Mass spectrometry and natural variations of iron isotopes
Abstract
An Erratum has been published for this article in Mass Spectrometry Reviews 25: 831–832, 2006.
Although the processes that govern iron isotope variations in nature are just beginning to be understood, multiple studies attest of the virtue of this system to solve important problems in geosciences and biology. In this article, we review recent advances in the geochemistry, cosmochemistry, and biochemistry of iron isotopes. In Section 2, we briefly address the question of the nucleosynthesis of Fe isotopes. In Section 3, we describe the different methods for purifying Fe and analyzing its isotopic composition. The methods of SIMS, RIMS, and TIMS are presented but more weight is given to measurements by MC‐ICPMS. In Section 4, the isotope anomalies measured in extraterrestrial material are briefly discussed. In Section 5, we show how high temperature processes like evaporation, condensation, diffusion, reduction, and phase partitioning can affect Fe isotopic composition. In Section 6, the various low temperature processes causing Fe isotopic fractionation are presented. These involve aqueous and biologic systems. © 2006 Wiley Periodicals, Inc., Mass Spec Rev 25:515–550, 2006
Citing Literature
Number of times cited: 151
- Benjamin Eickmann, Axel Hofmann, Martin Wille, Thi Hao Bui, Boswell A. Wing and Ronny Schoenberg, Isotopic evidence for oxygenated Mesoarchaean shallow oceans, Nature Geoscience, 11, 2, (133), (2018).
- Yusuke Sawaki, Miyuki Tahata, Tsuyoshi Komiya, Takafumi Hirata, Jian Han and Degan Shu, Redox history of the Three Gorges region during the Ediacaran and Early Cambrian as indicated by the Fe isotope, Geoscience Frontiers, 9, 1, (155), (2018).
- Olivier Rouxel, Brandy Toner, Yoan Germain and Brian Glazer, Geochemical and iron isotopic insights into hydrothermal iron oxyhydroxide deposit formation at Loihi Seamount, Geochimica et Cosmochimica Acta, 220, (449), (2018).
- Andrew M. Davis, Junjun Zhang, Nicolas D. Greber, Jingya Hu, François L.H. Tissot and Nicolas Dauphas, Titanium isotopes and rare earth patterns in CAIs: Evidence for thermal processing and gas-dust decoupling in the protoplanetary disk, Geochimica et Cosmochimica Acta, 221, (275), (2018).
- Yao Guan, Xiaoming Sun, Yingzhi Ren and Xiaodong Jiang, Mineralogy, geochemistry and genesis of the polymetallic crusts and nodules from the South China Sea, Ore Geology Reviews, 89, (206), (2017).
- Zhen-Ju Zhou, Hao-Shu Tang, Yan-Jing Chen and Zheng-Le Chen, Trace elements of magnetite and iron isotopes of the Zankan iron deposit, westernmost Kunlun, China: A case study of seafloor hydrothermal iron deposits, Ore Geology Reviews, 80, (1191), (2017).
- Kejun Hou, Xudong Ma, Yanhe Li, Feng Liu and Dan Han, Chronology, geochemical, Si and Fe isotopic constraints on the origin of Huoqiu banded iron formation (BIF), southeastern margin of the North China Craton, Precambrian Research, 298, (351), (2017).
- Jessica N. Fitzsimmons, Seth G. John, Christopher M. Marsay, Colleen L. Hoffman, Sarah L. Nicholas, Brandy M. Toner, Christopher R. German and Robert M. Sherrell, Iron persistence in a distal hydrothermal plume supported by dissolved–particulate exchange, Nature Geoscience, 10, 3, (195), (2017).
- G. da Costa, A. Hofmann and A. Agangi, Provenance of Detrital Pyrite in Archean Sedimentary Rocks, Sediment Provenance, 10.1016/B978-0-12-803386-9.00018-6, (509-531), (2017).
- Chris M. Marsay, Phoebe J. Lam, Maija I. Heller, Jong-Mi Lee and Seth G. John, Distribution and isotopic signature of ligand-leachable particulate iron along the GEOTRACES GP16 East Pacific Zonal Transect, Marine Chemistry, (2017).
- Drew D. Syverson, Andrew J. Luhmann, Chunyang Tan, David M. Borrok, Kang Ding and William E. Seyfried, Fe isotope fractionation between chalcopyrite and dissolved Fe during hydrothermal recrystallization: An experimental study at 350 °C and 500 bars, Geochimica et Cosmochimica Acta, 200, (87), (2017).
- Thomas M. Holmes, Zanna Chase, Pier van der Merwe, Ashley T. Townsend and Andrew R. Bowie, Detection, dispersal and biogeochemical contribution of hydrothermal iron in the ocean, Marine and Freshwater Research, 68, 12, (2184), (2017).
- T. Günther, R. Klemd, X. Zhang, I. Horn and S. Weyer, In-situ trace element and Fe-isotope studies on magnetite of the volcanic-hosted Zhibo and Chagangnuoer iron ore deposits in the Western Tianshan, NW China, Chemical Geology, 453, (111), (2017).
- Noah Planavsky and Vincent Busigny, Stable Iron Isotopes, Encyclopedia of Geochemistry, 10.1007/978-3-319-39193-9_267-1, (1-6), (2017).
- Paolo A. Sossi and Hugh St.C. O’Neill, The effect of bonding environment on iron isotope fractionation between minerals at high temperature, Geochimica et Cosmochimica Acta, 196, (121), (2017).
- V. E. McCoy, D. Asael and N. Planavsky, Benthic iron cycling in a high‐oxygen environment: Implications for interpreting the Archean sedimentary iron isotope record, Geobiology, 15, 5, (619-627), (2017).
