Upcycled synthesis and extraction of carbon-encapsulated iron carbide nanoparticles for gap Plasmon applications in perovskite solar cells

An effective method for obtaining large amounts of metal nanoparticles (NPs) encapsulated by carbon layers through upcycling from floating-catalyst aerosol chemical vapor-deposited carbon nanotubes is demonstrated. NPs with diameters of less than 20 μ m are selectively extracted from the synthesized carbon assortments through sonication, centrifugation, and filtration. The particles show an aggregation behavior owing to the π – π interaction between the graphitic carbon shells surrounding the iron carbides. By controlling the degree of the aggregation and arrangement, the light scattering by the gap-surface plasmon effect in perovskite solar cells is maximized. Application of the NPs to the devices increased the power conversion efficiency from 19.71% to 21.15%. The short-circuit current density ( J SC ) trend over the particle aggregation time accounts for the plasmonic effect. The devices show high stability analogue to the control devices, confirming that no metal-ion migration took place thanks to the encapsulation.


| INTRODUCTION
6][7][8] To achieve a high PCE, many efforts have been made by researchers globally.0][11][12][13] A more contemporary strategy is to use additives in PSCs.3][24] Such an additive approach is an attractive method because small amounts of materials entailed by a facile process have a tremendous impact on the PSC performance.Another well-established additive approach is the insertion of metal nanoparticles (NPs) to stimulate light absorption via the plasmonic effect. 25NPs [26][27][28] have been utilized in various fields, including biomedicine, 29 batteries, 30 and photovoltaics. 31The nanoscale size of NPs induces quantum effects, opening up infinite possibilities when employed in devices.8][39][40] A large number of electrons participate in the surface plasmonic resonance, improving the proximity field at the intrinsic frequency of the plasmonic metal NPs. 41,42hin-film solar cells such as organic solar cells [43][44][45][46] and PSCs [47][48][49][50] have exploited the properties of metal NPs to boost their PCE.However, it should be emphasized that applications of metal NP in PSCs are much fewer than those in organic solar cells.2][53][54] Inserting metal NPs within the PSC device system or, even worse, directly next to the perovskite layer, results in degradation of the PSCs.
Higgins et al. 34 and Yao et al. 38 suggested a solution to this, that is, protecting NPs by carbon materials, using which they increased the PCE of PSCs while retaining device stability.To date, two types of carbon-encapsulated metal NPs have been reported, namely, metallofullerenes and carbon-encapsulated iron carbide (FeC@C).FeC@C NPs were generated by heating ferrocene particles with carbon allotropes under high pressure. 37,620][61][62][63][64] The FeC in FeC@C has an Fe/Fe 1-x C x core/shell structure encapsulated by several carbon layers. 59,63This is simpler and incurs a much lower production cost and higher yield compared to metallofullerene synthesis.
In this study, we propose a facile and eco-friendly upcycling method of producing FeC@C NPs and demonstrate their applicability in photovoltaic devices as plasmonic NPs.6][67] As a result, the produced CNT films inevitably contain FeC@C NPs, which are regarded as impurities by CNT researchers.Unsuccessful synthesis leaves excess amounts of FeC@C NPs in CNT films, lowering the electrical performance of the CNTs.Instead of treating this as a failed CNT sample, FeC@C NPs can be selectively collected from the CNTs.Accordingly, a method of extracting FeC@C NPs from aerosol-synthesized CNTs is introduced in this work along with their application to PSCs as plasmonic light and charge transport enhancers that do not induce ion migration.FeC@C NPs with a diameter of ca.5-20 nm were extracted via sonication, centrifugation, and filtration.The collected NPs exhibited a fascinating trait of aggregation over time, which was attributed to the π-π interaction between the surrounding graphitic carbon layers, as observed from various analyses.By controlling the aggregation time, the gap plasmon coupling between the constituent NPs produced diverse plasmon modes, providing freedom to manipulate the optical properties via different nano-assemblies. 68This was supported by optical measurements and computational analyses.To exploit this phenomenon, the FeC@C NP solution was drop-cast onto the SnO 2 layer or onto the fluorinedoped tin oxide (FTO) layer, followed by certain periods of waiting time for aggregation to occur before the subsequent PSC fabrication.The FeC@C NP-added PSCs showed a considerably improved device performance compared to the control devices, irrespective of the FeC@C NPs above the SnO 2 layer or FTO layer.The aggregation waiting time of 3 h was optimal, giving the highest PCE of 21.15% and 20.57% from the PSCs with the NPs on SnO 2 and FTO, respectively.This is a substantial increase as the control PSCs without NPs gave a PCE of 19.71%.The increasing trend of short-circuit current density (J SC ) with the waiting time for NP aggregation revealed that the improved PCE resulted from the gap-surface plasmonic effect of the aggregated NPs.Enhanced electron collection by the inserted FeC@C NPs contributed to the increase in open-circuit voltage (V OC ) and fill factor (FF), which was corroborated by the investigation carried out herein.We conclude that the addition of FeC@C NPs induced not only the gap-surface plasmon effect but also favorable charge transport.The location of the added FeC@C NPs in the PSCs did not affect the device performance on SnO 2 or FTO.The unencapsulated FeC@C NP-added PSCs exhibited stable operation for over 40 days under ambient conditions compared to the control devices, confirming that no ion migration occurs and the use of NPs does not damage the perovskite layer.This is the first demonstration of carbonencapsulated metal NPs used as gap-surface plasmons in device applications.The proposed novel approach is a versatile and cost-effective route, which does not promote metal ion migration and will therefore lead to a breakthrough in the field of nanoparticle-based nextgeneration optoelectronics.

