Enhancement of Solar Energy Absorption and Optoelectronic Properties of SrCuSbS3 by Lead Doping
Abstract
Copper antimony sulfides (CAS) are of great interest for their applications in solar absorbers. Here, a new series of CAS materials is reported, namely the Sr1−x Pbx CuSbS3 (x = 0–0.2), which are synthesized via solid state reactions. The new compound SrCuSbS3 crystallizes in the orthorhombic space group Pbam and consists of 3D [CuSbS3]2− extended framework and Sr2+ ions. The [CuSbS3]2− framework is constructed by [CuS3]5− one‐dimensional chains and [SbS3]3− triangular pyramids. The compound is a semiconductor with a band gap of 1.91 eV. Partial replacement of Sr2+ by Pb2+ can narrow the band gap to 1.63 eV when the doping concentration is up to 20%. First‐principles calculations reveal that the SrCuSbS3 compound is a direct band gap semiconductor with the valence band maximum composed of Cu‐3d states and the conduction band minimum composed of Sb‐5p ‐S‐3p states. The Pb orbitals play critical roles in narrowing the band gap of Sr1‐x Pbx CuSbS3 (x = 0–0.2). The series of CAS materials also show evident photoelectric response properties which demonstrate their potential for applications for photovoltaic devices. In addition, these CAS materials are good photocatalysts for the photodegradation reaction of Rhodamine B (RhB). The Sr0.8Pb0.2CuSbS3 powder can degrade 100% of RhB within 3 h under simulated sunlight.