- Akane Ito, Tsubasa Otake, Ki-Cheol Shin, Kamar Shah Ariffin, Fei-Yee Yeoh and Tsutomu Sato, Geochemical signatures and processes in a stream contaminated by heavy mineral processing near Ipoh city, Malaysia, Applied Geochemistry, 82, (89), (2017).
- E.I. Stevenson, M.S. Fantle, S.B. Das, H.M. Williams and S.M. Aciego, The iron isotopic composition of subglacial streams draining the Greenland ice sheet, Geochimica et Cosmochimica Acta, 213, (237), (2017).
- Nicole X. Nie, Nicolas Dauphas and Richard C. Greenwood, Iron and oxygen isotope fractionation during iron UV photo-oxidation: Implications for early Earth and Mars, Earth and Planetary Science Letters, 458, (179), (2017).
- Miao Li, Yong-Sheng He, Jin-Ting Kang, Xiao-Yong Yang, Zhi-Wei He, Hui-Min Yu and Fang Huang, Why was iron lost without significant isotope fractionation during the lateritic process in tropical environments?, Geoderma, 290, (1), (2017).
- Philipp Nasemann, Melanie Gault-Ringold, Claudine H. Stirling, Andrea Koschinsky and Sylvia G. Sander, Processes affecting the isotopic composition of dissolved iron in hydrothermal plumes: A case study from the Vanuatu back-arc, Chemical Geology, 10.1016/j.chemgeo.2017.11.005, (2017).
- Stéphane Blain and Alessandro Tagliabue, Bibliography, Iron Cycle in Oceans, (91-115), (2016).
- K. Hashizume, D.L. Pinti, B. Orberger, C. Cloquet, M. Jayananda and H. Soyama, A biological switch at the ocean surface as a cause of laminations in a Precambrian iron formation, Earth and Planetary Science Letters, 446, (27), (2016).
- Florian Kurzweil, Martin Wille, Niklas Gantert, Nicolas J. Beukes and Ronny Schoenberg, Manganese oxide shuttling in pre-GOE oceans – evidence from molybdenum and iron isotopes, Earth and Planetary Science Letters, 452, (69), (2016).
- Akio Makishima, References, Thermal Ionization Mass Spectrometry (TIMS), (319-338), (2016).
- Tiffany Yesavage, Gary E. Stinchcomb, Matthew S. Fantle, Peter B. Sak, Alexander Kasznel and Susan L. Brantley, Investigation of a diabase-derived regolith profile from Pennsylvania: Mineralogy, chemistry and Fe isotope fractionation, Geoderma, 10.1016/j.geoderma.2016.03.004, 273, (83-97), (2016).
- Brandy M. Toner, Olivier J. Rouxel, Cara M. Santelli, Wolfgang Bach and Katrina J. Edwards, Iron Transformation Pathways and Redox Micro-Environments in Seafloor Sulfide-Mineral Deposits: Spatially Resolved Fe XAS and δ57/54Fe Observations, Frontiers in Microbiology, 7, (2016).
- Minako Kurisu, Yoshio Takahashi, Tsuyoshi Iizuka and Mitsuo Uematsu, Very low isotope ratio of iron in fine aerosols related to its contribution to the surface ocean, Journal of Geophysical Research: Atmospheres, 121, 18, (11,119), (2016).
- R. S. Hiebert, A. Bekker, M. G. Houlé, B. A. Wing and O. J. Rouxel, Tracing sources of crustal contamination using multiple S and Fe isotopes in the Hart komatiite-associated Ni–Cu–PGE sulfide deposit, Abitibi greenstone belt, Ontario, Canada, Mineralium Deposita, 51, 7, (919), (2016).
- J.A. Barrat, O. Rouxel, K. Wang, F. Moynier, A. Yamaguchi, A. Bischoff and J. Langlade, Early stages of core segregation recorded by Fe isotopes in an asteroidal mantle, Earth and Planetary Science Letters, 419, (93), (2015).
- Nicolas Dauphas, Franck Poitrasson, Christoph Burkhardt, Hiroshi Kobayashi and Kosuke Kurosawa, Planetary and meteoritic Mg/Si and δ 30 Si variations inherited from solar nebula chemistry, Earth and Planetary Science Letters, 427, (236), (2015).
- Feifei Zhang, Xiangkun Zhu, Bin Yan, Brian Kendall, Xi Peng, Jin Li, Thomas J. Algeo and Stephen Romaniello, Oxygenation of a Cryogenian ocean (Nanhua Basin, South China) revealed by pyrite Fe isotope compositions, Earth and Planetary Science Letters, 429, (11), (2015).
- Miyuki Tahata, Yusuke Sawaki, Kazumi Yoshiya, Manabu Nishizawa, Tsuyoshi Komiya, Takafumi Hirata, Naohiro Yoshida, Shigenori Maruyama and Brian F. Windley, The marine environments encompassing the Neoproterozoic glaciations: Evidence from C, Sr and Fe isotope ratios in the Hecla Hoek Supergroup in Svalbard, Precambrian Research, 263, (19), (2015).
- Fanny Chever, Olivier J. Rouxel, Peter L. Croot, Emmanuel Ponzevera, Kathrin Wuttig and Maureen Auro, Total dissolvable and dissolved iron isotopes in the water column of the Peru upwelling regime, Geochimica et Cosmochimica Acta, 162, (66), (2015).