| Synthesis of carbon-encapsulated iron carbide NPs
Carbon films containing a large proportion of FeC@C NPs were synthesized using the floating-catalyst aerosol chemical vapor deposition under a specific condition described in the experimental section.The produced carbon films were observed using high-resolution transmission electron microscopy (HR-TEM) (Figure 1A).Expectedly, a large amount of FeC@C NPs was attached to the surface of the CNT strands.Energy-dispersive X-ray spectroscopy (EDS) analysis of TEM was used to identify FeC@C NPs by focusing on one of the CNT strands (Figures 1B, S1).The presence of Fe along the CNT strand confirmed the existence of FeC@C NPs.The HR-TEM image of the carbon film shows that FeC@C NPs have diameters between 5 and 20 nm (Figure S2).Fe NPs with a diameter of $8 nm were predominant, and they appeared completely wrapped by several layers of carbon sheets (Figure S2b).X-ray photoelectron spectroscopy (XPS) was used to ascertain the identity of the FeC@C NPs by probing the elemental status before and after cleaning the carbon films with acid (Figures 1C-G, S3).In this XPS analysis, we introduced conventional CNT films as well for comparison.The intensity of the Fe 2p3 , Fe 3p , and Fe 2p peaks from the aerosol-synthesized carbon film was considerably greater than those from the conventionally synthesized CNT films in which ferrocene were also used as the catalyst (Figures 1C, S3).To prove that the produced Fe NPs were thoroughly encapsulated by the carbon sheet, we rinsed the carbon film with triflic acid (TFMS).The intensity of the C 1s peak decreased after the acid treatment, from which we can deduce that any remaining unencapsulated FeO along with carbon impurities were washed away (Figure 1D). 69,70The fact that the intensity of the Fe peaks is stronger after the acid treatment indicates the reduction of FeO (Figures 1E, S3b).The FeC@C NPs were completely encapsulated by the carbon sheet, therefore unaffected by the acid, as evidenced by the conspicuous Fe peaks.The disappearance of the O 1s shoulder at 530 eV indicates the removal of oxygen from FeO, which supports our claim (Figure 1F). 71,72The overall O 1s peak at 534 eV increased in intensity after the acid treatment, probably due to the hygroscopic TFMS-doped carbon films attracting H 2 O and O 2 .

