Volume 15, Issue 5

Global Lithium Availability

A Constraint for Electric Vehicles?

Paul W. Gruber

University of Michigan's Erb Institute in Ann Arbor, Michigan, USA

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Pablo A. Medina

University of Michigan's Erb Institute in Ann Arbor, Michigan, USA

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Mark P. Everson

Ford Motor Company's Research and Innovation Center in Dearborn, Michigan, USA

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Timothy J. Wallington

Ford Motor Company's Research and Innovation Center in Dearborn, Michigan, USA

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First published: 26 July 2011
Citations: 258

Gregory A. Keoleian
Center for Sustainable Systems
School of Natural Resources and
Environment
440 Church Street
Ann Arbor, MI 48109‐1041
USA
gregak@umich.edu
http://css.snre.umich.edu/

Summary

There is disagreement on whether the supply of lithium is adequate to support a future global fleet of electric vehicles. We report a comprehensive analysis of the global lithium resources and compare it to an assessment of global lithium demand from 2010 to 2100 that assumes rapid and widespread adoption of electric vehicles.

Recent estimates of global lithium resources have reached very different conclusions. We compiled data on 103 deposits containing lithium, with an emphasis on the 32 deposits that have a lithium resource of more than 100,000 tonnes each. For each deposit, data were compiled on its location, geologic type, dimensions, and content of lithium as well as current status of production where appropriate. Lithium demand was estimated under the assumption of two different growth scenarios for electric vehicles and other current battery and nonbattery applications.

The global lithium resource is estimated to be about 39 Mt (million tonnes), whereas the highest demand scenario does not exceed 20 Mt for the period 2010 to 2100. We conclude that even with a rapid and widespread adoption of electric vehicles powered by lithium‐ion batteries, lithium resources are sufficient to support demand until at least the end of this century.