- Urmidola Raye, Peir K. Pufahl, T. Kurtis Kyser, Estelle Ricard and Eric E. Hiatt, The role of sedimentology, oceanography, and alteration on the δ56Fe value of the Sokoman Iron Formation, Labrador Trough, Canada, Geochimica et Cosmochimica Acta, 164, (205), (2015).
- A. Agangi, A. Hofmann, C. Rollion-Bard, J. Marin-Carbonne, B. Cavalazzi, R. Large and S. Meffre, Gold accumulation in the Archaean Witwatersrand Basin, South Africa — Evidence from concentrically laminated pyrite, Earth-Science Reviews, 140, (27), (2015).
- Raphaelle Escoube, Olivier J. Rouxel, Oleg S. Pokrovsky, Andrew Schroth, Robert Max Holmes and Olivier F.X. Donard, Iron isotope systematics in Arctic rivers, Comptes Rendus Geoscience, 347, 7-8, (377), (2015).
- Matthew A. Marcus, Katrina J. Edwards, Bleuenn Gueguen, Sirine C. Fakra, Gregory Horn, Nicolas A. Jelinski, Olivier Rouxel, Jeffry Sorensen and Brandy M. Toner, Iron mineral structure, reactivity, and isotopic composition in a South Pacific Gyre ferromanganese nodule over 4 Ma, Geochimica et Cosmochimica Acta, 171, (61), (2015).
- Stéphane Aebischer, Christophe Cloquet, Jean Carignan, Charles Maurice and Reinhard Pienitz, Disruption of the geochemical metal cycle during mining: Multiple isotope studies of lake sediments from Schefferville, subarctic Québec, Chemical Geology, 412, (167), (2015).
- Stephan Schuth, Julia Hurraß, Carsten Münker and Tim Mansfeldt, Redox-dependent fractionation of iron isotopes in suspensions of a groundwater-influenced soil, Chemical Geology, 392, (74), (2015).
- Florian Kurzweil, Kerstin Drost, Jan Pašava, Martin Wille, Heinrich Taubald, Daniel Schoeckle and Ronny Schoenberg, Coupled sulfur, iron and molybdenum isotope data from black shales of the Teplá-Barrandian unit argue against deep ocean oxygenation during the Ediacaran, Geochimica et Cosmochimica Acta, 171, (121), (2015).
- V. A. Finlayson, J. G. Konter and L. Ma, The importance of a Ni correction with ion counter in the double spike analysis of Fe isotope compositions using a 57Fe/58Fe double spike, Geochemistry, Geophysics, Geosystems, 16, 12, (4209-4222), (2015).
- Akio Makishima, Cu Purification Using an Extraction Resin for Determination of Isotope Ratios by Multicollector ICP-MS, Chromatography, 1, 4, (96), (2014).
- Axel Hofmann, Andrey Bekker, Paul Dirks, Bleuenn Gueguen, Doug Rumble and Olivier J. Rouxel, Comparing orthomagmatic and hydrothermal mineralization models for komatiite-hosted nickel deposits in Zimbabwe using multiple-sulfur, iron, and nickel isotope data, Mineralium Deposita, 49, 1, (75), (2014).
- Marc-Alban Millet and Nicolas Dauphas, Ultra-precise titanium stable isotope measurements by double-spike high resolution MC-ICP-MS, Journal of Analytical Atomic Spectrometry, 29, 8, (1444), (2014).
- Johanna Marin-Carbonne, Claire Rollion-Bard, Andrey Bekker, Olivier Rouxel, Andrea Agangi, Barbara Cavalazzi, Cora C. Wohlgemuth-Ueberwasser, Axel Hofmann and Kevin D. McKeegan, Coupled Fe and S isotope variations in pyrite nodules from Archean shale, Earth and Planetary Science Letters, 392, (67), (2014).
- Junjun Zhang, Shichun Huang, Andrew M. Davis, Nicolas Dauphas, Akihiko Hashimoto and Stein B. Jacobsen, Calcium and titanium isotopic fractionations during evaporation, Geochimica et Cosmochimica Acta, 140, (365), (2014).
- Jelmer W. Eerkens, Gry H. Barfod, Kevin J. Vaughn, P. Ryan Williams and Charles E. Lesher, Iron isotope analysis of red and black pigments on pottery in Nasca, Peru, Archaeological and Anthropological Sciences, 6, 3, (241), (2014).
- Alisson Akerman, Franck Poitrasson, Priscia Oliva, Stéphane Audry, Jonathan Prunier and Jean-Jacques Braun, The isotopic fingerprint of Fe cycling in an equatorial soil–plant–water system: The Nsimi watershed, South Cameroon, Chemical Geology, 10.1016/j.chemgeo.2014.07.003, 385, (104-116), (2014).
- Kirsten Moeller, Ronny Schoenberg, Tor Grenne, Ingunn H. Thorseth, Kerstin Drost and Rolf B. Pedersen, Comparison of iron isotope variations in modern and Ordovician siliceous Fe oxyhydroxide deposits, Geochimica et Cosmochimica Acta, 126, (422), (2014).
- N.R. Posth, D.E. Canfield and A. Kappler, Biogenic Fe(III) minerals: From formation to diagenesis and preservation in the rock record, Earth-Science Reviews, 135, (103), (2014).
- T.D. Bullen, Metal Stable Isotopes in Weathering and Hydrology, Treatise on Geochemistry, 10.1016/B978-0-08-095975-7.00511-8, (329-359), (2014).
- Andrew J. Frierdich, Brian L. Beard, Michelle M. Scherer and Clark M. Johnson, Determination of the Fe(II)aq–magnetite equilibrium iron isotope fractionation factor using the three-isotope method and a multi-direction approach to equilibrium, Earth and Planetary Science Letters, 391, (77), (2014).