| Extraction of carbon-encapsulated iron carbide NPs
As the next step, FeC@C NPs were separated from the aerosol-synthesized carbon films by ultrasonication and filtration (Figure 2A).The separation procedure was as follows (Figure 2B): a carbon film containing a large amount of FeC@C-attached CNTs was sonicated intensively for 6 h in chlorobenzene (CB) to separate as many NPs as possible from the CNTs (Figure S4).4][75] The solution was centrifuged at 10 000 rpm for 20 min to sink large-size FeC@C NPs and CNTs.The supernatant of the solution was filtered by polytetrafluoroethylene (PTFE) with a 0.20-μm pore size to remove further impurities.The effects of sonication and filtration were analyzed using dynamic light scattering (DLS).The DLS data show that the sonicated solution contains FeC@C NPs with different sizes as well as some CNTs (Figures 2C, S6a); FeC@C NPs with a size of ca. 10 nm were dominant according to the DLS number graph (Figures 2D, S6a).This matches the size of the individual FeC@C NPs observed in the HR-TEM images (Figure S2).Remeasuring the same solution after a few hours of waiting did not show any peaks, indicating that the NPs and CNTs had sunk down below the detection range (Figure S6b).Interestingly, the measurement of the same solution after giving a gentle swirl showed the NP peaks but with an increased size, revealing that aggregation of NPs might have occurred owing to the π-π interaction between the graphitic carbon shells (Figure S6c).Further waiting increased the NP size even greater (Figures 2C, D,  S6d).The DLS data of the filtered solution showed that any particles greater than 100 nm, including CNTs, were removed (Figures 2D, S7).This means that we can control the size and degree of the FeC@C NP aggregation by waiting before drop-casting a NP solution onto a substrate.To confirm this, we used atomic force microscopy (AFM) and TEM.The FeC@C NPs were uniformly coated on a glass substrate according to the AFM images (Figure S8).However, the resolution of the images was not enough to observe NP aggregation.To verify the aggregation over the waiting time, we prepared FeC@C NPs on an HR-TEM grid according to the waiting time.We observed that some of the FeC@C NPs aggregated (Figure 2E), and the aggregation became stronger with the waiting time (Figure 2F).Despite our attempt to substantiate the π-π interaction between the carbon shells of the FeC@C NPs using the XPS technique, the quantity of FeC@C NPs coated on substrates was too low, and the Fe component was not detectable (Figure S9).

| Plasmonic effect of aggregated carbon-encapsulated iron carbide NPs
The controlled aggregation of the FeC@C NPs with fixed gaps between the NPs indicated that a powerful optical effect could be induced.This can lead to a remarkable improvement in photon absorption when exploited in device applications such as PSCs.To examine this, we conducted ultraviolet-visible (UV-Vis) absorption spectroscopy on the aggregated FeC@C NPs under different waiting time.The data show that the extinction increases with an increase in the waiting time (Figure 3A) and decreases back when the waiting time exceeds 3 h (Figure 3B).7][78][79] This phenomenon was investigated further using computational analysis.We modeled a spherical Fe core surrounded by a thin layer of C shell with varying diameters of Fe NP (D) and varying thickness of the C shell (t).The core diameter and the C shell Illustration of a method of separating FeC@C NPs from CNT. (C, D) DLS analysis of depending on the waiting time.(E) FeC@C NPs and enlarged TEM images.(F) HR-TEM results of FeC@C NPs that are aggregated depending on the waiting time.
thickness variables were set as 5, 10, and 15 nm, based on the information from the TEM images (Figure S2), and as 0, 1, 2, and 3 nm based on the reported multilayer graphene thickness (Table S1), respectively (Figures 3C,   S10). 80,81The absorption and scattering cross sections were calculated based on the varying core diameter and shell thickness, as well as different NP arrangements simulating NP aggregation (Figures 3d, S11).It was postulated that the scattering is favorable for the light absorption of the perovskite active film; however, the absorption of NPs themselves undermines the plasmonic enhancement.Thus, obtaining the conditions where the absorption cross section is minimal and the scattering cross section is maximum is important.According to the simulation results, a single FeC@C NP has absolutely no optical effect, regardless of the size (Figures S12, S13).However, the aggregated FeC@C NPs showed substantial scattering, despite a relatively small increase in absorption.In fact, the degree of absorption reverses when the number of aggregated NPs exceeds 4-5, whereas the degree of scattering increases continuously (Figure 3D).This indicates that the larger the aggregation, the greater is the plasmonic effect.Therefore, the gap plasmonic effect is a dominant factor in the near-field light absorption enhancement by the FeC@C NPs, and the shell thickness is a key parameter in determining the amount of generated plasmonic polaritons when electromagnetic fields are coupled with plasmons. 82With an increase in the shell thickness, the scattering cross-sectional red-shifts from ca. 500 nm to 700 nm, which is within the effective absorption range of the perovskite photoactive films. 83,84The shell thickness was deduced to be approximately 1 nm with 2-3 graphitic layers in the TEM images (Figure S2 and Table S1).Hence, we assume the shell thickness, t, to be 1, which produces a strong scattering cross section (Figure 3E) and gap-surface plasmon-induced electric field (Figure 3F) for all three core sizes, D. Raman spectroscopy was also performed on dropcast FeC@C NPs on glass substrates according to the waiting time to confirm the plasmonic effect.(Figure S14).The Raman peak intensity and band positions depend on the conditions of the carbon nanostructure. 85The difference in the Raman signal intensity for each excitation wavelength of the laser, namely 532, 633, and 785 nm, serves as indirect evidence for the electromagnetic field enhancement profile. 86At laser wavelengths of 532 and 633 nm, the Raman signal intensity of the D + D 0 band ($3 000 cm À1 ) was greater than that of the D band ($1500 cm À1 ).However, at 785 nm, the intensity of the D band intensified as the intensity of the D + D 'band decreased in all samples with different waiting times.This evidences the plasmonic effect in which the calculated scattering cross-sectional value decreases with an increase in the wavelength of the incident light.To our dismay, variation in the Raman intensity over the waiting time was not observed.8][89] As the electromagnetic mechanism-driven SERS effect arises from the nanoscale gaps between NPs, aggregation of FeC@C NPs is a key contributing factor.