Number of times cited according to CrossRef: 258

  • Metamorphic acceleration following the exposure to lithium and selenium on American bullfrog tadpoles (Lithobates catesbeianus), Ecotoxicology and Environmental Safety, 10.1016/j.ecoenv.2020.111101, 207, (111101), (2021).
  • Advanced Anode Materials of Potassium Ion Batteries: from Zero Dimension to Three Dimensions, Nano-Micro Letters, 10.1007/s40820-020-00541-y, 13, 1, (2020).
  • Comprehensive insights and perspectives into the recent progress of electrode materials for non-aqueous K-ion battery, Journal of Materiomics, 10.1016/j.jmat.2020.02.007, (2020).
  • DiaNanofiltration-based process for effective separation of Li+ from the high Mg2+/Li+ ratio aqueous solution, Separation and Purification Technology, 10.1016/j.seppur.2020.116965, (116965), (2020).
  • Review of critical metal dynamics to 2050 for 48 elements, Resources, Conservation and Recycling, 10.1016/j.resconrec.2019.104669, 155, (104669), (2020).
  • Recycling of mixed cathode lithium‐ion batteries for electric vehicles: Current status and future outlook, Carbon Energy, 10.1002/cey2.29, 2, 1, (6-43), (2020).
  • SiOC functionalization of MoS 2 as a means to improve stability as sodium-ion battery anode , Nanotechnology, 10.1088/1361-6528/ab6480, 31, 14, (145403), (2020).
  • Lithium extraction from brine in an ionic selective desalination battery, Desalination, 10.1016/j.desal.2020.114360, 481, (114360), (2020).
  • Selective recovery of lithium from geothermal water by EGDE cross-linked spherical CTS/LMO, Chemical Engineering Journal, 10.1016/j.cej.2020.124410, (124410), (2020).
  • Reviewing the material and metal security of low-carbon energy transitions, Renewable and Sustainable Energy Reviews, 10.1016/j.rser.2020.109789, 124, (109789), (2020).
  • Saharan lithium: Brine chemistry of chotts from eastern Algeria, Applied Geochemistry, 10.1016/j.apgeochem.2020.104566, 115, (104566), (2020).
  • Experimental Characterization of a Commercial Sodium-Nickel Chloride Battery for Telecom Applications, Applications in Electronics Pervading Industry, Environment and Society, 10.1007/978-3-030-37277-4_33, (285-291), (2020).
  • Surface chemistry features of spodumene with isomorphous substitution, Minerals Engineering, 10.1016/j.mineng.2019.106139, 146, (106139), (2020).
  • Three-dimensional carbonaceous for potassium ion batteries anode to boost rate and cycle life performance, Journal of Power Sources, 10.1016/j.jpowsour.2020.227727, 451, (227727), (2020).
  • Identifying the mechanism and impact of parasitic reactions occurring in carbonaceous seawater battery cathodes, Journal of Materials Chemistry A, 10.1039/D0TA02913K, (2020).
  • Resynthesizing LiFePO4/C materials from the recycled cathode via a green full-solid route, Journal of Alloys and Compounds, 10.1016/j.jallcom.2019.153292, 818, (153292), (2020).
  • Flexible C 6 BN Monolayers As Promising Anode Materials for High-Performance K-Ion Batteries , ACS Applied Materials & Interfaces, 10.1021/acsami.0c09451, 12, 27, (30731-30739), (2020).
  • Cathode for Thin-Film Lithium-Ion Batteries, Lithium-ion Batteries - Thin Film for Energy Materials and Devices, 10.5772/intechopen.73346, (2020).
  • Lithium and Brine Geochemistry in the Salars of the Southern Puna, Andean Plateau of Argentina, Economic Geology, 10.5382/econgeo.4754, 115, 5, (1079-1096), (2020).
  • Ab initio investigation of α- and ζ-V2O5 for beyond lithium ion battery cathodes, Journal of Power Sources, 10.1016/j.jpowsour.2020.228096, (228096), (2020).
  • The key factors and mechanism study on lithium extraction by TBP-FeCl3 extraction system, Chemical Physics Letters, 10.1016/j.cplett.2020.137740, 754, (137740), (2020).
  • Enhancement in Li+/Mg2+ separation from salt lake brine with PDA–PEI composite nanofiltration membrane, Journal of Applied Polymer Science, 10.1002/app.49549, 137, 47, (2020).
  • Assessment of lithium criticality in the global energy transition and addressing policy gaps in transportation, Nature Communications, 10.1038/s41467-020-18402-y, 11, 1, (2020).
  • Battery materials for low-cost electric transportation, Materials Today, 10.1016/j.mattod.2020.09.027, (2020).
  • Beyond the EVent horizon: Battery waste, recycling, and sustainability in the United Kingdom electric vehicle transition, Energy Research & Social Science, 10.1016/j.erss.2020.101581, 69, (101581), (2020).