- Christopher T. Reinhard, Noah J. Planavsky, Xiangli Wang, Woodward W. Fischer, Thomas M. Johnson and Timothy W. Lyons, The isotopic composition of authigenic chromium in anoxic marine sediments: A case study from the Cariaco Basin, Earth and Planetary Science Letters, 407, (9), (2014).
- Kejun Hou, Yanhe Li, Jianfeng Gao, Feng Liu and Yan Qin, Geochemistry and Si–O–Fe isotope constraints on the origin of banded iron formations of the Yuanjiacun Formation, Lvliang Group, Shanxi, China, Ore Geology Reviews, 57, (288), (2014).
- A. Bekker, N.J. Planavsky, B. Krapež, B. Rasmussen, A. Hofmann, J.F. Slack, O.J. Rouxel and K.O. Konhauser, Iron Formations: Their Origins and Implications for Ancient Seawater Chemistry, Treatise on Geochemistry, 10.1016/B978-0-08-095975-7.00719-1, (561-628), (2014).
- Thomas Zambardi, Craig C. Lundstrom, Xiaoxiao Li and Michael McCurry, Fe and Si isotope variations at Cedar Butte volcano; insight into magmatic differentiation, Earth and Planetary Science Letters, 405, (169), (2014).
- Josh Wimpenny, Qing-Zhu Yin, Darren Tollstrup, Lie-Wen Xie and Jimin Sun, Using Mg isotope ratios to trace Cenozoic weathering changes: A case study from the Chinese Loess Plateau, Chemical Geology, 376, (31), (2014).
- Florian Scholz, Silke Severmann, James McManus and Christian Hensen, Beyond the Black Sea paradigm: The sedimentary fingerprint of an open-marine iron shuttle, Geochimica et Cosmochimica Acta, 127, (368), (2014).
- N. Dauphas, M. Roskosz, E.E. Alp, D.R. Neuville, M.Y. Hu, C.K. Sio, F.L.H. Tissot, J. Zhao, L. Tissandier, E. Médard and C. Cordier, Magma redox and structural controls on iron isotope variations in Earth's mantle and crust, Earth and Planetary Science Letters, 398, (127), (2014).
- C.R. German and W.E. Seyfried, Hydrothermal Processes, Treatise on Geochemistry, 10.1016/B978-0-08-095975-7.00607-0, (191-233), (2014).
- Jiu-Bin Chen, Vincent Busigny, Jérôme Gaillardet, Pascale Louvat and Yi-Na Wang, Iron isotopes in the Seine River (France): Natural versus anthropogenic sources, Geochimica et Cosmochimica Acta, 128, (128), (2014).
- Giana Márcia dos Santos Pinheiro, Franck Poitrasson, Francis Sondag, Gérard Cochonneau and Lucieth Cruz Vieira, Contrasting iron isotopic compositions in river suspended particulate matter: the Negro and the Amazon annual river cycles, Earth and Planetary Science Letters, 394, (168), (2014).
- Vincent Busigny, Noah J. Planavsky, Didier Jézéquel, Sean Crowe, Pascale Louvat, Julien Moureau, Eric Viollier and Timothy W. Lyons, Iron isotopes in an Archean ocean analogue, Geochimica et Cosmochimica Acta, 133, (443), (2014).
- Z. Fekiacova, S. Pichat, S. Cornu and J. Balesdent, Inferences from the vertical distribution of Fe isotopic compositions on pedogenetic processes in soils, Geoderma, 209-210, (110), (2013).
- F. Castorina, R. Petrini, A. Galic, F.F. Slejko, U. Aviani, E. Pezzetta and G. Cavazzini, The fate of iron in waters from a coastal environment impacted by metallurgical industry in Northern Italy: hydrochemistry and Fe-isotopes, Applied Geochemistry, 34, (222), (2013).
- Andrew D. Czaja, Clark M. Johnson, Brian L. Beard, Eric E. Roden, Weiqiang Li and Stephen Moorbath, Biological Fe oxidation controlled deposition of banded iron formation in the ca. 3770Ma Isua Supracrustal Belt (West Greenland), Earth and Planetary Science Letters, 363, (192), (2013).
- Corliss Kin I Sio, Nicolas Dauphas, Fang-Zhen Teng, Marc Chaussidon, Rosalind T. Helz and Mathieu Roskosz, Discerning crystal growth from diffusion profiles in zoned olivine by in situ Mg–Fe isotopic analyses, Geochimica et Cosmochimica Acta, 123, (302), (2013).
- Lingling Wu, Rebecca Poulson Brucker, Brian L. Beard, Eric E. Roden and Clark M. Johnson, Iron Isotope Characteristics of Hot Springs at Chocolate Pots, Yellowstone National Park, Astrobiology, 13, 11, (1091), (2013).
- Tim M. Conway, Angela D. Rosenberg, Jess F. Adkins and Seth G. John, A new method for precise determination of iron, zinc and cadmium stable isotope ratios in seawater by double-spike mass spectrometry, Analytica Chimica Acta, 793, (44), (2013).
- A.M. Mloszewska, S.J. Mojzsis, E. Pecoits, D. Papineau, N. Dauphas and K.O. Konhauser, Chemical sedimentary protoliths in the >3.75Ga Nuvvuagittuq Supracrustal Belt (Québec, Canada), Gondwana Research, 23, 2, (574), (2013).
- Jian Sun, Xiangkun Zhu, Suohan Tang and Yuelong Chen, Investigation of matrix effects in the MC-ICP-MS induced by Nb, W, and Cu: Isotopic case studies of iron and copper, Chinese Journal of Geochemistry, 32, 1, (1), (2013).
