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Controllable Access to Furans and Dihydrofurans through Cyclization/Coupling of Internal Acetylenic β-Ketoesters with Aryl Bromides.

  •  23 November 2022


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The front cover picture illustrates the method enabling selective access to 2-benzylidene-dihydrofurans or 2-benzyl-furans, depending on the conditions. On reaching the Cyclization Hill, a metaphor for activation energy, the train on the left brakes to stop at Dihydrofurans station. Alternatively, more forcing conditions drive the right-hand train to pass the station and ascend a path leading through higher Isomerisation Hill towards Furans. Details can be found in the Research Article by Chaładaj and co-worker (B. Bisek, W. Chaładaj, Adv. Synth. Catal. 2022, 364, XXXX–XXXX; DOI: 10.1002/adsc.202200686)


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