, Journal of Polymer Science Part A: Polymer Chemistry, 46, 20, (6843-6850), (2008).
- Tsutomu Takahashi, Ken‐ichi Hirayama, Naozumi Teramoto and Mitsuhiro Shibata, Biocomposites composed of epoxidized soybean oil cured with terpene‐based acid anhydride and cellulose fibers, Journal of Applied Polymer Science, 108, 3, (1596-1602), (2008).
- Daniel P. Pfister, Jeffrey R. Baker, Phillip H. Henna, Yongshang Lu and Richard C. Larock, Preparation and properties of tung oil‐based composites using spent germ as a natural filler, Journal of Applied Polymer Science, 108, 6, (3618-3625), (2008).
- Raju Thomas, Ding Yumei, He Yuelong, Yang Le, Paula Moldenaers, Yang Weimin, Tibor Czigany and Sabu Thomas, Miscibility, morphology, thermal, and mechanical properties of a DGEBA based epoxy resin toughened with a liquid rubber, Polymer, 49, 1, (278), (2008).
- Fan-Long Jin and Soo-Jin Park, Impact-strength improvement of epoxy resins reinforced with a biodegradable polymer, Materials Science and Engineering: A, 10.1016/j.msea.2007.05.053, 478, 1-2, (402-405), (2008).
- Michael A. R. Meier, Jürgen O. Metzger and Ulrich S. Schubert, Plant oil renewable resources as green alternatives in polymer science, Chemical Society Reviews, 10.1039/b703294c, 36, 11, (1788), (2007).
- Yongshang Lu and Richard C. Larock, Fabrication, Morphology and Properties of Soybean Oil‐Based Composites Reinforced with Continuous Glass Fibers, Macromolecular Materials and Engineering, 292, 10‐11, (1085-1094), (2007).
- Marta Worzakowska, The kinetic study of the curing reaction of mono- and di-epoxides obtained during the reaction of divinylbenzene and hydrogen peroxide with acid anhydrides, Polymer, 10.1016/j.polymer.2006.12.020, 48, 4, (1148-1154), (2007).
- Liping Wang and Tong Wang, Chemical Modification of Partially Hydrogenated Vegetable Oil to Improve its Functional Properties for Candles, Journal of the American Oil Chemists' Society, 84, 12, (1149-1159), (2007).
- F. Seniha Güner, Yusuf Yağcı and A. Tuncer Erciyes, Polymers from triglyceride oils, Progress in Polymer Science, 10.1016/j.progpolymsci.2006.07.001, 31, 7, (633-670), (2006).
- Fan‐Long Jin, Mijeong Han and Soo‐Jin Park, Effect of side‐chain length of succinic anhydride on coefficient of thermal expansion behavior of epoxy resins, Polymer International, 55, 11, (1289-1295), (2006).
- Piotr Czub, Application of Modified Natural Oils as Reactive Diluents for Epoxy Resins, Macromolecular Symposia, 242, 1, (60-64), (2006).
- Piotr Czub, Characterization of an Epoxy Resin Modified with Natural Oil‐Based Reactive Diluents, Macromolecular Symposia, 245-246, 1, (533-538), (2007).
- Hélène Pelletier and Alessandro Gandini, Preparation of acrylated and urethanated triacylglycerols, European Journal of Lipid Science and Technology, 108, 5, (411), (2006).
- Soo‐Jin Park, Jun‐Gil Kang and Soo‐Han Kwon, Rheological and mechanical properties of DGEBA‐S epoxy copolymer initiated by N‐benzylquinoxalinium hexafluoroantimonate, Polymer International, 54, 6, (886-890), (2005).
- Soo‐Jin Park and Gun‐Young Heo, Effect of Alkyl Groups of Latent Cationic Catalysts on Cure and Dynamic Mechanical Behaviors of Epoxy Resins, Macromolecular Chemistry and Physics, 206, 11, (1134-1139), (2005).
- Soo-Jin Park, Fan-Long Jin and Changjin Lee, Preparation and physical properties of hollow glass microspheres-reinforced epoxy matrix resins, Materials Science and Engineering: A, 402, 1-2, (335), (2005).
- Soo-Jin Park, Fan-Long Jin, Jae-Rock Lee and Jae-Sup Shin, Cationic polymerization and physicochemical properties of a biobased epoxy resin initiated by thermally latent catalysts, European Polymer Journal, 10.1016/j.eurpolymj.2004.09.011, 41, 2, (231-237), (2005).
- Soo-Jin Park and Fan-Long Jin, Thermal stabilities and dynamic mechanical properties of sulfone-containing epoxy resin cured with anhydride, Polymer Degradation and Stability, 10.1016/j.polymdegradstab.2004.06.003, 86, 3, (515-520), (2004).
- Soo‐Jin Park, Fan‐Long Jin and Jae‐Rock Lee, Effect of Biodegradable Epoxidized Castor Oil on Physicochemical and Mechanical Properties of Epoxy Resins, Macromolecular Chemistry and Physics, 205, 15, (2048-2054), (2004).
