Macromolecular Rapid Communications
Communication

First Curl, Then Wrinkle

Ana C. Trindade

Departamento de Ciência dos Materiais and CENIMAT/I3N, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829–516 Caparica, Portugal

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João P. Canejo

Departamento de Ciência dos Materiais and CENIMAT/I3N, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829–516 Caparica, Portugal

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Paulo I. C. Teixeira

Instituto Superior de Engenharia de Lisboa, Rua Conselheiro Emídio Navarro, 1950–062 Lisboa, Portugal

Centro de Física Teórica e Computacional da Universidade de Lisboa, Avenida Professor Gama Pinto 2, 1649–003 Lisboa, Portugal

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Pedro Patrício

Corresponding Author

Instituto Superior de Engenharia de Lisboa, Rua Conselheiro Emídio Navarro, 1950–062 Lisboa, Portugal

Centro de Física Teórica e Computacional da Universidade de Lisboa, Avenida Professor Gama Pinto 2, 1649–003 Lisboa, Portugal

E‐mail:

pedro.patricio@adf.isel.pt

),

mhg@fct.unl.pt

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Maria H. Godinho

Corresponding Author

Departamento de Ciência dos Materiais and CENIMAT/I3N, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829–516 Caparica, Portugal

E‐mail:

pedro.patricio@adf.isel.pt

),

mhg@fct.unl.pt

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First published: 19 August 2013
Cited by: 12
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Abstract

The excellent properties of elastomers are exploited to trigger wrinkling instabilities in curved shells. Micro‐ and nano‐fibres are produced by electrospinning and UV irradiated: each fibre consists of a soft core and a stiff outer half‐shell. Upon solvent de‐swelling, the fibres curl because the shell and the core have different natural lengths. Wrinkling only starts after the fibre has attained a well‐defined helical shape. A simple analytical model is proposed to find the curling curvature and wrinkle wavelength, as well as the transition between the “curling” and “wrinkling” regimes. This new instability resembles that found in the tendrils of climbing plants as they dry and lignify.

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