  • Potential impact of the end-of-life batteries recycling of electric vehicles on lithium demand in China: 2010–2050, Science of The Total Environment, 10.1016/j.scitotenv.2020.142835, (142835), (2020).
  • Breaking Free from Cobalt Reliance in Lithium-Ion Batteries, iScience, 10.1016/j.isci.2020.101505, 23, 9, (101505), (2020).
  • Understanding the role of sodium hydroxide in the selective flotation separation of spodumene from feldspar and quartz, Minerals Engineering, 10.1016/j.mineng.2020.106648, 159, (106648), (2020).
  • Spinel H4Ti5O12 nanotubes for Li recovery from aqueous solutions: Thermodynamics and kinetics study, Journal of Environmental Chemical Engineering, 10.1016/j.jece.2020.104679, (104679), (2020).
  • The rise and fall of American lithium, Resources, Conservation and Recycling, 10.1016/j.resconrec.2020.105034, 162, (105034), (2020).
  • Review on the production of high-purity lithium metal, Journal of Materials Chemistry A, 10.1039/D0TA07611B, (2020).
  • Sulfonated poly (ether ether ketone) composite cation exchange membrane for selective recovery of lithium by electrodialysis, Desalination, 10.1016/j.desal.2020.114755, 496, (114755), (2020).
  • Lithium recovery from salt-lake brine: Impact of competing cations, pretreatment and preconcentration, Chemosphere, 10.1016/j.chemosphere.2020.127623, 260, (127623), (2020).
  • The EV revolution: The road ahead for critical raw materials demand, Applied Energy, 10.1016/j.apenergy.2020.115072, 280, (115072), (2020).
  • Interdependencies of lithium mining and communities sustainability in Salar de Atacama, Chile, Journal of Cleaner Production, 10.1016/j.jclepro.2020.120838, (120838), (2020).
  • High-performance Na–CO 2 batteries with ZnCo 2 O 4 @CNT as the cathode catalyst , Journal of Materials Chemistry A, 10.1039/D0TA09235E, (2020).
  • Selective regeneration of lithium from spent lithium-ion batteries using ionic substitution stimulated by mechanochemistry, Journal of Cleaner Production, 10.1016/j.jclepro.2020.123612, (123612), (2020).
  • Selective extraction of valuable metals from spent EV power batteries using sulfation roasting and two stage leaching process, Separation and Purification Technology, 10.1016/j.seppur.2020.118078, (118078), (2020).
  • Metabolic, immunologic, and histopathologic responses on premetamorphic American bullfrog (Lithobates catesbeianus) following exposure to lithium and selenium, Environmental Pollution, 10.1016/j.envpol.2020.116086, (116086), (2020).
  • Comparison of the effects of edge functionalized graphene oxide membranes on monovalent cation selectivity, Journal of Membrane Science, 10.1016/j.memsci.2020.118892, (118892), (2020).
  • Highly dispersed ultra-small nano Sn-SnSb nanoparticles anchored on N-doped graphene sheets as high performance anode for sodium ion batteries, Applied Surface Science, 10.1016/j.apsusc.2020.145686, (145686), (2020).
  • Production of Lithium Metal with Ion-Selective Solid Electrolytes, Green Energy & Environment, 10.1016/j.gee.2020.04.011, (2020).
  • Development of a co-precipitation process for the preparation of magnesium hydroxide containing lithium carbonate from Li-enriched brines, Hydrometallurgy, 10.1016/j.hydromet.2020.105515, (105515), (2020).
  • Effectively enhancing recovery of fine spodumene via aggregation flotation, Rare Metals, 10.1007/s12598-019-01365-5, (2020).
  • High-purity electrolytic lithium obtained from low-purity sources using solid electrolyte, Nature Sustainability, 10.1038/s41893-020-0485-x, (2020).
  • A Review of Processes and Technologies for the Recycling of Spent Lithium-ion Batteries, IOP Conference Series: Materials Science and Engineering, 10.1088/1757-899X/782/2/022025, 782, (022025), (2020).
  • Integrated Approach Based on Dual Extended Kalman Filter and Multivariate Autoregressive Model for Predicting Battery Capacity Using Health Indicator and SOC/SOH, Energies, 10.3390/en13092138, 13, 9, (2138), (2020).
  • The Particle Size Effect on Platinum Dissolution: Considerations for Accelerated Stability Testing of Fuel Cell Catalysts, ACS Catalysis, 10.1021/acscatal.0c00779, (2020).
  • Experimental Investigation of an Electrical Model for Sodium–Nickel Chloride Batteries, Energies, 10.3390/en13102652, 13, 10, (2652), (2020).
  • Lithium-Rich Claystone in the McDermitt Caldera, Nevada, USA: Geologic, Mineralogical, and Geochemical Characteristics and Possible Origin, Minerals, 10.3390/min10010068, 10, 1, (68), (2020).