| PSC application of carbonencapsulated iron NPs
Cs 0.05 FA 0.80 MA 0.15 PbI 2.75 Br 0.25 -based PSCs were fabricated in the configurational structure of FTO/SnO 2 / perovskite/spiro-MeOTAD/Au, where the FeC@C NPs were drop-cast onto FTO layers or SnO 2 layers (Figure 4A, B).The top-view SEM images show that the quality of the perovskite films was similar for both cases; however, the perovskite films formed on pristine SnO 2 showed a marginally larger crystal domain size than the perovskite films formed on the FeC@C NP-deposited SnO 2 (Figure 4C, D).We suspect that the presence of FeC@C NPs on SnO 2 may hinder the growth of the perovskite film, even though the FeC@C NPs were not visible in the cross-sectional SEM images (Figure 4E, F).EDS was performed on the same device.However, as the amount of FeC@C NP was too low to be detectable from the cross-sectional images (Figure S15).The devices were fabricated with different waiting times for FeC@C NP aggregations.In both cases, a waiting time of 3 h gave the highest PCEs (Figures S16, S17).The statistical analyses show that there is a trend of J SC and V OC increasing with the waiting time and reducing when the waiting time is longer than 3 h.This verifies the aforementioned plasmonic effect of the aggregated FeC@C NPs, as the increase in J SC is related to the number of absorbed photons. 90,91For the devices with the best performance, the PSCs where FeC@C NPs were coated on FTO gave a PCE of 20.57% with J SC of 25.05 mA cm À2 , V OC of 1.10 V, and FF of 0.74 (Figure .4g and Table 1).The PSCs with FeC@C NPs on SnO 2 exhibited an even higher PCE of 21.15% with a J SC of 25.73 mA cm À2 , V OC of 1.11 V, and FF of 0.74 (Figure 4H and Table 2).The difference in device performance was mainly due to the J SC values.92][93][94] The PSCs with FeC@C NPs on FTO exhibited a larger crystal domain size (Figure 4C, D).Nevertheless, PSCs with FeC@C NPs on SnO 2 produced a much higher J SC owing to the FeC@C NPs right under the perovskite film, inducing the plasmonic effect in closer proximity.Steadystate PL and time-resolved (tr-PL) of perovskite films on SnO 2 /FeC@C NPs/FTO samples and FeC@C NPs/SnO 2 / FTO samples were carried out at different waiting times.The increase in quenching of the PL spectra of both types of samples over the waiting time as well as the blueshifts indicate that the application of FeC@C NPs enhances the charge transfer and reduces the number of trap sites in SnO 2 . 95This explains the increase in V OC and FF of the FeC@C NP-applied PSCs in both the cases of FeC@C NPs above/under the SnO 2 layer.We postulate that the high-electron affinity of the carbon shell as well as the host-guest electronic interaction [37][38][39][40] augmenting exciton extraction.The higher external quantum efficiency (EQE) of the PSC using FeC@C NPs than that of the control device in the short-wavelength region from 300 to 600 nm is suspected to originate from the enhanced electron collection by the FeC@C NPs next to SnO 2 . 96The higher EQE of the PSC using the FeC@C NPs in the long-wavelength region from 650 nm to 800 nm corresponds to the greater light absorption due to the plasmonic effect (Figure S18).The device stability under constant illumination of one sun was checked to examine ion migration (Figure S19).All unencapsulated FeC@C NP-used PSCs showed good operational stability equal to that of the control device in both cases of FeC@C NPs above/under the SnO 2 layer.This indicates that there is no ion migration occurring within the device system owing to the Fe particles being fully encapsulated by the carbon shell.