- Jian Sun, Xiangkun Zhu, Yuelong Chen and Nan Fang, Iron isotopic constraints on the genesis of Bayan Obo ore deposit, Inner Mongolia, China, Precambrian Research, 235, (88), (2013).
- Giana Márcia dos Santos Pinheiro, Franck Poitrasson, Francis Sondag, Lucieth Cruz Vieira and Márcio Martins Pimentel, Iron isotope composition of the suspended matter along depth and lateral profiles in the Amazon River and its tributaries, Journal of South American Earth Sciences, 10.1016/j.jsames.2012.08.001, 44, (35-44), (2013).
- Fang-Zhen Teng, Nicolas Dauphas, Shichun Huang and Bernard Marty, Iron isotopic systematics of oceanic basalts, Geochimica et Cosmochimica Acta, 107, (12), (2013).
- Akio Makishima, A Simple and Fast Separation Method of Fe Employing Extraction Resin for Isotope Ratio Determination by Multicollector ICP-MS, International Journal of Analytical Mass Spectrometry and Chromatography, 01, 02, (95), (2013).
- Myriam Telus, Nicolas Dauphas, Frédéric Moynier, François L.H. Tissot, Fang-Zhen Teng, Peter I. Nabelek, Paul R. Craddock and Lee A. Groat, Iron, zinc, magnesium and uranium isotopic fractionation during continental crust differentiation: The tale from migmatites, granitoids, and pegmatites, Geochimica et Cosmochimica Acta, 97, (247), (2012).
- Alexei V. Fedkin, Lawrence Grossman, Fred J. Ciesla and Steven B. Simon, Mineralogical and isotopic constraints on chondrule formation from shock wave thermal histories, Geochimica et Cosmochimica Acta, 87, (81), (2012).
- K.A. Kamesh Raju, Durbar Ray, Abhay Mudholkar, G.P.S. Murty, V.K. Gahalaut, Kiranmai Samudrala, A.L. Paropkari, Ratheesh Ramachandran and L. Surya Prakash, Tectonic and volcanic implications of a cratered seamount off Nicobar Island, Andaman Sea, Journal of Asian Earth Sciences, 56, (42), (2012).
- Kun Wang, Frédéric Moynier, Nicolas Dauphas, Jean-Alix Barrat, Paul Craddock and Corliss K. Sio, Iron isotope fractionation in planetary crusts, Geochimica et Cosmochimica Acta, 89, (31), (2012).
- Thomas Walczyk, The Use of Stable Isotope Techniques for Studying Mineral and Trace Element Metabolism in Humans, Isotopic Analysis, (435-494), (2012).
- N. Dauphas, M. Roskosz, E.E. Alp, D.C. Golden, C.K. Sio, F.L.H. Tissot, M.Y. Hu, J. Zhao, L. Gao and R.V. Morris, A general moment NRIXS approach to the determination of equilibrium Fe isotopic fractionation factors: Application to goethite and jarosite, Geochimica et Cosmochimica Acta, 94, (254), (2012).
- Monika Guelke-Stelling and Friedhelm von Blanckenburg, Fe isotope fractionation caused by translocation of iron during growth of bean and oat as models of strategy I and II plants, Plant and Soil, 352, 1-2, (217), (2012).
- D. Gagnevin, A.J. Boyce, C.D. Barrie, J.F. Menuge and R.J. Blakeman, Zn, Fe and S isotope fractionation in a large hydrothermal system, Geochimica et Cosmochimica Acta, 88, (183), (2012).
- Martin J. Van Kranendonk, Contributors:, Wladyslaw Altermann, Brian L. Beard, Paul F. Hoffman, Clark M. Johnson, James F. Kasting, Victor A. Melezhik, Allen P. Nutman, Dominic Papineau and Franco Pirajno, A Chronostratigraphic Division of the Precambrian, The Geologic Time Scale, 10.1016/B978-0-444-59425-9.00016-0, (299-392), (2012).
- Noah Planavsky, Olivier J. Rouxel, Andrey Bekker, Axel Hofmann, Crispin T.S. Little and Timothy W. Lyons, Iron isotope composition of some Archean and Proterozoic iron formations, Geochimica et Cosmochimica Acta, 80, (158), (2012).
- Paul R. Craddock and Nicolas Dauphas, Iron Isotopic Compositions of Geological Reference Materials and Chondrites, Geostandards and Geoanalytical Research, 35, 1, (101-123), (2010).
- Toshiyuki Fujii, Frédéric Moynier, Nicolas Dauphas and Minori Abe, Theoretical and experimental investigation of nickel isotopic fractionation in species relevant to modern and ancient oceans, Geochimica et Cosmochimica Acta, 75, 2, (469), (2011).
- Johanna Marin-Carbonne, Claire Rollion-Bard and Béatrice Luais, In-situ measurements of iron isotopes by SIMS: MC-ICP-MS intercalibration and application to a magnetite crystal from the Gunflint chert, Chemical Geology, 285, 1-4, (50), (2011).
- Mirjam Kiczka, Jan G. Wiederhold, Jakob Frommer, Andreas Voegelin, Stephan M. Kraemer, Bernard Bourdon and Ruben Kretzschmar, Iron speciation and isotope fractionation during silicate weathering and soil formation in an alpine glacier forefield chronosequence, Geochimica et Cosmochimica Acta, 75, 19, (5559), (2011).