  • Artificial Neural Network Prediction of Metastable Zone Widths in Reactive Crystallization of Lithium Carbonate, Industrial & Engineering Chemistry Research, 10.1021/acs.iecr.9b06074, (2020).
  • Assessment of the Supply Chain under Uncertainty: The Case of Lithium, Minerals, 10.3390/min10070604, 10, 7, (604), (2020).
  • State-of-the-Art Electrode Materials for Sodium-Ion Batteries, Materials, 10.3390/ma13163453, 13, 16, (3453), (2020).
  • Compressively Stressed Silicon Nano-Clusters as an Anti-Fracture Mechanism for High-Performance Lithium-Ion Battery Anodes, ACS Applied Materials & Interfaces, 10.1021/acsami.0c10609, (2020).
  • African international trade in the global value chain of lithium batteries, Mitigation and Adaptation Strategies for Global Change, 10.1007/s11027-020-09911-8, (2020).
  • Metal-Based Electrocatalysts for High-Performance Lithium-Sulfur Batteries: A Review, Catalysts, 10.3390/catal10101137, 10, 10, (1137), (2020).
  • A Review of Life Cycle Assessment Studies of Electric Vehicles with a Focus on Resource Use, Resources, 10.3390/resources9030032, 9, 3, (32), (2020).
  • Solid–Liquid Phase Equilibria of the Aqueous Ternary System (Li 2 CO 3 + Na 2 CO 3 + H 2 O) at (278.15 to 308.15) K , Journal of Chemical & Engineering Data, 10.1021/acs.jced.0c00660, (2020).
  • Understanding the future of lithium: Part 2, temporally and spatially resolved life‐cycle assessment modeling, Journal of Industrial Ecology, 10.1111/jiec.12942, 24, 1, (90-100), (2019).
  • The Effect of Boron Forms on the Crystallization Process of Lithium Carbonate, Crystal Research and Technology, 10.1002/crat.201900169, 55, 1, (2019).
  • Understanding the future of lithium: Part 1, resource model, Journal of Industrial Ecology, 10.1111/jiec.12949, 24, 1, (80-89), (2019).
  • Fabrication and Evaluation of Aminoethyl benzo-12-crown-4 Functionalized Polymer Brushes adsorbents Formed by Surface-initiated ATRP Based on Macroporous PolyHIPEs and Postsynthetic Modification, Chemical Engineering Journal, 10.1016/j.cej.2019.122495, (122495), (2019).
  • Advanced rechargeable Na–CO 2 batteries enabled by a ruthenium@porous carbon composite cathode with enhanced Na 2 CO 3 reversibility , Chemical Communications, 10.1039/C9CC02737H, (2019).
  • Beta-spodumene: Na2CO3:NaCl system calcination: a kinetic study of the conversion to lithium salt, Chemical Engineering Research and Design, 10.1016/j.cherd.2019.05.019, (2019).
  • Integration of selectrodialysis and selectrodialysis with bipolar membrane to salt lake treatment for the production of lithium hydroxide, Desalination, 10.1016/j.desal.2019.04.024, 465, (1-12), (2019).
  • Technology generation and international collaboration in the Global Value Chain of Lithium Batteries, Resources, Conservation and Recycling, 10.1016/j.resconrec.2019.03.026, 146, (232-243), (2019).
  • Potential distributions of electric vehicle secondary used batteries for frequency regulation in Europe, Energy Procedia, 10.1016/j.egypro.2018.12.070, 159, (394-399), (2019).
  • A prospective material for the highly selective extraction of lithium ions based on a photochromic crowned spirobenzopyran, Journal of Materials Chemistry B, 10.1039/C8TB02906G, (2019).
  • Lithium: Production and estimated consumption. Evidence of persistence, Resources Policy, 10.1016/j.resourpol.2019.01.006, 60, (198-202), (2019).
  • Wetting characteristics of spodumene surfaces as influenced by collector adsorption, Minerals Engineering, 10.1016/j.mineng.2018.10.010, 130, (117-128), (2019).
  • An economic and environmental assessment on landfill gas to vehicle fuel conversion for waste hauling operations, Resources, Conservation and Recycling, 10.1016/j.resconrec.2018.11.021, 142, (155-166), (2019).
  • Stibium: A Promising Electrode toward Building High-Performance Na-Ion Full-Cells, Chem, 10.1016/j.chempr.2019.08.007, (2019).
  • Design of a systematic value chain for lithium-ion batteries from the raw material perspective, Resources Policy, 10.1016/j.resourpol.2019.101473, 64, (101473), (2019).
  • Chemo-economic analysis of battery aging and capacity fade in lithium-ion battery, Journal of Energy Storage, 10.1016/j.est.2019.100911, 25, (100911), (2019).
  • Recovery of lithium from mineral resources: State-of-the-art and perspectives – A review, Hydrometallurgy, 10.1016/j.hydromet.2019.105129, (105129), (2019).