| CONCLUSION
The synthesis and extraction of FeC@C NPs from aerosolsynthesized CNT films were demonstrated.Assortments of aerosol-synthesized CNTs containing FeC@C NPs of different sizes were dispersed in CB.FeC@C NPs with a desired size were collected through intensive sonication and filtration.The presence and size of the FeC@C NPs were verified using various techniques such as SEM, EDS, AFM, and TEM.The FeC@C NPs showed aggregation over time, entailing an increasing intensity of the gapsurface plasmon effect.The self-aggregated FeC@C NPs have great potential for application in optoelectronic devices because tailoring the number and position of the NPs in close-packed clusters can induce diverse plasmon modes exhibiting strong magnetic and Fano resonance.Capitalizing on this point, PSCs were fabricated with aggregated NPs placed on the SnO 2 layer and the FTO layer.The addition of the FeC@C NPs to PSCs improved the PCE, which was attributed to both the enhanced light absorption and charge transfer by the plasmonic effect and by the host-guest electronic interaction, respectively.The excellent device stability shown by the FeC@C NP-added PSCs proves that the metal ions in the NPs did not migrate T A B L E 1 Photovoltaic parameters of the PSCs with SnO 2 on FeC@C NPs under one sun (AM 1.5 G, 100 mW cm À2 ).The average values from 20 devices with error ranges are given in the square brackets.

Device structure and NP aggregation time
T A B L E 2 Photovoltaic parameters of the PSCs with FeC@C NPs on SnO 2 under one sun (AM 1.5 G, 100 mW cm À2 ).
Device structure and NP aggregation time Ref.  into the perovskite layer even when FeC@C NPs were next to the perovskite film.

| EXPERIMENTAL SECTION 4.1 | Preparation of FeC@C
Aerosol-synthesized CNT films containing a large number of FeC@C NPs were prepared using the floatingcatalyst aerosol chemical vapor deposition (CVD) method.Ferrocene (100 cc) was vaporized by passing CO through a cartridge filled with ferrocene powder.To stabilize the synthesis, 1.4% CO 2 was added to CO.The flow containing ferrocene vapor was introduced to the hightemperature zone of a quartz tube reactor through a water-cooled probe and mixed with additional CO.Ferrocene vapor was thermally decomposed in the gas phase of the aerosol CVD reactor at 850 C. CO gas was supplied at 0.35 L min À1 and decomposed on the Fe NPs, resulting in the growth of FeC@C NPs.The as-synthesized CNTs and FeC@C NPs were collected by passing the flow through CNTs, and FeC@C NPs were collected by filtering the flow through a nitrocellulose membrane filter (Millipore Corp., USA; HAWP, 0.45-μm pore diameter) downstream of the reactor for 93 h.The FeC@C-containing film was placed in a vial containing CB.To separate the intertwined FeC@C/CNT, sonication was performed at 40 k Hz for 6 h.This process separated the FeC@C particles from the CNTs.The supernatant containing FeC@C NPs was separated by centrifugation at 10 000 rpm for 20 min.The supernatant was filtered using PTFE with a pore diameter of 0.20 μm.The presence and size of the FeC@C NPs were determined using various analytical equipment described in Section 2. Next, the SnO 2 layer was spin-coated on the FTO glass (or SnO 2 layer) at 2 000 rpm for 30 s, which was later annealed at 150 C for 30 min.A solution containing FeC@C NPs was drop-casted on either FTO or SnO 2 after a designated waiting time from sonication to induce π-π aggregation.When the FeC@C solvent was dried, 100 μL of the perovskite solution was filtered through a 0.45-μm PTFE filter before being spin-coated on the SnO 2 layer at 7 000 rpm for 40 s.Antisolvent (1 mL of diethyl ether) was applied during the spin-coating of the perovskite solution at 37-38 s after spin-coating, followed by annealing at 150 C for 10 min.The spiro-MeOTAD solution was prepared by mixing 90.9 mg spiro-MeOTAD, 23 μL of a stock solution of 516 mg mL À1 Li-TFSI in anhydrous acetonitrile, 10 μL of a stock solution of 395 mg mL À1 FK209 in anhydrous acetonitrile, and 39 μL of t-BP in 1.0 mL of anhydrous CB.The hole-transporting layer was deposited from the 100 μL spiro-MeOTAD solution at 4 000 rpm for 20 s.Finally, an 80-nm-thick Au anode was fabricated by thermal deposition under a pressure of 10 À6 Torr.