- Donald J. DePaolo, Surface kinetic model for isotopic and trace element fractionation during precipitation of calcite from aqueous solutions, Geochimica et Cosmochimica Acta, 75, 4, (1039), (2011).
- Karin Hotz, Heinz Augsburger and Thomas Walczyk, Isotopic signatures of iron in body tissues as a potential biomarker for iron metabolism, Journal of Analytical Atomic Spectrometry, 26, 7, (1347), (2011).
- Gaëlle Saunier, Gleb S. Pokrovski and Franck Poitrasson, First experimental determination of iron isotope fractionation between hematite and aqueous solution at hydrothermal conditions, Geochimica et Cosmochimica Acta, 75, 21, (6629), (2011).
- Charlotte Weinstein, Frédéric Moynier, Kun Wang, Randal Paniello, Julien Foriel, Jeff Catalano and Sylvain Pichat, Isotopic fractionation of Cu in plants, Chemical Geology, (2011).
- Romain Guilbaud, Ian B. Butler, Rob M. Ellam, David Rickard and Anthony Oldroyd, Experimental determination of the equilibrium Fe isotope fractionation between and FeSm (mackinawite) at 25 and 2°C, Geochimica et Cosmochimica Acta, 75, 10, (2721), (2011).
- Norbert Jakubowski, Thomas Prohaska, Frank Vanhaecke, Peter H. Roos and Torsten Lindemann, Inductively coupled plasma- and glow discharge plasma-sector field mass spectrometry : Part II. Applications, Journal of Analytical Atomic Spectrometry, 10.1039/c0ja00007h, 26, 4, (727), (2011).
- Fang Huang, Zhaofeng Zhang, Craig C. Lundstrom and Xiachen Zhi, Iron and magnesium isotopic compositions of peridotite xenoliths from Eastern China, Geochimica et Cosmochimica Acta, 75, 12, (3318), (2011).
- Olivier J. Rouxel and Maureen Auro, Iron Isotope Variations in Coastal Seawater Determined by Multicollector ICP‐MS, Geostandards and Geoanalytical Research, 34, 2, (135-144), (2010).
- Marc Blanchard, Guillaume Morin, Michele Lazzeri and Etienne Balan, First-principles study of the structural and isotopic properties of Al- and OH-bearing hematite, Geochimica et Cosmochimica Acta, 74, 14, (3948), (2010).
- Mirjam Kiczka, Jan G. Wiederhold, Jakob Frommer, Stephan M. Kraemer, Bernard Bourdon and Ruben Kretzschmar, Iron isotope fractionation during proton- and ligand-promoted dissolution of primary phyllosilicates, Geochimica et Cosmochimica Acta, 74, 11, (3112), (2010).
- Jay R. Black, Edward D. Young and Abby Kavner, Electrochemically controlled iron isotope fractionation, Geochimica et Cosmochimica Acta, 10.1016/j.gca.2009.10.047, 74, 3, (809-817), (2010).
- Yang Liu, Michael J. Spicuzza, Paul R. Craddock, James M.D. Day, John W. Valley, Nicolas Dauphas and Lawrence A. Taylor, Oxygen and iron isotope constraints on near-surface fractionation effects and the composition of lunar mare basalt source regions, Geochimica et Cosmochimica Acta, 74, 21, (6249), (2010).
- Seth G. John and Jess F. Adkins, Analysis of dissolved iron isotopes in seawater, Marine Chemistry, 119, 1-4, (65), (2010).
- Monika Guelke, Friedhelm von Blanckenburg, Ronny Schoenberg, Michael Staubwasser and Hartmut Stuetzel, Determining the stable Fe isotope signature of plant-available iron in soils, Chemical Geology, 277, 3-4, (269), (2010).
- A. Kappler, C.M. Johnson, H.A. Crosby, B.L. Beard and D.K. Newman, Evidence for equilibrium iron isotope fractionation by nitrate-reducing iron(II)-oxidizing bacteria, Geochimica et Cosmochimica Acta, 74, 10, (2826), (2010).
- Frank M. Richter, E. Bruce Watson, Ruslan Mendybaev, Nicolas Dauphas, Bastian Georg, James Watkins and John Valley, Isotopic fractionation of the major elements of molten basalt by chemical and thermal diffusion, Geochimica et Cosmochimica Acta, 73, 14, (4250), (2009).
- Raphaelle Escoube, Olivier J. Rouxel, Edward Sholkovitz and Olivier F.X. Donard, Iron isotope systematics in estuaries: The case of North River, Massachusetts (USA), Geochimica et Cosmochimica Acta, 73, 14, (4045), (2009).
- Frank Wombacher, Anton Eisenhauer, Alexander Heuser and Stefan Weyer, Separation of Mg, Ca and Fe from geological reference materials for stable isotope ratio analyses by MC-ICP-MS and double-spike TIMS, Journal of Analytical Atomic Spectrometry, 24, 5, (627), (2009).
- Frank Vanhaecke, Lieve Balcaen and Dmitry Malinovsky, Use of single-collector and multi-collector ICP-mass spectrometry for isotopic analysis, Journal of Analytical Atomic Spectrometry, 24, 7, (863), (2009).
- , Abstracts, Meteoritics & Planetary Science, 44, S7, (A15-A229), (2010).
- , References, Handbook of Stable Isotope Analytical Techniques, 10.1016/B978-0-444-51115-7.00028-0, (1123-1321), (2009).
- Grit Steinhoefel, Ingo Horn and Friedhelm von Blanckenburg, Matrix-independent Fe isotope ratio determination in silicates using UV femtosecond laser ablation, Chemical Geology, 268, 1-2, (67), (2009).
