Advanced Materials
Communication

Atomic‐Level‐Designed Catalytically Active Palladium Atoms on Ultrathin Gold Nanowires

Rui Liu

State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco‐Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085 China

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Li‐Qiang Zhang

State Key Laboratory of Heavy Oil Processing and Department of Materials Science and Engineering, China University of Petroleum, Beijing, 102249 China

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Cun Yu

State Key Laboratory of Heavy Oil Processing and Department of Materials Science and Engineering, China University of Petroleum, Beijing, 102249 China

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Meng‐Tao Sun

Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, 100190 China

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Jing‐Fu Liu

Corresponding Author

E-mail address: jfliu@rcees.ac.cn

State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco‐Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085 China

E‐mail:

jfliu@rcees.ac.cn

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Gui‐Bin Jiang

State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco‐Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085 China

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First published: 07 December 2016
Citations: 19
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Abstract

A Ag monolayer facilitates the deposition of isolated Pd atoms rather than continuous ones on ultrathin Au nanowires. During the hydrogenation of nitrophenol and the electrooxidation of ethanol, these two groups of Pd atoms show distinctive but geometry‐dependent catalytic activity. This new atomic geometry maneuvering strategy is ready for the atomically precise design of nanocatalysts.

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