| Device and film characterizations
The J-V curves of the PSCs under light were measured using a source meter (Keithley 2400, Tektronix) under simulated sunlight irradiation of 1 sun (AM 1.5G; 100 mW cm À2 ) using a solar simulator (Oriel ® Sol3A™ Class AAA solar simulator, model 94043A).The source meter was calibrated using a standard PV reference cell (2 cm Â 2 cm monocrystalline silicon solar cell, calibrated at NREL, Colorado, USA).The incident photon-to-current conversion efficiency also known as external quantum efficiency (EQE) spectrum was measured using an Oriel ® IQE-200TM equipped with a 250-W quartz tungsten halogen lamp as the light source and a monochromator, an optical chopper, a lock-in amplifier, and a calibrated silicon photodetector.Prior to the use of light, the spectral response and light intensity were calibrated using a monosilicon detector.The impedance response was measured over the range of 1 Hz to 1 MHz with an oscillation amplitude of 15 mV under dark conditions (Bio-Logic VMP-3).The experimental data were simulated using commercial Z-view software to estimate the values of each component using the corresponding equivalent circuits.The film surface and cross-sectional morphology were characterized via field emission scanning electron microscopy (FE-SEM, HITACHI Regulus8100).Photoluminescence (PL) was measured using a Quantaurus-QY plus (C-13534-12) from Hamamatsu Co., Ltd.

| Computational analysis
The finite-difference time-domain (FDTD) simulation of the plasmonic scattering and absorption of NPs was performed using the Lumerical FDTD software.The model comprised a 3D spatial domain of 80 Â 80 Â 80 nm 3 , which was meshed into 0.1 nm in all xyz coordinates, and its boundary condition was set as a perfectly matched layer that absorbs all outgoing waves.An optical source with a wavelength ranging from 300 to 800 nm generates a plane wave propagating toward a target set of scatterers designated with a specific number of NPs with a core diameter (D) and shell thickness (t).The source type was chosen as a total-field scattered-field, where the model considers only the scattered portion of optical energy from NPs and ignores the rest of the portion that does not interact with any objects.Two detectors (frequency-domain field and power) surrounded the simulation domain and monitored the absorbed and scattered optical energy by the NPs, resulting in effective scattering/absorption cross sections.The optical field pattern within the NPs aligned in a plane normal to the incoming plane wave was recorded using a DFT monitor.The timedomain simulation was terminated by either a 100-fs time limit or an early shutoff of 10 À5 .

AUTHOR CONTRIBUTIONS
JH and IJ wrote the manuscript.IJ concieved the project.MT and JH synthesized the nanoparticles and purified them.JH, KK, KP, YL, JWL fabricated devices.DK and IC performed time-resolved photoluminescence, JL and AL analayzed plasmonic effect.JH carried out other meausurement and sample for the analyses.HS, EK, IJ supervised the project.

F
I G U R E 1 (A) TEM image of the aerosol-synthesized carbon film.(B) Result of EDS analysis through TEM to confirm the existence of Fe components.(C) XPS result of iron region (Fe 2p3 ) in pristine CNT and carbon film.(C-F) XPS result of the C 1s peak, iron region (Fe 3p , Fe 2p ) and O 1s peak before and after acid treatment on the carbon film.

F
I G U R E 3 Optical analysis of FeC@C NPs (A, B) UV-Vis results of FeC@C NPs by waiting time, (C) Schematic illustration of FeC@C NPs, (D) geometry by number of FeC@C NPs, (E) When the t is 1 nm, graphs of absorption cross section and scattering cross section according to the change in the D, (F) When the D is 10 nm, the electric field according to the change in the t.

F
I G U R E 4 (A, B) Configurational structure and (C-F) SEM image of two type devices.(G, H) J-V curves of optimized devices based on the photovoltaic performance and the location of FeC@C NPs.(I-L) Steady-state PL and tr-PL of perovskite films on SnO 2 /FeC@C NPs/FTO samples and FeC@C NPs/SnO 2 /FTO samples under different waiting times.

Note:
Carbon-encapsulated iron carbide NPs are upcycled from CNTs for PSC application.The NPs aggregate owing to the π-π interaction of the graphitic shells.A gap-surface plasmon effect is induced depending on the degree of the aggregation and arrangements.When applied to solar cells, the efficiency increases from 19.7% to 21.2%.The added NPs do not instigate ion migration as they are encapsulated by the carbon shells.The average values from 20 devices with error ranges are given in the square brackets.