Induced Self‐Assembly of a Tetrathiafulvalene‐Based Open‐Shell Dyad through Intramolecular Electron Transfer†
This work was supported by the DGI grant POMAs (grant number CTQ2010‐19501), the Networking Research Center on Bioengineering, Biomaterials, and Nanomedicine (CIBER‐BBN), and the Generalitat de Catalunya (grant number 2009SGR00516). J.G. is grateful to the CSIC for a “JAE‐Doc” fellowship.
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Abstract
An organic switch : An open‐shell dyad, consisting of an electron acceptor perchlorotriphenylmethyl radical unit linked to an electron π‐donor tetrathiafulvalene unit through a vinylene π‐bridge, was synthesized (see picture). The self‐assembly of the dyad in solution induced by its intramolecular electron transfer was studied.
