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Angewandte Chemie International Edition
Communication

Co‐Monomer Control of Carbon Nitride Semiconductors to Optimize Hydrogen Evolution with Visible Light

Jinshui Zhang

Research Institute of Photocatalysis, State Key Laboratory, Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China)

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Guigang Zhang

Research Institute of Photocatalysis, State Key Laboratory, Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China)

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Xiufang Chen

Research Institute of Photocatalysis, State Key Laboratory, Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China)

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Dr. Sen Lin

Research Institute of Photocatalysis, State Key Laboratory, Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China)

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Lennart Möhlmann

Institute of Chemistry, Technical University Berlin, Strasse des 17. Juni 135, 10623 Berlin (Germany)

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Dr. Grzegorz Dołęga

Institute of Chemistry, Technical University Berlin, Strasse des 17. Juni 135, 10623 Berlin (Germany)

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Dr. Grzegorz Lipner

Institute of Chemistry, Technical University Berlin, Strasse des 17. Juni 135, 10623 Berlin (Germany)

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Prof. Markus Antonietti

Department of Colloid Chemistry, Max‐Planck Institute of Colloids and Interfaces, Research Campus Golm, 14476 Potsdam (Germany)

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Prof. Siegfried Blechert

Institute of Chemistry, Technical University Berlin, Strasse des 17. Juni 135, 10623 Berlin (Germany)

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Prof. Xinchen Wang

Corresponding Author

E-mail address: xcwang@fzu.edu.cn

Research Institute of Photocatalysis, State Key Laboratory, Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China)

Research Institute of Photocatalysis, State Key Laboratory, Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China)
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First published: 14 February 2012
Cited by: 313

Supported by the National Natural Science Foundation of China (21033003 and 21173043), PCSIRT (0818), and the Light2Hydrogen Project.

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Abstract

Bottom–up synthesis of graphitic carbon nitride semiconductor catalysts for the photocatalytic evolution of hydrogen by visible light is achieved through the polymerization of dicyandiamide with organic monomers bearing cyano groups, amino groups, or both. This strategy allows ample opportunity to adjust the physical and chemical properties of the resulting heterogeneous carbon‐nitride‐based organocatalysts.

Number of times cited according to CrossRef: 313

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