- Nicolas Dauphas, Ali Pourmand and Fang-Zhen Teng, Routine isotopic analysis of iron by HR-MC-ICPMS: How precise and how accurate?, Chemical Geology, 267, 3-4, (175), (2009).
- John B. Chapman, Dominik J. Weiss, Yao Shan and Marcus Lemburger, Iron isotope fractionation during leaching of granite and basalt by hydrochloric and oxalic acids, Geochimica et Cosmochimica Acta, 73, 5, (1312), (2009).
- Grit Steinhoefel, Ingo Horn and Friedhelm von Blanckenburg, Micro-scale tracing of Fe and Si isotope signatures in banded iron formation using femtosecond laser ablation, Geochimica et Cosmochimica Acta, 73, 18, (5343), (2009).
- Brian Beard, Ariel Anbar, Christopher Romanek and C Andrus, Nontraditional Stable Isotopes in Environmental Sciences, Environmental Isotopes in Biodegradation and Bioremediation, 10.1201/9781420012613.ch12, (385-435), (2010).
- Nicolas Estrade, Jean Carignan, Jeroen E. Sonke and Olivier F.X. Donard, Mercury isotope fractionation during liquid–vapor evaporation experiments, Geochimica et Cosmochimica Acta, 73, 10, (2693), (2009).
- Axel Hofmann, Andrey Bekker, Olivier Rouxel, Doug Rumble and Sharad Master, Multiple sulphur and iron isotope composition of detrital pyrite in Archaean sedimentary rocks: A new tool for provenance analysis, Earth and Planetary Science Letters, 286, 3-4, (436), (2009).
- Nadya Teutsch, Martin Schmid, Beat Müller, Alex N. Halliday, Helmut Bürgmann and Bernhard Wehrli, Large iron isotope fractionation at the oxic–anoxic boundary in Lake Nyos, Earth and Planetary Science Letters, 285, 1-2, (52), (2009).
- Maureen Feineman, Sarah Penniston-Dorland, Franck Poitrasson and Stefan Weyer, Applications of non-traditional stable isotopes in high-temperature geochemistry, Chemical Geology, 258, 1-2, (1), (2009).
- Christophe Thomazo, Daniele L. Pinti, Vincent Busigny, Magali Ader, Ko Hashizume and Pascal Philippot, Biological activity and the Earth's surface evolution: Insights from carbon, sulfur, nitrogen and iron stable isotopes in the rock record, Comptes Rendus Palevol, 8, 7, (665), (2009).
- Marc Blanchard, Franck Poitrasson, Merlin Méheut, Michele Lazzeri, Francesco Mauri and Etienne Balan, Iron isotope fractionation between pyrite (FeS2), hematite (Fe2O3) and siderite (FeCO3): A first-principles density functional theory study, Geochimica et Cosmochimica Acta, 73, 21, (6565), (2009).
- Toshiyuki Fujii, Frédéric Moynier and Francis Albarède, The nuclear field shift effect in chemical exchange reactions, Chemical Geology, 267, 3-4, (139), (2009).
- Christophe Cloquet, Jean Carignan, Moritz F. Lehmann and Frank Vanhaecke, Variation in the isotopic composition of zinc in the natural environment and the use of zinc isotopes in biogeosciences: a review, Analytical and Bioanalytical Chemistry, 390, 2, (451), (2008).
- A. Kavner, S.G. John, S. Sass and E.A. Boyle, Redox-driven stable isotope fractionation in transition metals: Application to Zn electroplating, Geochimica et Cosmochimica Acta, 72, 7, (1731), (2008).
- Alain R. Préat, Jeroen T.M. de Jong, Bernard L. Mamet and Nadine Mattielli, Stable Iron Isotopes and Microbial Mediation in Red Pigmentation of the Rosso Ammonitico (Mid-Late Jurassic, Verona Area, Italy), Astrobiology, 8, 4, (841), (2008).
- T. Arnold, J.N. Harvey and D.J. Weiss, An experimental and theoretical investigation into the use of H2 for the simultaneous removal of ArO+ and ArOH+ isobaric interferences during Fe isotope ratio analysis with collision cell based Multi-Collector Inductively Coupled Plasma Mass Spectrometry, Spectrochimica Acta Part B: Atomic Spectroscopy, 63, 6, (666), (2008).
- Adriana Heimann, Brian L. Beard and Clark M. Johnson, The role of volatile exsolution and sub-solidus fluid/rock interactions in producing high 56Fe/54Fe ratios in siliceous igneous rocks, Geochimica et Cosmochimica Acta, 72, 17, (4379), (2008).
- M. Egal, F. Elbaz-Poulichet, C. Casiot, M. Motelica-Heino, P. Négrel, O. Bruneel, A.M. Sarmiento and J.M. Nieto, Iron isotopes in acid mine waters and iron-rich solids from the Tinto–Odiel Basin (Iberian Pyrite Belt, Southwest Spain), Chemical Geology, 253, 3-4, (162), (2008).
- F.-Z. Teng, N. Dauphas and R. T. Helz, Iron Isotope Fractionation During Magmatic Differentiation in Kilauea Iki Lava Lake, Science, 320, 5883, (1620), (2008).
- Clark M. Johnson, Brian L. Beard and Eric E. Roden, The Iron Isotope Fingerprints of Redox and Biogeochemical Cycling in Modern and Ancient Earth, Annual Review of Earth and Planetary Sciences, 36, 1, (457), (2008).
- Shawn D. Domagal-Goldman and James D. Kubicki, Density functional theory predictions of equilibrium isotope fractionation of iron due to redox changes and organic complexation, Geochimica et Cosmochimica Acta, 72, 21, (5201), (2008).
