Recent developments in the field of high oxidation states of transition elements in oxides stabilization of Six‐coordinated Iron(V)*
Dedicated to Professor Rudolf Hoppe on his 60th birthday
Abstract
enAn evaluation of the physical properties of iron, cobalt, nickel, and copper high oxidation states in oxides shows the influence of chemical bonding and structural factors on the electronic configuration. Such correlations are illustrated by the synthesis of the first six‐coordinated iron(V) oxide: La2LiFeO6.
Abstract
deNeue Entwicklungen auf dem Gebiet der hohen Oxydationsstufen der Übergangsmetalle in Oxiden. Stabilisierung des sechsfach‐koordinierten Eisen(V)
Eine Bestimmung der physikalischen Eigenschaften von Eisen, Cobalt, Nickel und Kupfer hoher Oxydationsstufen in Oxiden zeigt den Einfluß der chemischen Bindung und struktureller Faktoren auf die elektronische Konfiguration. Diese Zusammenhänge werden gezeigt bei der Synthese des ersten sechsfach‐koordinierten Eisen(V)‐oxids: La2LiFeO6.
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