  • Recent advances on electrodialysis for the recovery of lithium from primary and secondary resources, Hydrometallurgy, 10.1016/j.hydromet.2019.105124, (105124), (2019).
  • New conversion chemistry of CuSO4 as ultra-high-energy cathode material for rechargeable sodium battery, Energy Storage Materials, 10.1016/j.ensm.2019.07.013, (2019).
  • Determination of Boundary Conditions for Highly Efficient Separation of Magnesium and Lithium from Salt Lake Brine by Reaction-Coupled Separation Technology, Separation and Purification Technology, 10.1016/j.seppur.2019.115813, (115813), (2019).
  • The effect of critical material prices on the competitiveness of clean energy technologies, Materials for Renewable and Sustainable Energy, 10.1007/s40243-019-0146-z, 8, 2, (2019).
  • Selective recovery of lithium from the Great Salt Lake using lithium manganese oxide-diatomaceous earth composite, Hydrometallurgy, 10.1016/j.hydromet.2019.03.011, (2019).
  • Lithium extraction from complex aqueous solutions using supported ionic liquid membranes, Journal of Membrane Science, 10.1016/j.memsci.2019.03.013, (2019).
  • How will second-use of batteries affect stocks and flows in the EU? A model for traction Li-ion batteries, Resources, Conservation and Recycling, 10.1016/j.resconrec.2019.02.022, 145, (279-291), (2019).
  • Selective extraction of lithium (Li) and preparation of battery grade lithium carbonate (Li2CO3) from spent Li-ion batteries in nitrate system, Journal of Power Sources, 10.1016/j.jpowsour.2019.01.072, 415, (179-188), (2019).
  • Material flow analysis on critical raw materials of lithium-ion batteries in China, Journal of Cleaner Production, 10.1016/j.jclepro.2019.01.081, (2019).
  • Improved rate and cycling performance of FeF2-rGO hybrid cathode with poly (acrylic acid) binder for sodium ion batteries, Journal of Power Sources, 10.1016/j.jpowsour.2018.12.040, 413, (449-458), (2019).
  • Size induced structural changes in maricite-NaFePO 4 : an in-depth study by experiment and simulations , Physical Chemistry Chemical Physics, 10.1039/C9CP03838H, (2019).
  • Separation of lithium, cobalt and nickel from spent lithium-ion batteries using TBP and imidazolium-based ionic liquids, Journal of Industrial and Engineering Chemistry, 10.1016/j.jiec.2019.10.023, (2019).
  • Semi-continuous electrochemical extraction of lithium from brine using CF-NMMO/AC asymmetric hybrid capacitors, Electrochimica Acta, 10.1016/j.electacta.2019.135285, (135285), (2019).
  • Metallogenic characteristics and prospecting of granitic pegmatite-type rare metal deposits in the Tugeman area, middle part of Altyn Tagh, Acta Petrologica Sinica, 10.18654/1000-0569/2019.11.03, 35, 11, (3303-3316), (2019).
  • X‐ray Nano‐computed Tomography of Electrochemical Conversion in Lithium‐ion Battery, ChemSusChem, 10.1002/cssc.201901123, 12, 15, (3550-3561), (2019).
  • Photo‐Supercapacitors Based on Third‐Generation Solar Cells, ChemSusChem, 10.1002/cssc.201900398, 12, 15, (3431-3447), (2019).
  • Technology Policy and Road Map of Battery, Nanostructured Materials for Next-Generation Energy Storage and Conversion, 10.1007/978-3-662-58675-4, (1-59), (2019).
  • A Quantitative Metric for the Design of Selective Supercritical CO2 Extraction of Lithium from Geothermal Brine, ChemSusChem, 10.1002/cssc.201901200, 12, 15, (3532-3540), (2019).
  • CHARACTERIZATION OF LITHIUM CYCLING IN THE SALAR DE OLAROZ, CENTRAL ANDES, USING A GEOCHEMICAL AND ISOTOPIC APPROACH, Chemical Geology, 10.1016/j.chemgeo.2019.119340, (119340), (2019).
  • Water legislation in the context of lithium mining in Argentina, Resources Policy, 10.1016/j.resourpol.2019.101510, 64, (101510), (2019).
  • Bio-inspired interfaces for easy-to-recycle lithium-ion batteries, Extreme Mechanics Letters, 10.1016/j.eml.2019.100594, (100594), (2019).
  • Enhancing lithium ion capture by using a negatively overcharged biomass-based hybrid adsorbent, Journal of Environmental Chemical Engineering, 10.1016/j.jece.2019.103337, (103337), (2019).
  • Green principles for responsible battery management in mobile applications, Journal of Energy Storage, 10.1016/j.est.2019.100779, 24, (100779), (2019).
  • Synthesis of Polyporous Ion-sieve and Its Application for Selective Recovery of Lithium from Geothermal Water, ACS Applied Materials & Interfaces, 10.1021/acsami.9b07401, (2019).
  • Water Condensation in Traction Battery Systems, Energies, 10.3390/en12061171, 12, 6, (1171), (2019).
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