- Daniele L. Pinti, Ko Hashizume, Beate Orberger, Jean‐Paul Gallien, Christophe Cloquet and Marc Massault, Biogenic nitrogen and carbon in Fe‐Mn‐oxyhydroxides from an Archean chert, Marble Bar, Western Australia, Geochemistry, Geophysics, Geosystems, 8, 2, (2007).
- Hugh C. Jenkyns, Alan Matthews, Harilaos Tsikos and Yigal Erel, Nitrate reduction, sulfate reduction, and sedimentary iron isotope evolution during the Cenomanian‐Turonian oceanic anoxic event, Paleoceanography, 22, 3, (2007).
- , Current literature in mass spectrometry, Journal of Mass Spectrometry, 42, 3, (407-418), (2007).
- Franck Poitrasson, Does planetary differentiation really fractionate iron isotopes?, Earth and Planetary Science Letters, 256, 3-4, (484), (2007).
- David L. COOK, Meenakshi WADHWA, Robert N. CLAYTON, Nicolas DAUPHAS, Philip E. JANNEY and Andrew M. DAVIS, Mass‐dependent fractionation of nickel isotopes in meteoritic metal, Meteoritics & Planetary Science, 42, 12, (2067-2077), (2010).
- Dan Asael, Alan Matthews, Miryam Bar-Matthews and Ludwik Halicz, Copper isotope fractionation in sedimentary copper mineralization (Timna Valley, Israel), Chemical Geology, 243, 3-4, (238), (2007).
- Nicolas Dauphas, Diffusion‐driven kinetic isotope effect of Fe and Ni during formation of the Widmanstätten pattern, Meteoritics & Planetary Science, 42, 9, (1597-1613), (2010).
- V.B. Polyakov, R.N. Clayton, J. Horita and S.D. Mineev, Equilibrium iron isotope fractionation factors of minerals: Reevaluation from the data of nuclear inelastic resonant X-ray scattering and Mössbauer spectroscopy, Geochimica et Cosmochimica Acta, 71, 15, (3833), (2007).
- Jeffrey R. Bacon, Kathryn L. Linge, Randall R. Parrish and Luc Van Vaeck, Atomic spectrometry update. Atomic mass spectrometry, Journal of Analytical Atomic Spectrometry, 10.1039/b707553g, 22, 8, (973), (2007).
- Nicolas Dauphas, Nicole L. Cates, Stephen J. Mojzsis and Vincent Busigny, Identification of chemical sedimentary protoliths using iron isotopes in the >3750 Ma Nuvvuagittuq supracrustal belt, Canada, Earth and Planetary Science Letters, 254, 3-4, (358), (2007).
- Jan G. Wiederhold, Nadya Teutsch, Stephan M. Kraemer, Alex N. Halliday and Ruben Kretzschmar, Iron isotope fractionation in oxic soils by mineral weathering and podzolization, Geochimica et Cosmochimica Acta, 71, 23, (5821), (2007).
- Vincent Busigny and Nicolas Dauphas, Tracing paleofluid circulations using iron isotopes: A study of hematite and goethite concretions from the Navajo Sandstone (Utah, USA), Earth and Planetary Science Letters, 254, 3-4, (272), (2007).
- Dominik J. Weiss, Nicole Rausch, Thomas F.D. Mason, Barry J. Coles, Jamie J. Wilkinson, Liisa Ukonmaanaho, Tim Arnold and Tiina M. Nieminen, Atmospheric deposition and isotope biogeochemistry of zinc in ombrotrophic peat, Geochimica et Cosmochimica Acta, 71, 14, (3498), (2007).
- Nicolas Dauphas, Mark van Zuilen, Vincent Busigny, Aivo Lepland, Meenakshi Wadhwa and Philip E. Janney, Iron isotope, major and trace element characterization of early Archean supracrustal rocks from SW Greenland: Protolith identification and metamorphic overprint, Geochimica et Cosmochimica Acta, 71, 19, (4745), (2007).
- Jan A. Schuessler, Ronny Schoenberg, Harald Behrens and Friedhelm von Blanckenburg, The experimental calibration of the iron isotope fractionation factor between pyrrhotite and peralkaline rhyolitic melt, Geochimica et Cosmochimica Acta, 71, 2, (417), (2007).
- Ronny Schoenberg and Friedhelm von Blanckenburg, Modes of planetary-scale Fe isotope fractionation, Earth and Planetary Science Letters, 252, 3-4, (342), (2006).
- Ingo Horn, Friedhelm von Blanckenburg, Ronny Schoenberg, Grit Steinhoefel and Gregor Markl, In situ iron isotope ratio determination using UV-femtosecond laser ablation with application to hydrothermal ore formation processes, Geochimica et Cosmochimica Acta, 70, 14, (3677), (2006).
- Frédéric Moynier, Audrey Bouvier, Janne Blichert-Toft, Philippe Telouk, Daniela Gasperini and Francis Albarède, Europium isotopic variations in Allende CAIs and the nature of mass-dependent fractionation in the solar nebula, Geochimica et Cosmochimica Acta, 70, 16, (4287), (2006).
- Andreas Pack, Andres Höweling, Dominik C. Hezel, Maren T. Stefanak, Anne-Katrin Beck, Stefan T. M. Peters, Sukanya Sengupta, Daniel Herwartz and Luigi Folco, Tracing the oxygen isotope composition of the upper Earth’s atmosphere using cosmic spherules, Nature Communications, 10.1038/ncomms15702, 8, (15702), (2017).
